|
|
Strategies for discovery and optimization of thermoelectric materials: Role of real objects and local fields |
Hao Zhu, Chong Xiao() |
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science & Technology of China, Hefei 230026, China |
|
|
Abstract Thermoelectric materials provide a renewable and eco-friendly solution to mitigate energy shortages and to reduce environmental pollution via direct heat-to-electricity conversion. Discovery of the novel thermoelectric materials and optimization of the state-of-the-art material systems lie at the core of the thermoelectric society, the basic concept behind these being comprehension and manipulation of the physical principles and transport properties regarding thermoelectric materials. In this mini-review, certain examples for designing high-performance bulk thermoelectric materials are presented from the perspectives of both real objects and local fields. The highlights of this topic involve the Rashba effect, Peierls distortion, local magnetic field, and local stress field, which cover several aspects in the field of thermoelectric research. We conclude with an overview of future developments in thermoelectricity.
|
Keywords
thermoelectric materials
real objects
local fields
|
Corresponding Author(s):
Hao Zhu,Chong Xiao
|
Issue Date: 25 May 2018
|
|
1 |
J. P. Heremans, V. Jovovic, E. S. Toberer, A. Saramat, K. Kurosaki, A. Charoenphakdee, S. Yamanaka, and G. J. Snyder, Enhancement of thermoelectric efficiency in PbTe by distortion of the electronic density of states, Science 321(5888), 554 (2008)
https://doi.org/10.1126/science.1159725
|
2 |
G. Tan, L. D. Zhao, and M. G. Kanatzidis, Rationally designing high-performance bulk thermoelectric materials, Chem. Rev. 116(19), 12123 (2016)
https://doi.org/10.1021/acs.chemrev.6b00255
|
3 |
A. I. Hochbaum, R. Chen, R. D. Delgado, W. Liang, E. C. Garnett, M. Najarian, A. Majumdar, and P. Yang, Enhanced thermoelectric performance of rough silicon nanowires, Nature 451(7175), 163 (2008)
https://doi.org/10.1038/nature06381
|
4 |
A. I. Boukai, Y. Bunimovich, J. Tahir-Kheli, J. K. Yu, III Goddard, and J. R. Heath, Silicon nanowires as efficient thermoelectric materials, Nature 451(7175), 168 (2008)
https://doi.org/10.1038/nature06458
|
5 |
K. Biswas, J. He, I. D. Blum, C. I. Wu, T. P. Hogan, D. N. Seidman, V. P. Dravid, and M. G. Kanatzidis, Highperformance bulk thermoelectrics with all-scale hierarchical architectures, Nature 489(7416), 414 (2012)
https://doi.org/10.1038/nature11439
|
6 |
Y. Wang, N. S. Rogado, R. J. Cava, and N. P. Ong, Spin entropy as the likely source of enhanced thermopower in NaxCo2O4, Nature 423(6938), 425 (2003)
https://doi.org/10.1038/nature01639
|
7 |
T. Zhu, C. Fu, H. Xie, Y. Liu, and X. Zhao, High efficiency half-Heusler thermoelectric materials for energy harvesting, Adv. Energy Mater. 5(19), 1500588 (2015)
https://doi.org/10.1002/aenm.201500588
|
8 |
