Polyaniline–polypyrrole nanocomposites using a green and porous wood as support for supercapacitors

doi:10.15302/J-FASE-2019257

Front. Agr. Sci. Eng.

2019, Vol. 6

Issue (2) : 137-143 https://doi.org/10.15302/J-FASE-2019257

RESEARCH ARTICLE

Polyaniline–polypyrrole nanocomposites using a green and porous wood as support for supercapacitors

Jian LI(

), Yue JIAO

Material Science and Engineering College, Northeast Forestry University, Harbin 150040, China

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Abstract

Wood is an ideal type of support material whose porous structure and surface functional groups are beneficial for deposition of various guest substances for different applications. In this paper, wood is employed as a porous support, combined with two kinds of conductive polymers (i.e., polyaniline (PANI) and polypyrrole (PPy)) using an easy and fast liquid polymerization method. Scanning electron microscope observations indicate that the PANI–PPy complex consists of nanoparticles with a size of ~20 nm. The interactions between oxygen-containing groups of the wood and the nitrogen composition of PANI–PPy were verified by Fourier transform infrared spectroscopy. The self-supported PANI–PPy/wood composite is capable of acting as a free-standing supercapacitor electrode, which delivers a high gravimetric specific capacitance of 360 F·g⁻¹ at 0.2 A·g⁻¹.

Keywords wood polypyrrole polyaniline supercapacitors nanocomposites

Corresponding Author(s): Jian LI

Just Accepted Date: 27 March 2019 Online First Date: 26 April 2019 Issue Date: 22 May 2019

Cite this article:

Jian LI,Yue JIAO. Polyaniline–polypyrrole nanocomposites using a green and porous wood as support for supercapacitors[J]. Front. Agr. Sci. Eng. , 2019, 6(2): 137-143.

URL:

https://academic.hep.com.cn/fase/EN/10.15302/J-FASE-2019257
https://academic.hep.com.cn/fase/EN/Y2019/V6/I2/137

Fig.1 Schematic diagram for the synthesis of PANI?PPy/wood

Fig.2 SEM images of the wood support (a) and PANI?PPy/wood (b, c); (d) EDX patterns of the wood support and PANI?PPy/wood.

Fig.3 FTIR spectra of the wood support and PANI?PPy/wood

Fig.4 CV curves of the PANI?PPy/wood electrode at different scan rates

Fig.5 GCD curves of the PANI?PPy/wood electrode at different current densities

Fig.6 Gravimetric specific capacitances of the PANI?PPy/wood electrode at different current densities

