1. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, National Center for Nanoscience and Technology, Beijing 100190, China 2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China 3. Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education, School of Physics and Technology, Wuhan University, Wuhan 430072, China
Detection of solar-blind ultraviolet (SB-UV) light is important in applications like confidential communication, flame detection, and missile warning system. However, the existing SB-UV photodetectors still show low sensitivities. In this work, we demonstrate the extraordinary SB-UV detection performance of α-In2Se3 phototransistors. Benefiting from the coupled semiconductor and ferroelectricity property, the phototransistor has an ultraweak detectable power of 17.85 fW, an ultrahigh gain of 1.2 × 106, a responsivity of 2.6 × 105 A/W, a detectivity of 1.3 × 1016 Jones and an ultralow noise-equivalent-power of 4.2 × 10−20 W/Hz1/2 for 275 nm light. Its performance exceeds most other UV detectors, even including commercial photomultiplier tubes and avalanche photodiodes. It can be also implemented as an optoelectronic synapse for neuromorphic computing. A 784×300×10 artificial neural network (ANN) based on this optoelectronic synapse is constructed and demonstrated with a high recognition accuracy and good noise-tolerance for the Fashion-MNIST dataset. These extraordinary features endow this phototransistor with the potential for constructing advanced SB-UV detectors and intelligent hardware.
Gong M. , Liu Q. , Cook B. , Kattel B. , Wang T. , L. Chan W. , Ewing D. , Casper M. , Stramel A. , Z. Wu J. . All-printable ZnO quantum dots/graphene van der Waals heterostructures for ultrasensitive detection of ultraviolet light. ACS Nano, 2017, 11(4): 4114 https://doi.org/10.1021/acsnano.7b00805
2
Xu X.Chen J.Cai S.Long Z.Zhang Y.Su L.He S.Tang C.Liu P.Peng H.Fang X., A real-time wearable UV-radiation monitor based on a high-performance p-CuZnS/n-TiO2 photodetector, Adv. Mater. 30(43), 1803165 (2018)
3
Zhang D. , Zheng W. , Lin R. , Li Y. , Huang F. . Ultrahigh EQE (15%) solar‐blind UV photovoltaic detector with organic–inorganic heterojunction via dual built‐in fields enhanced photogenerated carrier separation efficiency mechanism. Adv. Funct. Mater., 2019, 29(26): 1900935 https://doi.org/10.1002/adfm.201900935
4
N. Lin C. , J. Lu Y. , Yang X. , Z. Tian Y. , J. Gao C. , L. Sun J. , Dong L. , Zhong F. , D. Hu W. , X. Shan C. . Diamond-based all-carbon photodetectors for solar-blind imaging. Adv. Opt. Mater., 2018, 6(15): 1800068 https://doi.org/10.1002/adom.201800068
5
Yang W. , Hu K. , Teng F. , Weng J. , Zhang Y. , Fang X. . High-performance silicon-compatible large-area UV-to-visible broadband photodetector based on integrated lattice-matched Type II Se/n-Si heterojunctions. Nano Lett., 2018, 18(8): 4697 https://doi.org/10.1021/acs.nanolett.8b00988
6
Zhang Y. , Li S. , Li Z. , Liu H. , Liu X. , Chen J. , Fang X. . High-performance two-dimensional perovskite Ca2Nb3O10 UV photodetectors. Nano Lett., 2021, 21(1): 382 https://doi.org/10.1021/acs.nanolett.0c03759
7
Kumar A. , A. Khan M. , Kumar M. . Recent advances in UV photodetectors based on 2D materials: A review. J. Phys. D Appl. Phys., 2022, 55(13): 133002 https://doi.org/10.1088/1361-6463/ac33d7
8