D. Y. Chung, T. Hogan, P. Brazis, M. Rocci-Lane, C. Kannewurf, M. Bastea, C. Uher, and M. G. Kanatzidis, CsBi4Te6: A high-performance thermoelectric material for low-temperature applications, Science 287(5455), 1024 (2000)
https://doi.org/10.1126/science.287.5455.1024
|
9 |
J. R. Sootsman, D. Y. Chung, and M. G. Kanatzidis, New and old concepts in thermoelectric materials, Angew. Chem. Int. Ed. 48(46), 8616 (2009)
https://doi.org/10.1002/anie.200900598
|
10 |
J. He and T. M. Tritt, Advances in thermoelectric materials research: Looking back and moving forward, Science 357(6358), eaak9997 (2017)
|
11 |
C. Xiao, Z. Li, K. Li, P. Huang, and Y. Xie, Decoupling interrelated parameters for designing high performance thermoelectric materials, Acc. Chem. Res. 47(4), 1287 (2014)
https://doi.org/10.1021/ar400290f
|
12 |
G. J. Snyder and E. S. Toberer, Complex thermoelectric materials, Nat. Mater. 7(2), 105 (2008)
https://doi.org/10.1038/nmat2090
|
13 |
A. M. Dehkordi, M. Zebarjadi, J. He, and T. M. Tritt, Thermoelectric power factor: Enhancement mechanisms and strategies for higher performance thermoelectric materials, Mater. Sci. Eng. R 97, 1 (2015)
https://doi.org/10.1016/j.mser.2015.08.001
|
14 |
X. Shi, L. Chen, and C. Uher, Recent advances in highperformance bulk thermoelectric materials, Int. Mater. Rev. 61(6), 379 (2016)
https://doi.org/10.1080/09506608.2016.1183075
|
15 |
L. D. Zhao, V. P. Dravid, and M. G. Kanatzidis, The panoscopic approach to high performance thermoelectrics, Energy Environ. Sci. 7(1), 251 (2014)
https://doi.org/10.1039/C3EE43099E
|
16 |
E. S. Toberer, A. F. May, and G. J. Snyder, Zintl chemistry for designing high efficiency thermoelectric materials, Chem. Mater. 22(3), 624 (2010)
https://doi.org/10.1021/cm901956r
|
17 |
W. G. Zeier, J. Schmitt, G. Hautier, U. Aydemir, Z. M. Gibbs, C. Felser, and G. J. Snyder, Engineering half- Heusler thermoelectric materials using Zintl chemistry, Nat. Rev. Mater. 1(6), 16032 (2016)
https://doi.org/10.1038/natrevmats.2016.32
|
18 |
R. Venkatasubramanian, Lattice thermal conductivity reduction and phonon localizationlike behavior in superlattice structures, Phys. Rev. B 61(4), 3091 (2000)
https://doi.org/10.1103/PhysRevB.61.3091
|
19 |
S. I. Kim, K. H. Lee, H. A. Mun, H. S. Kim, S. W. Hwang, J. W. Roh, D. J. Yang, W. H. Shin, X. S. Li, Y. H. Lee, G. J. Snyder, and S. W. Kim, Dense dislocation arrays embedded in grain boundaries for highperformance bulk thermoelectrics, Science 348(6230), 109 (2015)
https://doi.org/10.1126/science.aaa4166
|
20 |
X. Shi, J. Yang, J. R. Salvador, M. Chi, J. Y. Cho, H. Wang, S. Bai, J. Yang, W. Zhang, and L. Chen, Multiple-filled skutterudites: High thermoelectric figure of merit through separately optimizing electrical and thermal transports, J. Am. Chem. Soc. 133(20), 7837 (2011)
https://doi.org/10.1021/ja111199y
|
21 |
W. Kim, Strategies for engineering phonon transport in thermoelectrics, J. Mater. Chem. C 3(40), 10336 (2015)
https://doi.org/10.1039/C5TC01670C
|
22 |
Z. Chen, B. Ge, W. Li, S. Lin, J. Shen, Y. Chang, R. Hanus, G. J. Snyder, and Y. Pei, Vacancy-induced dislocations within grains for high-performance PbSe thermoelectrics, Nat. Commun. 8, 13828 (2017)