Fig.7 Nyquist plots of the PANI?PPy/wood electrode

1	GWang, L Zhang, JZhang. A review of electrode materials for electrochemical supercapacitors. Chemical Society Reviews, 2012, 41(2): 797–828 https://doi.org/10.1039/C1CS15060J pmid: 21779609
2	CDu, N Pan. High power density supercapacitor electrodes of carbon nanotube films by electrophoretic deposition. Nanotechnology, 2006, 17(21): 5314–5318 https://doi.org/10.1088/0957-4484/17/21/005
3	JYan, Z Fan, TWei, WQian, M Zhang, FWei. Fast and reversible surface redox reaction of graphene–MnO2 composites as supercapacitor electrodes. Carbon, 2010, 48(13): 3825–3833 https://doi.org/10.1016/j.carbon.2010.06.047
4	C CHu, J C Chen, K H Chang. Cathodic deposition of Ni(OH)2 and Co(OH)2 for asymmetric supercapacitors: importance of the electrochemical reversibility of redox couples. Journal of Power Sources, 2013, 221: 128–133 https://doi.org/10.1016/j.jpowsour.2012.07.111
5	CWan, Y Jiao, JLi. A cellulose fibers-supported hierarchical forest-like cuprous oxide/copper array architecture as a flexible and free-standing electrode for symmetric supercapacitors. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2017, 5(33): 17267–17278 https://doi.org/10.1039/C7TA04994C
6	KHung, C Masarapu, TKo, BWei. Wide-temperature range operation supercapacitors from nanostructured activated carbon fabric. Journal of Power Sources, 2009, 193(2): 944–949 https://doi.org/10.1016/j.jpowsour.2009.01.083
7	MZhi, C Xiang, JLi, MLi, N Wu. Nanostructured carbon-metal oxide composite electrodes for supercapacitors: a review. Nanoscale, 2013, 5(1): 72–88 https://doi.org/10.1039/C2NR32040A pmid: 23151936
8	CZhong, Y Deng, WHu, JQiao, L Zhang, JZhang, JQiao, L Zhang, JZhang. A review of electrolyte materials and compositions for electrochemical supercapacitors. Chemical Society Reviews, 2015, 44(21): 7484–7539 https://doi.org/10.1039/C5CS00303B pmid: 26050756
9	G ASnook, P Kao, A SBest. Conducting-polymer-based supercapacitor devices and electrodes. Journal of Power Sources, 2011, 196(1): 1–12 https://doi.org/10.1016/j.jpowsour.2010.06.084
10	JZhang, X S Zhao. Conducting polymers directly coated on reduced graphene oxide sheets as high-performance supercapacitor electrodes. Journal of Physical Chemistry C, 2012, 116(9): 5420–5426 https://doi.org/10.1021/jp211474e
11	CWan, Y Jiao, JLi. Flexible, highly conductive, and free-standing reduced graphene oxide/polypyrrole/cellulose hybrid papers for supercapacitor electrodes. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2017, 5(8): 3819–3831 https://doi.org/10.1039/C6TA04844G
12	CWan, J Li. Wood-derived biochar supported polypyrrole nanoparticles as a free-standing supercapacitor electrode. RSC Advances, 2016, 6(89): 86006–86011 https://doi.org/10.1039/C6RA17044G
13	JLi, W Lu, YYan, T WChou. High performance solid-state flexible supercapacitor based on Fe3O4/carbon nanotube/polyaniline ternary films. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2017, 5(22): 11271–11277 https://doi.org/10.1039/C7TA02008B
14	CWan, J Li. Synthesis and electromagnetic interference shielding of cellulose-derived carbon aerogels functionalized with α-Fe2O3 and polypyrrole. Carbohydrate Polymers, 2017, 161: 158–165 https://doi.org/10.1016/j.carbpol.2017.01.003 pmid: 28189223
15	JTian, D Peng, XWu, WLi, H Deng, SLiu. Electrodeposition of Ag nanoparticles on conductive polyaniline/cellulose aerogels with increased synergistic effect for energy storage. Carbohydrate Polymers, 2017, 156: 19–25 https://doi.org/10.1016/j.carbpol.2016.09.005 pmid: 27842813
16	Y ZZhang, Y Wang, TCheng, W YLai, HPang, W Huang. Flexible supercapacitors based on paper substrates: a new paradigm for low-cost energy storage. Chemical Society Reviews, 2015, 44(15): 5181–5199 https://doi.org/10.1039/C5CS00174A pmid: 25951808
17	CWan, Y Lu, QSun, JLi. Hydrothermal synthesis of zirconium dioxide coating on the surface of wood with improved UV resistance. Applied Surface Science, 2014, 321: 38–42 https://doi.org/10.1016/j.apsusc.2014.09.135
18	CWan, Y Jiao, JLi. In situ deposition of graphene nanosheets on wood surface by one-pot hydrothermal method for enhanced UV-resistant ability. Applied Surface Science, 2015, 347: 891–897 https://doi.org/10.1016/j.apsusc.2015.04.178
19	RBana, A K Banthia. Green composites: development of poly(vinyl alcohol)-wood dust composites. Polymer-Plastics Technology and Engineering, 2007, 46(9): 821–829 https://doi.org/10.1080/03602550701278079
20	CChen, Y Zhang, YLi, JDai, J Song, YYao, YGong, I Kierzewski, JXie, LHu. All-wood, low tortuosity, aqueous, biodegradable supercapacitors with ultra-high capacitance. Energy & Environmental Science, 2017, 10(2): 538–545 https://doi.org/10.1039/C6EE03716J
21	YJiao, C Wan, JLi. Scalable synthesis and characterization of free-standing supercapacitor electrode using natural wood as a green substrate to support rod-shaped polyaniline. Journal of Materials Science Materials in Electronics, 2017, 28(3): 2634–2641 https://doi.org/10.1007/s10854-016-5840-3
22	CWan, Y Lu, YJiao, CJin, Q Sun, JLi. Ultralight and hydrophobic nanofibrillated cellulose aerogels from coconut shell with ultrastrong adsorption properties. Journal of Applied Polymer Science, 2015, 132(24): 42037 https://doi.org/10.1002/app.42037
23	B FTjeerdsma, HMilitz. Chemical changes in hydrothermal treated wood: FTIR analysis of combined hydrothermal and dry heat-treated wood. Holz als Roh- und Werkstoff, 2005, 63(2): 102–111 https://doi.org/10.1007/s00107-004-0532-8
24	S YOh, D I Yoo, Y Shin, GSeo. FTIR analysis of cellulose treated with sodium hydroxide and carbon dioxide. Carbohydrate Research, 2005, 340(3): 417–428 https://doi.org/10.1016/j.carres.2004.11.027 pmid: 15680597
25	JXu, L Zhu, ZBai, GLiang, LLiu, D Fang, WXu. Conductive polypyrrole–bacterial cellulose nanocomposite membranes as flexible supercapacitor electrode. Organic Electronics, 2013, 14(12): 3331–3338 https://doi.org/10.1016/j.orgel.2013.09.042
26	JXu, Y Zhang, DZhang, YTang, H Cang. Electrosynthesis of PANI/PPy coatings doped by phosphotungstate on mild steel and their corrosion resistances. Progress in Organic Coatings, 2015, 88: 84–91 https://doi.org/10.1016/j.porgcoat.2015.06.024
27	CWan, J Yue, LJian. Core–shell composite of wood-derived biochar supported MnO2 nanosheets for supercapacitor applications. RSC Advances, 2016, 6(69): 64811–64817 https://doi.org/10.1039/C6RA12043A
28	HWang, L Bian, PZhou, JTang, W Tang. Core–sheath structured bacterial cellulose/polypyrrole nanocomposites with excellent conductivity as supercapacitors. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2013, 1(3): 578–584 https://doi.org/10.1039/C2TA00040G
29	HWang, E Zhu, JYang, PZhou, D Sun, WTang. Bacterial cellulose nanofiber-supported polyaniline nanocomposites with flake-shaped morphology as supercapacitor electrodes. Journal of Physical Chemistry C, 2012, 116(24): 13013–13019 https://doi.org/10.1021/jp301099r
30	HChen, J Jiang, LZhang, HWan, T Qi, DXia. Highly conductive NiCo2S4 urchin-like nanostructures for high-rate pseudocapacitors. Nanoscale, 2013, 5(19): 8879–8883 https://doi.org/10.1039/c3nr02958a pmid: 23903234
31	TZhao, H Jiang, JMa. Surfactant-assisted electrochemical deposition of α-cobalt hydroxide for supercapacitors. Journal of Power Sources, 2011, 196(2): 860–864 https://doi.org/10.1016/j.jpowsour.2010.06.042

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