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Cobalt-based layered double hydroxides as oxygen evolving electrocatalysts in neutral eletrolyte |
Hong LIN1(), Ye ZHANG1, Gang WANG2, Jian-Bao LI1,3 |
1. State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China; 2. College of Chemical Engineering, Qinghai University, Xining 810016, China; 3. Key Laboratory of Ministry of Education for Application Technology of Chemical Materials in Hainan Superior Resources, Hainan Provincial Key Laboratory of Research on Utilization of Si-Zr-Ti Resources, College of Materials Science and Chemical Engineering, Hainan University, Haikou 570228, China |
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Abstract Co–M (M= Co, Ni, Fe, Mn) layered double hydroxides (LDHs) were successfully fabricated by a hexamethylenetetramine (HMT) pyrolysis method. Composite electrodes were made using a self-assembly fashion at inorganic/organic surface binder-free and were used to catalyze oxygen evolution reaction. Water oxidation can take place in neutral electrolyte operating with modest overpotential. The doping of other transitional metal cations affords mix valences and thus more intimate electronic interactions for reversible chemisorption of dioxygen molecules. The application of employing LDH materials in water oxidation process bodes well to facilitate future hydrogen utilization.
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Keywords
layered double hydroxide (LDH)
oxygen evolution reaction
neutral
cobalt catalyst
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Corresponding Author(s):
LIN Hong,Email:hong-lin@tsinghua.edu.cn
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Issue Date: 05 June 2012
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