https://doi.org/10.1038/ncomms13828
|
23 |
Y. Pei, X. Shi, A. LaLonde, H. Wang, L. Chen, and G. J. Snyder, Convergence of electronic bands for high performance bulk thermoelectrics, Nature 473(7345), 66 (2011)
https://doi.org/10.1038/nature09996
|
24 |
L. D. Zhao, G. Tan, S. Hao, J. He, Y. Pei, H. Chi, H. Wang, S. Gong, H. Xu, V. P. Dravid, C. Uher, G. J. Snyder, C. Wolverton, and M. G. Kanatzidis, Ultrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe, Science 351(6269), 141 (2016)
https://doi.org/10.1126/science.aad3749
|
25 |
Y. Tang, Z. M. Gibbs, L. A. Agapito, G. Li, H. S. Kim, M. B. Nardelli, S. Curtarolo, and G. J. Snyder, Convergence of multi-valley bands as the electronic origin of high thermoelectric performance in CoSb3 skutterudites, Nat. Mater. 14(12), 1223 (2015)
https://doi.org/10.1038/nmat4430
|
26 |
K. Biswas, J. He, Q. Zhang, G. Wang, C. Uher, V. P. Dravid, and M. G. Kanatzidis, Strained endotaxial nanostructures with high thermoelectric figure of merit, Nat. Chem. 3(2), 160 (2011)
https://doi.org/10.1038/nchem.955
|
27 |
W. G. Zeier, J. Schmitt, G. Hautier, U. Aydemir, Z. M. Gibbs, C. Felser, and G. J. Snyder, Engineering half- Heusler thermoelectric materials using Zintl chemistry,Nat. Rev. Mater. 1(6), 16032 (2016)
https://doi.org/10.1038/natrevmats.2016.32
|
28 |
W. Liu, X. Tan, K. Yin, H. Liu, X. Tang, J. Shi, Q. Zhang, and C. Uher, Convergence of conduction bands as a means of enhancing thermoelectric performance of n-type Mg2Si1−xSnx solid solutions, Phys. Rev. Lett. 108(16), 166601 (2012)
https://doi.org/10.1103/PhysRevLett.108.166601
|
29 |
H. Wang, Y. Pei, A. D. LaLonde, and G. J. Snyder, Weak electron-phonon coupling contributing to high thermoelectric performance in n-type PbSe, Proc. Natl. Acad. Sci. USA 109(25), 9705 (2012)
https://doi.org/10.1073/pnas.1111419109
|
30 |
Y. Pei, H. Wang, and G. J. Snyder, Band engineering of thermoelectric materials, Adv. Mater. 24(46), 6125 (2012)
https://doi.org/10.1002/adma.201202919
|
31 |
Y. Pei, C. Chang, Z. Wang, M. Yin, M. Wu, G. Tan, H. Wu, Y. Chen, L. Zheng, S. Gong, T. Zhu, X. Zhao, L. Huang, J. He, M. G. Kanatzidis, and L. D. Zhao, Multiple converged conduction bands in K2Bi8Se13: A promising thermoelectric material with extremely low thermal conductivity, J. Am. Chem. Soc. 138(50), 16364 (2016)
https://doi.org/10.1021/jacs.6b09568
|
32 |
H. Liu, X. Shi, F. Xu, L. Zhang, W. Zhang, L. Chen, Q. Li, C. Uher, T. Day, and G. J. Snyder, Copper ion liquid-like thermoelectrics, Nat. Mater. 11(5), 422 (2012)
https://doi.org/10.1038/nmat3273
|
33 |
C. W. Li, J. Hong, A. F. May, D. Bansal, S. Chi, T. Hong, G. Ehlers, and O. Delaire, Orbitally driven giant phonon anharmonicity in SnSe, Nat. Phys. 11(12), 1063 (2015)
|
34 |
G. J. Snyder, M. Christensen, E. Nishibori, T. Caillat, and B. B. Iversen, Disordered zinc in Zn4Sb3 with phonon-glass and electron-crystal thermoelectric properties, Nat. Mater. 3(7), 458 (2004)
