Pt–C interactions in carbon-supported Pt-based electrocatalysts

doi:10.1007/s11705-023-2300-5

Front. Chem. Sci. Eng.

2023, Vol. 17

Issue (11) : 1677-1697 https://doi.org/10.1007/s11705-023-2300-5

REVIEW ARTICLE

Pt–C interactions in carbon-supported Pt-based electrocatalysts

Yu-Xuan Xiao¹, Jie Ying¹(

), Hong-Wei Liu¹, Xiao-Yu Yang²(

)

¹. School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, China
². State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & Shenzhen Research Institute & Joint Laboratory for Marine Advanced Materials in Pilot National Laboratory for Marine Science and Technology (Qingdao), Wuhan University of Technology, Wuhan 430070, China

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Abstract

Carbon-supported Pt-based materials are highly promising electrocatalysts. The carbon support plays an important role in the Pt-based catalysts by remarkably influencing the growth, particle size, morphology, dispersion, electronic structure, physiochemical property and function of Pt. This review summarizes recent progress made in the development of carbon-supported Pt-based catalysts, with special emphasis being given to how activity and stability enhancements are related to Pt–C interactions in various carbon supports, including porous carbon, heteroatom doped carbon, carbon-based binary support, and their corresponding electrocatalytic applications. Finally, the current challenges and future prospects in the development of carbon-supported Pt-based catalysts are discussed.

Keywords Pt–C interactions Pt-based materials carbon support electrocatalysis

Corresponding Author(s): Jie Ying,Xiao-Yu Yang

About author:

Peng Lei and Charity Ngina Mwangi contributed equally to this work.

Online First Date: 25 April 2023 Issue Date: 25 October 2023

Cite this article:

Yu-Xuan Xiao,Jie Ying,Hong-Wei Liu, et al. Pt–C interactions in carbon-supported Pt-based electrocatalysts[J]. Front. Chem. Sci. Eng., 2023, 17(11): 1677-1697.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-023-2300-5
https://academic.hep.com.cn/fcse/EN/Y2023/V17/I11/1677

Fig.1 Diagram outlining the different Pt–C interactions brought about by different carbon supports.

Tab.1 A summary of the pore size of carbon materials synthesized by different methods

Fig.2 Pt-based nanoparticles supported in OMC with (a) hierarchically hollow straight mesopores in thick wall, (b) hierarchically hollow straight mesopores in thin wall, (c) interacted mesopores, and (d) straight mesopores. Reprinted with permission from Ref. [72], copyright 2020, Wiley-VCH, Ref. [73], copyright 2021, Wiley-VCH, Ref. [74], copyright 2014, Elsevier, and Ref. [75], copyright 2016, Royal Society of Chemistry.

Fig.3 Pt-based nanoparticles supported in/on MOFs-derived porous carbon. (a) Hollow PtCo and Pt single atoms encapsulated in MOFs-derived carbon shells. Reprinted with permission from Ref. [78], copyright 2018, American Chemical Society. (b) Pt nanoparticles supported on MOFs-derived porous carbon. Reprinted with permission from Ref. [79], copyright 2018, American Chemical Society. (c) Pt nanoparticles embedded in MOFs-derived hierarchically hollow porous carbon. Reprinted with permission from Ref. [80], copyright 2017, Elsevier. (d) PtCo and Co nanoparticles embedded in MOFs-derived hierarchically hollow porous carbon. Reprinted with permission from Ref. [81], copyright 2018, Elsevier.

Fig.4 Pt-based nanoparticles supported on 3D porous carbon of (a) CNT arrays, (b) CNT aerogels, (c) 3D carbon foam, and (d) OMC films. Reprinted with permission from Ref. [83], copyright 2011, Wiley-VCH, Ref. [84], copyright 2016, American Chemical Society, Ref. [85], copyright 2020, Elsevier, and Ref. [86], copyright 2021, Royal Society of Chemistry.

Fig.5 (a) Illustration of the pathway for direct N doping of a carbon support derived from MOFs. (b–d) Morphology characterization of the samples. (e) Illustration of the defects and vacancies. Reprinted with permission from Ref. [78], copyright 2018, American Chemical Society.

Fig.7 Pt-based nanoparticles supported on (a) 0D/0D, (b) 0D/1D, (c) 0D/2D, and (d) 1D/2D carbon/carbon binary supports. Reprinted with permission from Ref. [122], copyright 2022, American Chemical Society, Ref. [123], copyright 2017, American Chemical Society, Ref. [127], copyright 2020, Elsevier, and Ref. [128], copyright 2018, American Chemical Society.

Fig.8 Pt-based nanoparticles supported on (a) carbon/SiO₂, (b) carbon/TiO₂, (c) carbon/NiO_x, and (d) carbon/TaO_x binary supports. Reprinted with permission from Ref. [134], copyright 2021, Elsevier, Ref. [136], copyright 2022, American Chemical Society, Ref. [137], copyright 2017, Elsevier, and Ref. [139], copyright 2017, American Chemical Society.

Fig.9 Pt-based nanoparticles supported on (a) carbon/polyaniline, (b) carbon/5,10,15,20-tetrakis(1-methyl-4-pyridinio)porphyrin tetra(p-toluenesulfonate), (c) carbon/polyindole, and (d) carbon/ZIF-8 binary supports. Reprinted with permission from Ref. [141], copyright 2011, American Chemical Society, Ref. [143], copyright 2014, Royal Society of Chemistry, Ref. [144], copyright 2015, Elsevier, and Ref. [145], copyright 2019, American Chemical Society.

Fig.10 (a) ORR polarization curves and (b) corresponding specific activities of PtPd/CNF, PtPd/a-CNF, PtPd/CNF-EG, PtPd/ACNF, and commercial Pt/C. Reprinted with permission from Ref. [147], copyright 2019, Elsevier. (c) HER polarization curves of Pt₁/NMHCS, PtNP/MHCS, NMHCS, Pt wire and 20 wt % Pt/C. (d) Corresponding mass activities and overpotential of Pt₁/NMHCS, PtNP/MHCS and 20 wt % Pt/C. Reprinted with permission from Ref. [111], copyright 2019, Wiley-VCH. (e) FAOR cyclic voltammetry curves and (f) corresponding mass activities of Pt-Au/C and Pt/C. Reprinted with permission from Ref. [113], copyright 2018, Elsevier.

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