Cao R. , Zhang Y. , Wang H. , Zeng Y. , Zhao J. , Zhang L. , Li J. , Meng F. , Shi Z. , Fan D. , Guo Z. . Solar-blind deep-ultraviolet photodetectors based on solution-synthesized quasi-2D Te nanosheets. Nanophotonics, 2020, 9(8): 2459 https://doi.org/10.1515/nanoph-2019-0539
9
Zheng W. , Lin R. , Zhang Z. , Huang F. . Vacuum-ultraviolet photodetection in few-layered h-BN. ACS Appl. Mater. Interfaces, 2018, 10(32): 27116 https://doi.org/10.1021/acsami.8b07189
10
Chu J. , Wang F. , Yin L. , Lei L. , Yan C. , Wang F. , Wen Y. , Wang Z. , Jiang C. , Feng L. , Xiong J. , Li Y. , He J. . High-performance ultraviolet photodetector based on a few-layered 2D NiPS3 nanosheet. Adv. Funct. Mater., 2017, 27(32): 1701342 https://doi.org/10.1002/adfm.201701342
11
Y. Kong W. , A. Wu G. , Y. Wang K. , F. Zhang T. , F. Zou Y. , D. Wang D. , B. Luo L. . Graphene-β-Ga2O3 heterojunction for highly sensitive deep UV photodetector application. Adv. Mater., 2016, 28(48): 10725 https://doi.org/10.1002/adma.201604049
12
Li S. , Zhang Y. , Yang W. , Liu H. , Fang X. . 2D perovskite Sr2Nb3O10 for high‐performance UV photodetectors. Adv. Mater., 2020, 32(7): 1905443 https://doi.org/10.1002/adma.201905443
13
K. Lubsandorzhiev B. . On the history of photomultiplier tube invention. Nucl. Instrum. Methods Phys. Res. A, 2006, 567(1): 236 https://doi.org/10.1016/j.nima.2006.05.221
14
Lafuente A. , Abanades A. , T. Leon P. , Sordo F. , M. Martinez-Val J. . Dynamic response of an accelerator driven system to accelerator beam interruptions for criticality. Nucl. Instrum. Methods Phys. Res. A, 2008, 591(2): 327 https://doi.org/10.1016/j.nima.2008.03.003
15
Su L. , Zhang Q. , Wu T. , Chen M. , Su Y. , Zhu Y. , Xiang R. , Gui X. , Tang Z. . High-performance zero-bias ultraviolet photodetector based on p-GaN/n-ZnO heterojunction. Appl. Phys. Lett., 2014, 105(7): 072106 https://doi.org/10.1063/1.4893591
16
Nie B. , G. Hu J. , B. Luo L. , Xie C. , H. Zeng L. , Lv P. , Z. Li F. , S. Jie J. , Feng M. , Y. Wu C. , Q. Yu Y. , H. Yu S. . Monolayer graphene film on ZnO nanorod array for high-performance Schottky junction ultraviolet photodetectors. Small, 2013, 9(17): 2872 https://doi.org/10.1002/smll.201203188
17
Wan X. , Xu Y. , Guo H. , Shehzad K. , Ali A. , Liu Y. , Yang J. , Dai D. , T. Lin C. , Liu L. , C. Cheng H. , Wang F. , Wang X. , Lu H. , Hu W. , Pi X. , Dan Y. , Luo J. , Hasan T. , Duan X. , Li X. , Xu J. , Yang D. , Ren T. , Yu B. . A self-powered high-performance graphene/silicon ultraviolet photodetector with ultra-shallow junction: Breaking the limit of silicon?. npj 2D Mater. Appl., 2017, 1(1): 4 https://doi.org/10.1038/s41699-017-0008-4
18
A. Kang M. , Kim S. , S. Jeon I. , R. Lim Y. , Y. Park C. , Song W. , S. Lee S. , Lim J. , S. An K. , Myung S. . Highly efficient and flexible photodetector based on MoS2–ZnO heterostructures. RSC Adv., 2019, 9(34): 19707 https://doi.org/10.1039/C9RA00578A
19
Li H. , Su S. , Liang C. , Huang M. , Ma X. , Yu G. , Tao H. . Ultraviolet photodetector based on the hybrid graphene/phosphor field-effect transistor. Opt. Mater., 2020, 109: 110439 https://doi.org/10.1016/j.optmat.2020.110439
20
Krishnamurthi V. , X. Low M. , Kuriakose S. , Sriram S. , Bhaskaran M. , Walia S. . Black phosphorus nanoflakes vertically stacked on MoS2 nanoflakes as heterostructures for photodetection. ACS Appl. Nano Mater., 2021, 4(7): 6928 https://doi.org/10.1021/acsanm.1c00972
21
