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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

Postal Subscription Code 80-969

2018 Impact Factor: 2.809

Front. Chem. Sci. Eng.    2024, Vol. 18 Issue (7) : 81    https://doi.org/10.1007/s11705-024-2436-y
Microwave-assisted pyrolysis of plastics for aviation oil production: energy and economic analyses
Sichen Fan1, Yifan Liu1, Yaning Zhang1(), Wenke Zhao1, Chunbao Xu2()
1. School of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, China
2. School of Energy and Environment, City University of Hong Kong, Hong Kong SAR, China
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Abstract

Microwave-assisted pyrolysis is an effective method for recycling plastic wastes into oils that can be used for aviation fuels. In this study, energy and economic analyses of aviation oil production from microwave-assisted pyrolysis of polystyrene were performed. The total energy efficiency, recovered energy efficiency, unitary cost, unitary energy economic cost, relative cost difference, and energy economic factor were detailed. And the effects of microwave power, pyrolysis temperature, microwave absorbent loading, and microwave absorbent type on these parameters were covered. It was found that pyrolysis temperature has the most significant effect on the unitary cost and unitary energy economic cost of aviation oil, and-microwave absorbent type has a significant influence on energy economic factor during the whole microwave-assisted pyrolysis process. The optimum reaction conditions at the tonnage system for pyrolysis of 1 t polystyrene were microwave power of 650 W, pyrolysis temperature of 460 °C, and silicon carbide (microwave absorbent) at a loading of 2 t (twice than feedstock loading). At these optimal conditions, the total energy efficiency, recovered energy efficiency, unitary cost, unitary energy economic cost, relative cost difference, and energy economic factor were 62.78%, 96.51%, 3.21 × 104 yuan·t–1, 779 yuan·GJ–1, 1.49, and 71.02%, respectively.

Keywords energy analysis      economic analysis      microwave-assisted pyrolysis      polystyrene      aviation oil     
Corresponding Author(s): Yaning Zhang,Chunbao Xu   
Just Accepted Date: 12 March 2024   Issue Date: 27 May 2024
 Cite this article:   
Sichen Fan,Yifan Liu,Yaning Zhang, et al. Microwave-assisted pyrolysis of plastics for aviation oil production: energy and economic analyses[J]. Front. Chem. Sci. Eng., 2024, 18(7): 81.
 URL:  
https://academic.hep.com.cn/fcse/EN/10.1007/s11705-024-2436-y
https://academic.hep.com.cn/fcse/EN/Y2024/V18/I7/81
Fig.1  Input and output stream processes in the MAP system (MA represents microwave absorbent).
ParameterDataUnitRemarks
PS cost10000yuan·t–1According to the price of recycled PS in the market
Electricity cost0.51yuan·kW–1·h–1The electric charge standard in Harbin City, Heilongjiang Province, China
Tonnage microwave oven price3000000yuanThe quoted price according to evaluation by the manufacturer
Interest rate2.75%Interest rate in China (year 2023)
Number of annual batches3500Calculated based on 10 batch production per day (350 days)
Microwave oven lifespan8yearAssumption
Tab.1  Parameters involved in energy economic analysis
Microwave power/WHHVoil/(GJ·t–1)Qoil/GJQPS/GJQelectricity/GJQinput/GJ
45041.5235.0242.2228.8071.02
55041.7838.2142.2224.6066.82
65041.2540.7542.2222.6864.90
75041.3537.2642.2220.1662.38
85041.3336.2542.2223.2865.50
Tab.2  Energy analysis at different microwave powers
Fig.2  Energy efficiencies at different microwave powers.
Microwave power/WUCoil/(yuan·t–1)CED/yuanfEC%rEC
4503.87 × 1041.20 × 10460.681.79
5503.50 × 1049.14 × 10366.971.62
6503.21 × 1047.56 × 10371.021.49
7503.48 × 1047.65 × 10370.781.77
8503.59 × 1049.09 × 10367.091.76
Tab.3  Energy economic analysis at different microwave powers
Fig.3  Unitary energy economic cost and relative cost difference at different microwave powers.
Pyrolysis temperature/°CHHVoil/(GJ·t–1)Qoil/GJQPS/GJQelectricity/GJQinput/GJ
34042.1723.6242.2227.3669.58
40041.2933.1742.2221.6063.82
46041.2540.7542.2222.6864.90
52040.8337.2042.2221.3663.58
58041.1734.9042.2221.7263.94
Tab.4  Energy analysis at different pyrolysis temperatures
Fig.4  Energy efficiencies at different pyrolysis temperatures.
Pyrolysis temperature/°CUCoil/(yuan·t–1)CED/yuanfEC/%rEC
3405.79 × 1041.51 × 10455.093.18
4003.93 × 1049.48 × 10366.152.08
4603.21 × 1047.56 × 10371.021.49
5203.46 × 1048.14 × 10369.481.75
5803.73 × 1048.99 × 10367.321.92
Tab.5  Energy economic analysis at different pyrolysis temperatures
Fig.5  Unitary energy economic cost and relative cost difference at different pyrolysis temperatures.
Microwave absorbent loading/tHHVoil/(GJ·t–1)Qoil/GJQPS/GJQelectricity/GJQinput/GJ
1.040.9533.7642.2224.1266.34
1.541.4538.1342.2222.6864.90
2.041.2540.7542.2222.6864.90
2.541.6938.7342.2225.6867.90
3.041.9935.8342.2230.0072.22
Tab.6  Energy analysis at different microwave absorbent loadings
Fig.6  Energy efficiencies at different microwave absorbent loadings.
Microwave absorbent loading/tUCoil/(yuan·t–1)CED/yuanfEC/%rEC
1.03.87 × 1041.04 × 10464.151.98
1.53.45 × 1048.38 × 10368.871.66
2.03.21 × 1047.56 × 10371.021.49
2.53.46 × 1049.42 × 10366.291.57
3.03.84 × 1041.23 × 10460.141.71
Tab.7  Energy economic analysis at different microwave absorbent loadings
Fig.7  Unitary energy economic cost and relative cost difference at different microwave absorbent loadings.
Fig.8  Energy efficiencies at different microwave absorbent types.
Microwave absorbent typeHHVoil/(GJ·t–1)Qoil/GJQPS/GJQelectricity/GJQinput/GJ
Fe41.3338.0742.2295.88138.10
Fe3O441.4539.4242.2243.8086.02
FeS240.2337.2842.2242.5184.73
SiC41.2540.7542.2222.6864.90
Tab.8  Energy analysis at different microwave absorbent types
Microwave absorbent typeUCoil/(yuan·t–1)CED/yuanfEC/%rEC
Fe1.52 × 1057.08 × 10420.755.60
Fe3O41.22 × 1052.85 × 10439.426.65
FeS21.24 × 1052.79 × 10439.907.14
SiC3.21 × 1047.56 × 10371.021.49
Tab.9  Energy economic analysis at different microwave absorbent types
Fig.9  Unitary energy economic cost and relative cost difference at different microwave absorbent types.
Fig.10  Circular energy and economic assessment: (a) energy flow and (b) economic flow.
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