https://doi.org/10.1038/nmat1154
|
35 |
M. Christensen, A. B. Abrahamsen, N. B. Christensen, F. Juranyi, N. H. Andersen, K. Lefmann, J. Andreasson, C. R. H. Bahl, and B. B. Iversen, Avoided crossing of rattler modes in thermoelectric materials, Nat. Mater. 7(10), 811 (2008)
https://doi.org/10.1038/nmat2273
|
36 |
O. Delaire, J. Ma, K. Marty, A. F. May, M. A. McGuire, M. H. Du, D. J. Singh, A. Podlesnyak, G. Ehlers, M. D. Lumsden, and B. C. Sales, Giant anharmonic phonon scattering in PbTe, Nat. Mater. 10(8), 614 (2011)
https://doi.org/10.1038/nmat3035
|
37 |
W. Zhao, P. Wei, Q. Zhang, H. Peng, W. Zhu, D. Tang, J. Yu, H. Zhou, Z. Liu, X. Mu, D. He, J. Li, C. Wang, X. Tang, and J. Yang, Multi-localization transport behaviour in bulk thermoelectric materials, Nat. Commun. 6(1), 6197 (2015)
https://doi.org/10.1038/ncomms7197
|
38 |
Z. Li, C. Xiao, H. Zhu, and Y. Xie, Defect chemistry for thermoelectric materials, J. Am. Chem. Soc. 138(45), 14810 (2016)
https://doi.org/10.1021/jacs.6b08748
|
39 |
T. Zhu, L. Hu, X. Zhao, and J. He, New insights into intrinsic point defects in V2VI3 thermoelectric materials, Adv. Sci. 3(7), 1600004 (2016)
https://doi.org/10.1002/advs.201600004
|
40 |
C. Xiao, J. Xu, B. Cao, K. Li, M. Kong, and Y. Xie, Solid-solutioned homojunction nanoplates with disordered lattice: A promising approach toward “phonon glass electron crystal” thermoelectric materials, J. Am. Chem. Soc. 134(18), 7971 (2012)
https://doi.org/10.1021/ja3020204
|
41 |
L. E. Bell, Cooling, heating, generating power, and recovering waste heat with thermoelectric systems, Science 321(5895), 1457 (2008)
https://doi.org/10.1126/science.1158899
|
42 |
P. Gorai, V. Stevanović, and E. S. Toberer, Computationally guided discovery of thermoelectric materials, Nat. Rev. Mater. 2(9), 17053 (2017)
https://doi.org/10.1038/natrevmats.2017.53
|
43 |
J. P. Heremans, R. J. Cava, and N. Samarth, Tetradymites as thermoelectrics and topological insulators, Nat. Rev. Mater. 2(10), 17049 (2017)
https://doi.org/10.1038/natrevmats.2017.49
|
44 |
J. Ravichandran, Thermoelectric and thermal transport properties of complex oxide thin films, heterostructures and superlattices, J. Mater. Res. 32(01), 183 (2017)
https://doi.org/10.1557/jmr.2016.419
|
45 |
X. Wang, P. Wang, J. Wang, W. Hu, X. Zhou, N. Guo, H. Huang, S. Sun, H. Shen, T. Lin, M. Tang, L. Liao, A. Jiang, J. Sun, X. Meng, X. Chen, W. Lu, and J. Chu, Ultrasensitive and broadband MoS2 photodetector driven by ferroelectrics, Adv. Mater. 27(42), 6575 (2015)
https://doi.org/10.1002/adma.201503340
|
46 |
W. Ren, H. Geng, Z. Zhang, and L. Zhang, Fillingfraction fluctuation leading to glasslike ultralow thermal conductivity in caged skutterudites, Phys. Rev. Lett. 118(24), 245901 (2017)
https://doi.org/10.1103/PhysRevLett.118.245901
|
47 |
E. Cappelluti, C. Grimaldi, and F. Marsiglio, Topological change of the Fermi surface in low-density rashba gases: Application to superconductivity, Phys. Rev. Lett. 98(16), 167002 (2007)
https://doi.org/10.1103/PhysRevLett.98.167002