Seo J. , H. Lee J. , Pak J. , Cho K. , K. Kim J. , Kim J. , Jang J. , Ahn H. , C. Lim S. , Chung S. , Kang K. , Lee T. . Ultrasensitive photodetection in MoS2 avalanche phototransistors. Adv. Sci. (Weinh.), 2021, 8(19): 2102437 https://doi.org/10.1002/advs.202102437
P. García de Arquer F. , Armin A. , Meredith P. , H. Sargent E. . Solution-processed semiconductors for next-generation photodetectors. Nat. Rev. Mater., 2017, 2(3): 16100 https://doi.org/10.1038/natrevmats.2016.100
24
Feng J. , Gong C. , Gao H. , Wen W. , Gong Y. , Jiang X. , Zhang B. , Wu Y. , Wu Y. , Fu H. , Jiang L. , Zhang X. . Single-crystalline layered metal-halide perovskite nanowires for ultrasensitive photodetectors. Nat. Electron., 2018, 1(7): 404 https://doi.org/10.1038/s41928-018-0101-5
25
Gong X. , Tong M. , Xia Y. , Cai W. , S. Moon J. , Cao Y. , Yu G. , L. Shieh C. , Nilsson B. , J. Heeger A. . High-detectivity polymer photodetectors with spectral response from 300 nm to 1450 nm. Science, 2009, 325(5948): 1665 https://doi.org/10.1126/science.1176706
26
Konstantatos G. , Badioli M. , Gaudreau L. , Osmond J. , Bernechea M. , P. Garcia de Arquer F. , Gatti F. , H. Koppens F. . Hybrid graphene-quantum dot phototransistors with ultrahigh gain. Nat. Nanotechnol., 2012, 7(6): 363 https://doi.org/10.1038/nnano.2012.60
27
Guo F. , Yang B. , Yuan Y. , Xiao Z. , Dong Q. , Bi Y. , Huang J. . A nanocomposite ultraviolet photodetector based on interfacial trap-controlled charge injection. Nat. Nanotechnol., 2012, 7(12): 798 https://doi.org/10.1038/nnano.2012.187
28
Zhang Y. , J. Hellebusch D. , D. Bronstein N. , Ko C. , F. Ogletree D. , Salmeron M. , P. Alivisatos A. . Ultrasensitive photodetectors exploiting electrostatic trapping and percolation transport. Nat. Commun., 2016, 7(1): 11924 https://doi.org/10.1038/ncomms11924
29
Yang J. , Wang F. , F. Guo J. , R. Wang Y. , X. Jiang C. , H. Li S. , C. Cai Y. , Y. Zhan X. , F. Liu X. , H. Cheng Z. , He J. , X. Wang Z. . Ultrasensitive ferroelectric semiconductor phototransistors for photon‐level detection. Adv. Funct. Mater., 2022, 32(36): 2205468 https://doi.org/10.1002/adfm.202205468
30
X. Hou Y. , Li Y. , C. Zhang Z. , Q. Li J. , H. Qi D. , D. Chen X. , J. Wang J. , W. Yao B. , X. Yu M. , B. Lu T. , Zhang J. . Large-scale and flexible optical synapses for neuromorphic computing and integrated visible information sensing memory processing. ACS Nano, 2021, 15(1): 1497 https://doi.org/10.1021/acsnano.0c08921
31
J. Fuller E. , E. Gabaly F. , Leonard F. , Agarwal S. , J. Plimpton S. , B. Jacobs-Gedrim R. , D. James C. , J. Marinella M. , A. Talin A. . Li-ion synaptic transistor for low power analog computing. Adv. Mater., 2017, 29(4): 1604310 https://doi.org/10.1002/adma.201604310
32
Sun J. , Oh S. , Choi Y. , Seo S. , J. Oh M. , Lee M. , B. Lee W. , J. Yoo P. , H. Cho J. , H. Park J. . Optoelectronic synapse based on IGZO-alkylated graphene oxide hybrid structure. Adv. Funct. Mater., 2018, 28(47): 1804397 https://doi.org/10.1002/adfm.201804397
33
Luo Z. , Wang Z. , Guan Z. , Ma C. , Zhao L. , Liu C. , Sun H. , Wang H. , Lin Y. , Jin X. , Yin Y. , Li X. . High-precision and linear weight updates by subnanosecond pulses in ferroelectric tunnel junction for neuro-inspired computing. Nat. Commun., 2022, 13(1): 699 https://doi.org/10.1038/s41467-022-28303-x
34
