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Frontiers of Environmental Science & Engineering

ISSN 2095-2201

ISSN 2095-221X(Online)

CN 10-1013/X

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Front Envir Sci Eng    2013, Vol. 7 Issue (3) : 302-325    https://doi.org/10.1007/s11783-013-0511-6
FEATURE ARTICLE
The abatement of major pollutants in air and water by environmental catalysis
Junhua LI1(), Hong HE2, Chun HU2, Jincai ZHAO3()
1. Tsinghua University, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Beijing 100084, China; 2. Chinese Academy of Science, Ecoenvironmental Science Research Center, Beijing 100085, China; 3. Chinese Academy of Sciences, Institute of Chemistry, Beijing 100190, China
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Abstract

This review reports the research progress in the abatement of major pollutants in air and water by environmental catalysis. For air pollution control, the selective catalytic reduction of NOx (SCR) by ammonia and hydrocarbons on metal oxide and zeolite catalysts are reviewed and discussed, as is the removal of Hg from flue gas by catalysis. The oxidation of Volatile organic compounds (VOCs) by photo- and thermal- catalysis for indoor air quality improvement is reviewed. For wastewater treatment, the catalytic elimination of inorganic and organic pollutants in wastewater is presented. In addition, the mechanism for the procedure of abatement of air and water pollutants by catalysis is discussed in this review. Finally, a research orientation on environment catalysis for the treatment of air pollutants and wastewater is proposed.
Keywords air pollution control      wastewater treatment      DeNOx      selective catalytic reduction (SCR)      Volatile organic compounds (VOCs)      environmental catalysis     
Corresponding Author(s): LI Junhua,Email:lijunhua@tsinhua.edu.cn; ZHAO Jincai,Email:jczhao@iccas.ac.cn   
Issue Date: 01 June 2013
 Cite this article:   
Junhua LI,Hong HE,Chun HU, et al. The abatement of major pollutants in air and water by environmental catalysis[J]. Front Envir Sci Eng, 2013, 7(3): 302-325.
 URL:  
https://academic.hep.com.cn/fese/EN/10.1007/s11783-013-0511-6
https://academic.hep.com.cn/fese/EN/Y2013/V7/I3/302
Fig.1  Mechanistic scheme of the catalytic cycle of the SCR reaction over the VO/TiO catalyst in the presence of oxygen []
Fig.2  Mechanism of NH-SCR of NO over Mn-Fe catalysts []
Fig.3  Scheme of the proposed mechanism of the standard SCR reaction on Fe/HBEA zeolite []
Fig.4  Schematic diagram of the Fe(III)-initiated Fenton-like chain reaction []
Fig.5  Proposed Fenton-like mechanism of Fe(III)-resin under visible light irradiation []
Fig.6  Proposed photodegradation mechanisms of organic pollutants in the aqueous HO/FePR system under visible light irradiation []
Fig.7  Suggested reaction mechanism during catalytic ozonation with AlO []
Fig.8  Schematic showing the transformation of , , , and trichloroethylene (TCE) on a Pd-M catalyst particle (M= Cu, In, Re) []
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