|
48 |
R. Winkler, S. J. Papadakis, E. P. Poortere, and M. Shayegan, Spin-orbit coupling in two-dimensional electron and hole systems, Adv. Solid State Phys. 41, 211 (2003)
https://doi.org/10.1007/3-540-44946-9_18
|
49 |
K. Ishizaka, M. S. Bahramy, H. Murakawa, M. Sakano, T. Shimojima, T. Sonobe, K. Koizumi, S. Shin, H. Miyahara, A. Kimura, K. Miyamoto, T. Okuda, H. Namatame, M. Taniguchi, R. Arita, N. Nagaosa, K. Kobayashi, Y. Murakami, R. Kumai, Y. Kaneko, Y. Onose, and Y. Tokura, Giant Rashba-type spin splitting in bulk BiTeI, Nat. Mater. 10(7), 521 (2011)
https://doi.org/10.1038/nmat3051
|
50 |
M. Sakano, M. S. Bahramy, A. Katayama, T. Shimojima, H. Murakawa, Y. Kaneko, W. Malaeb, S. Shin, K. Ono, H. Kumigashira, R. Arita, N. Nagaosa, H. Y. Hwang, Y. Tokura, and K. Ishizaka, Strongly spinorbit coupled two-dimensional electron gas emerging near the surface of polar semiconductors, Phys. Rev. Lett. 110(10), 107204 (2013)
https://doi.org/10.1103/PhysRevLett.110.107204
|
51 |
H. Murakawa, M. S. Bahramy, M. Tokunaga, Y. Kohama, C. Bell, Y. Kaneko, N. Nagaosa, H. Y. Hwang, and Y. Tokura, Detection of Berry’s phase in a bulk Rashba semiconductor, Science 342(6165), 1490 (2013)
https://doi.org/10.1126/science.1242247
|
52 |
S. Brown and G. Grüner, Charge and spin density waves, Sci. Am. 270(4), 50 (1994)
https://doi.org/10.1038/scientificamerican0494-50
|
53 |
J. S. Rhyee, K. H. Lee, S. M. Lee, E. Cho, S. I. Kim, E. Lee, Y. S. Kwon, J. H. Shim, and G. Kotliar, Peierls distortion as a route to high thermoelectric performance in In4Se3−dcrystals, Nature 459(7249), 965 (2009)
https://doi.org/10.1038/nature08088
|
54 |
W. G. Zeier, A. Zevalkink, Z. M. Gibbs, G. Hautier, M. G. Kanatzidis, and G. J. Snyder, Thinking like a chemist: Intuition in thermoelectric materials, Angew. Chem. Int. Ed. 55(24), 6826 (2016)
https://doi.org/10.1002/anie.201508381
|
55 |
H. Wang, J. Wang, X. Cao, and G. J. Snyder, Thermoelectric alloys between PbSe and PbS with effective thermal conductivity reduction and high figure of merit, J. Mater. Chem. A 2(9), 3169 (2014)
https://doi.org/10.1039/c3ta14929c
|
56 |
W. Zhao, Z. Liu, P. Wei, Q. Zhang, W. Zhu, X. Su, X. Tang, J. Yang, Y. Liu, J. Shi, Y. Chao, S. Lin, and Y. Pei, Magnetoelectric interaction and transport behaviours in magnetic nanocomposite thermoelectric materials, Nat. Nanotechnol. 12(1), 55 (2016)
https://doi.org/10.1038/nnano.2016.182
|
57 |
W. Zhao, Z. Liu, Z. Sun, Q. Zhang, P. Wei, X. Mu, H. Zhou, C. Li, S. Ma, D. He, P. Ji, W. Zhu, X. Nie, X. Su, X. Tang, B. Shen, X. Dong, J. Yang, Y. Liu, and J. Shi, Superparamagnetic enhancement of thermoelectric performance, Nature 549(7671), 247 (2017)
https://doi.org/10.1038/nature23667
|
58 |
J. Zhang, L. Song, G. K. H. Madsen, K. F. F. Fischer, W. Zhang, X. Shi, and B. B. Iversen, Designing highperformance layered thermoelectric materials through orbital engineering, Nat. Commun. 7, 10892 (2016)
https://doi.org/10.1038/ncomms10892
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|