Wang S. , Liu L. , Gan L. , Chen H. , Hou X. , Ding Y. , Ma S. , W. Zhang D. , Zhou P. . Two-dimensional ferroelectric channel transistors integrating ultra-fast memory and neural computing. Nat. Commun., 2021, 12(1): 53 https://doi.org/10.1038/s41467-020-20257-2
35
van de Burgt Y. , Lubberman E. , J. Fuller E. , T. Keene S. , C. Faria G. , Agarwal S. , J. Marinella M. , Alec Talin A. , Salleo A. . A non-volatile organic electrochemical device as a low-voltage artificial synapse for neuromorphic computing. Nat. Mater., 2017, 16(4): 414 https://doi.org/10.1038/nmat4856
36
Prezioso M. , Merrikh-Bayat F. , D. Hoskins B. , C. Adam G. , K. Likharev K. , B. Strukov D. . Training and operation of an integrated neuromorphic network based on metal-oxide memristors. Nature, 2015, 521(7550): 61 https://doi.org/10.1038/nature14441
37
B. Strukov D. , S. Snider G. , R. Stewart D. , S. Williams R. . The missing memristor found. Nature, 2008, 453(7191): 80 https://doi.org/10.1038/nature06932
38
Tuma T. , Pantazi A. , Le Gallo M. , Sebastian A. , Eleftheriou E. . Stochastic phase-change neurons. Nat. Nanotechnol., 2016, 11(8): 693 https://doi.org/10.1038/nnano.2016.70
39
Y. Wang C. , J. Liang S. , Wang S. , F. Wang P. , A. Li Z. , R. Wang Z. , Y. Gao A. , Pan C. , Liu C. , Liu J. , F. Yang H. , W. Liu X. , H. Song W. , Wang C. , Cheng B. , M. Wang X. , J. Chen K. , L. Wang Z. , J. Watanabe K. , Taniguchi T. , J. Yang J. , Miao F. . Gate-tunable van der Waals heterostructure for reconfigurable neural network vision sensor. Sci. Adv., 2020, 6(26): eaba6173 https://doi.org/10.1126/sciadv.aba6173
40
Ahmed T. , Tahir M. , X. Low M. , Ren Y. , A. Tawfik S. , L. H. Mayes E. , Kuriakose S. , Nawaz S. , J. S. Spencer M. , Chen H. , Bhaskaran M. , Sriram S. , Walia S. . Fully light-controlled memory and neuromorphic computation in layered black phosphorus. Adv. Mater., 2021, 33(10): 2004207 https://doi.org/10.1002/adma.202004207
41
Y. Wang T. , L. Meng J. , Y. He Z. , Chen L. , Zhu H. , Q. Sun Q. , J. Ding S. , Zhou P. , W. Zhang D. . Ultralow power wearable heterosynapse with photoelectric synergistic modulation. Adv. Sci. (Weinh.), 2020, 7(8): 1903480 https://doi.org/10.1002/advs.201903480
42
Zhou F. , Zhou Z. , Chen J. , H. Choy T. , Wang J. , Zhang N. , Lin Z. , Yu S. , Kang J. , P. Wong H. , Chai Y. . Optoelectronic resistive random access memory for neuromorphic vision sensors. Nat. Nanotechnol., 2019, 14(8): 776 https://doi.org/10.1038/s41565-019-0501-3
43
Wu Q. , Wang J. , Cao J. , Lu C. , Yang G. , Shi X. , Chuai X. , Gong Y. , Su Y. , Zhao Y. , Lu N. , Geng D. , Wang H. , Li L. , Liu M. . Photoelectric plasticity in oxide thin film transistors with tunable synaptic functions. Adv. Electron. Mater., 2018, 4(12): 1800556 https://doi.org/10.1002/aelm.201800556
44
Luo P. , Liu C. , Lin J. , Duan X. , Zhang W. , Ma C. , Lv Y. , Zou X. , Liu Y. , Schwierz F. , Qin W. , Liao L. , He J. , Liu X. . Molybdenum disulfide transistors with enlarged van der Waals gaps at their dielectric interface via oxygen accumulation. Nat. Electron., 2022, 5(12): 849 https://doi.org/10.1038/s41928-022-00877-w
45
Y. Yang J. , J. Yeom M. , Park Y. , Heo J. , Yoo G. . Ferroelectric α‐In2Se3 wrapped‐gate β‐Ga2O3 field‐effect transistors for dynamic threshold voltage control. Adv. Electron. Mater., 2021, 7(8): 2100306 https://doi.org/10.1002/aelm.202100306
46
