Study on a green synthesis of <italic>μ</italic>-oxo-bis[tetraarylphenylporphyrinatoiron]

doi:10.1007/s11705-009-0058-z

Front Chem Eng Chin

2009, Vol. 3

Issue (2) : 219-221 https://doi.org/10.1007/s11705-009-0058-z

RESEARCH ARTICLE

Study on a green synthesis of μ-oxo-bis[tetraarylphenylporphyrinatoiron]

Aixin WANG, Yuanbin SHE(

), Jing FAN

Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing 100124, China

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Abstract

A novel method for the synthesis of μ-oxo-bis[tetraarylporphyrinatoiron] ([TRPPFe]₂O) based on the reaction between tetraarylporphyrinironchloride (TRPPFeCl) and H₂O in toluene was investigated in this paper. Three kinds of [TRPPFe]₂O were synthesized by this novel synthetic method, and their structures were characterized by elemental analysis, IR spectra and UV-Vis spectroscopy.

Keywords μ-oxo-bis[tetraarylphenylporphinatoiron] green synthesis water

Corresponding Author(s): SHE Yuanbin,Email:sheyb@bjut.edu.cn

Issue Date: 05 June 2009

Cite this article:

Aixin WANG,Yuanbin SHE,Jing FAN. Study on a green synthesis of μ-oxo-bis[tetraarylphenylporphyrinatoiron][J]. Front Chem Eng Chin, 2009, 3(2): 219-221.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-009-0058-z
https://academic.hep.com.cn/fcse/EN/Y2009/V3/I2/219

Fig.1 Structures of three of [TRPPFe]O
1 R = R = H, [TPPFe]O; 2 R = CH, R = H, [T(-CH)PPFe]O; 3 R = H, R = Cl, [T(-Cl)PPFe]O

Tab.1 Data of UV-Vis spectra, elemental analysis and IR of [TRPPFe]O

Fig.2 IR spectra of TPPFeCl and [TPPFe]O

Fig.3 UV-Vis spectra of TPPFeCl and [TPPFe]O

Fig.4

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