Intelligent deformation of biomedical polyurethane

doi:10.1007/s11706-021-0538-8

Front. Mater. Sci.

2021, Vol. 15

Issue (1) : 1-9 https://doi.org/10.1007/s11706-021-0538-8

VIEWS & COMMENTS

Intelligent deformation of biomedical polyurethane

Maolan ZHANG¹, Huan WANG¹, Junjie MAO¹, Da SUN², Xiaoling LIAO¹(

)

¹. Institute of Biomedical Engineering, Chongqing Engineering Laboratory of Nano/Micro Biological Medicine Detection Technology, Chongqing University of Science and Technology, Chongqing 401331, China
². Institute of Life Sciences & Biomedicine Collaborative Innovation Center, Wenzhou University, Wenzhou 325035, China

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Corresponding Author(s): Xiaoling LIAO

Online First Date: 22 January 2021 Issue Date: 11 March 2021

Cite this article:

Maolan ZHANG,Huan WANG,Junjie MAO, et al. Intelligent deformation of biomedical polyurethane[J]. Front. Mater. Sci., 2021, 15(1): 1-9.

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https://academic.hep.com.cn/foms/EN/10.1007/s11706-021-0538-8
https://academic.hep.com.cn/foms/EN/Y2021/V15/I1/1

Fig.1 Shape memory process of polyurethane (T_g, glass transition temperature of polyurethane; T_m, melting point of polyurethane soft segment).

Fig.2 Illustration of the molecular structure of AMPs. The model indicates that the AMPs consist of switches and net points. The net points can be of a chemically cross-linking, physical cross-linking and other entangled chains like interpenetrated networks and CDs interlocking. The switches include crystallization soft phase, amorphous soft phase, liquid crystalline phase and supramolecular switches. Reproduced with permission from Ref. [¹⁷].

Fig.3 (a) An example for the recovery process of shape memory effect when the PCL50 sample was placed in water of 70 °C. Reproduced with permission from Ref. [²⁵]. (b) Tungsten-doped foam visibility under fluoroscopic guidance during NFC 4 delivery. Reproduced with permission from Ref. [²⁸].

Fig.4 (a) Photographs showing the NIR light triggered shape memory behavior of a folded PU/BP film. (b) Plot of the shape recovery rate vs. the irradiation time. (c)(d) Photographs showing the NIR light triggered shape memory behavior of a rolled PU/BP film put in air and in water. Reproduced with permission from Ref. [³⁵].

Fig.5 (a) Application of a designed multifunctional wearable wrist band integrated electric heater and temperature indicator. (b) Time-dependent temperature profiles of wearable wrist band derived from TPU/SP-25 composite electrothermal film during the repeated heating-cooling 20 cycles. (c) The sheet resistance change and the relative resistance variation of TPU/SP-25 based wrist band during cyclic heating-cooling tests up to 20 cycles at 10 V (the inset shows Raman spectra of the TPU/SP-25 composite before and after the electrothermal test). Reproduced with permission from Ref. [³⁹].

Fig.6 (a) Skin model with a magnifying image showing collagen-elastin dual network. (b1) Skin collagen fiber/polyurethane (SCF/PU) composite. (b2) Proposed structural model of SCF/PU. (b3) Collagen fiber composed of three α spiral peptides which are stabled by hydrogen bonds. (b4) Microphase structure of polyurethane elastomer where soft segments composed of PTMG while hard segments consist of IPDI. (c) Water responsive shape memory behavior of SCF/PU composite. Reproduced with permission from Ref. [⁵²].

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