Cui J. , Wang L. , Du Z. , Ying P. , Deng Y. . High thermoelectric performance of a defect in α-In2Se3-based solid solution upon substitution of Zn for In. J. Mater. Chem. C, 2015, 3(35): 9069 https://doi.org/10.1039/C5TC01977J
47
J. Wang J. , Wang F. , X. Wang Z. , H. Huang W. , Y. Yao Y. , R. Wang Y. , Yang J. , N. Li N. , Yin L. , Q. Cheng R. , Y. Zhan X. , X. Shan C. , He J. . Logic and in-memory computing achieved in a single ferroelectric semiconductor transistor. Sci. Bull. (Beijing), 2021, 66(22): 2288 https://doi.org/10.1016/j.scib.2021.06.020
48
Ding W. , Zhu J. , Wang Z. , Gao Y. , Xiao D. , Gu Y. , Zhang Z. , Zhu W. . Prediction of intrinsic two-dimensional ferroelectrics in In2Se3 and other III2-VI3 van der Waals materials. Nat. Commun., 2017, 8(1): 14956 https://doi.org/10.1038/ncomms14956
49
Zhou Y. , Wu D. , Zhu Y. , Cho Y. , He Q. , Yang X. , Herrera K. , Chu Z. , Han Y. , C. Downer M. , Peng H. , Lai K. . Out-of-plane piezoelectricity and ferroelectricity in layered α-In2Se3 nanoflakes. Nano Lett., 2017, 17(9): 5508 https://doi.org/10.1021/acs.nanolett.7b02198
50
Xue F. , Hu W. , C. Lee K. , S. Lu L. , Zhang J. , L. Tang H. , Han A. , T. Hsu W. , Tu S. , H. Chang W. , H. Lien C. , H. He J. , Zhang Z. , J. Li L. , Zhang X. . Room-temperature ferroelectricity in hexagonally layered α-In2Se3 nanoflakes down to the monolayer limit. Adv. Funct. Mater., 2018, 28(50): 1803738 https://doi.org/10.1002/adfm.201803738
51
Zheng C. , Yu L. , Zhu L. , L. Collins J. , Kim D. , Lou Y. , Xu C. , Li M. , Wei Z. , Zhang Y. , T. Edmonds M. , Li S. , Seidel J. , Zhu Y. , Z. Liu J. , X. Tang W. , S. Fuhrer M. . Room temperature in-plane ferroelectricity in van der Waals In2Se3. Sci. Adv., 2018, 4(7): eaar7720 https://doi.org/10.1126/sciadv.aar7720
52
Zhang Y. , Wang L. , Chen H. , Ma T. , Lu X. , P. Loh K. . Analog and digital mode α‐In2Se3 memristive devices for neuromorphic and memory applications. Adv. Electron. Mater., 2021, 7(12): 2100609 https://doi.org/10.1002/aelm.202100609
53
Si M. , K. Saha A. , Gao S. , Qiu G. , Qin J. , Duan Y. , Jian J. , Niu C. , Wang H. , Wu W. , K. Gupta S. , D. Ye P. . A ferroelectric semiconductor field-effect transistor. Nat. Electron., 2019, 2(12): 580 https://doi.org/10.1038/s41928-019-0338-7
54
Xue F. , He X. , Liu W. , Periyanagounder D. , Zhang C. , Chen M. , H. Lin C. , Luo L. , Yengel E. , Tung V. , D. Anthopoulos T. , J. Li L. , H. He J. , Zhang X. . Optoelectronic ferroelectric domain‐wall memories made from a single van der Waals ferroelectric. Adv. Funct. Mater., 2020, 30(52): 2004206 https://doi.org/10.1002/adfm.202004206
55
Xu K. , Jiang W. , Gao X. , Zhao Z. , Low T. , Zhu W. . Optical control of ferroelectric switching and multifunctional devices based on van der Waals ferroelectric semiconductors. Nanoscale, 2020, 12(46): 23488 https://doi.org/10.1039/D0NR06872A
56
Zhang Y. , Dai J. , Zhong X. , Zhang D. , Zhong G. , Li J. . Probing ultrafast dynamics of ferroelectrics by time-resolved pump-probe spectroscopy. Adv. Sci. (Weinh.), 2021, 8(22): 2102488 https://doi.org/10.1002/advs.202102488
57
Wang H. , Guo J. , Miao J. , Luo W. , Gu Y. , Xie R. , Wang F. , Zhang L. , Wang P. , Hu W. . Emerging single-photon detectors based on low-dimensional materials. Small, 2022, 18(5): 2103963 https://doi.org/10.1002/smll.202103963
58
Han X.Kashif R.Roland V., Fashion-MNIST: A novel image dataset for benchmarking machine learning algorithms, arXiv: 1708.07747 (2017)