|
|
Catalytic oxidation of o-chlorophenol over Co2XAl (X= Co, Mg, Ca, Ni) hydrotalcite-derived mixed oxide catalysts |
Na Li1,2, Xin Xing1,2, Yonggang Sun1,2, Jie Cheng2(), Gang Wang1, Zhongshen Zhang2, Zhengping Hao1,2() |
1. Key Laboratory of Environmental Nanotechnology and Health Effects, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China 2. National Engineering Laboratory for VOCs Pollution Control Material & Technology, Research Center for Environmental Material and Pollution Control Technology, University of Chinese Academy of Sciences, Beijing 101408, China |
|
|
Abstract • Superior catalytic activity observed for o-chlorophenol oxidation on Co2MgAlO. • The reducibility, oxygen species and basicity influenced catalytic activity. • The organic by-products were generated in o-chlorophenol catalytic oxidation. ![]() A cobalt-based hydrotalcite-like compound was prepared using a constant-pH coprecipitation method. Cobalt-transition metal oxides (Co2XAlO, X= Co, Mg, Ca and Ni) were investigated for the deep catalytic oxidation of o-chlorophenol as a typical heteroatom contaminant containing chlorine atoms. The partial substitution of Co by Mg, Ca or Ni in the mixed oxide can promote the catalytic oxidation of o-chlorophenol. The Co2MgAlO catalyst presented the best catalytic activity, and could maintain 90% o-chlorophenol conversion at 167.1°C, compared only 27% conversion for the Co3AlO catalyst. The results demonstrated that the high activity could be attributed to its increased low-temperature reducibility, rich active oxygen species and excellent oxygen mobility. In the existence of acid and base sites, catalysts with strong basicity also showed preferred activity. The organic by-products generated during the o-chlorophenol catalytic oxidation over Co2MgAlO catalyst included carbon tetrachloride, trichloroethylene, 2,4-dichlorophenol, and 2,6-dichloro-p-benzoquinon, et al. This work provides a facile method for the preparation of Co-based composite oxide catalysts, which represent promising candidates for typical chlorinated and oxygenated volatile organic compounds.
|
Keywords
Hydrotalcite-derived mixed oxides
o-chlorophenol
Catalytic oxidation
Organic by-products
|
Corresponding Author(s):
Jie Cheng,Zhengping Hao
|
Issue Date: 28 June 2020
|
|
1 |
B Y Bai, J H Li (2014). Positive effects of K+ ions on three-dimensional mesoporous Ag/Co3O4 catalyst for HCHO oxidation. ACS Catalysis, 4(8): 2753–2762
https://doi.org/10.1021/cs5006663
|
2 |
N Blanch-Raga, A E Palomares, J Martínez-Triguero, G Fetter, P Bosch (2013). Cu mixed oxides based on hydrotalcite-like compounds for the oxidation of trichloroethylene. Industrial & Engineering Chemistry Research, 52(45): 15772–15779
https://doi.org/10.1021/ie4024935
|
3 |
N Blanch-Raga, A E Palomares, J Martínez-Triguero, M Puche, G Fetter, P Bosch (2014). The oxidation of trichloroethylene over different mixed oxides derived from hydrotalcites. Applied Catalysis B: Environmental, 160–161: 129–134
https://doi.org/10.1016/j.apcatb.2014.05.014
|
4 |
P H Bolt, F H P M Habraken, J W Geus (1998). Formation of nickel, cobalt, copper, and iron aluminates from a- and l-alumina-supported oxides: A comparative study. Journal of Solid State Chemistry, 135(1): 59–69
https://doi.org/10.1006/jssc.1997.7590
|
5 |
T Cai, H Huang, W Deng, Q G Dai, W Liu, X Y Wang (2015). Catalytic combustion of 1,2-dichlorobenzene at low temperature over Mn-modified Co3O4 catalysts. Applied Catalysis B: Environmental, 166–167: 393–405
https://doi.org/10.1016/j.apcatb.2014.10.047
|
6 |
C A Chagas, E F de Souza, R L Manfro, S M Landi, M M V M Souza, M Schmal (2016). Copper as promoter of the NiO-CeO2 catalyst in the preferential CO oxidation. Applied Catalysis B: Environmental, 182: 257–265
https://doi.org/10.1016/j.apcatb.2015.09.033
|
7 |
J Cheng, J J Yu, X P Wang, L D Li, J J Li, Z P Hao (2008). Novel CH4 combustion catalysts derived from Cu-Co/X-Al (X= Fe, Mn, La, Ce) hydrotalcite-like compounds. Energy & Fuels, 22(4): 2131–2137
https://doi.org/10.1021/ef8000168
|
8 |
Q G Dai, W Wang, X Y Wang, G Z Lu (2017). Sandwich-structured CeO2@ZSM-5 hybrid composites for catalytic oxidation of 1,2-dichloroethane: An integrated solution to coking and chlorine poisoning deactivation. Applied Catalysis B: Environmental, 203: 31–42
https://doi.org/10.1016/j.apcatb.2016.10.009
|
9 |
C S Evans, B Dellinger (2005). Surface-mediated formation of polybrominated dibenzo-p-dioxins and dibenzofurans from the high-temperature pyrolysis of 2-bromophenol on a CuO/silica surface. Environmental Science & Technology, 39(13): 4857–4863
https://doi.org/10.1021/es048057z
|
10 |
Y F Gu, T Cai, X H Gao, H Q Xia, W Sun, J Zhao, Q G Dai, X Y Wang (2019). Catalytic combustion of chlorinated aromatics over WOx/CeO2 catalysts at low temperature. Applied Catalysis B: Environmental, 248: 264–276
https://doi.org/10.1016/j.apcatb.2018.12.055
|
11 |
L J Guo, N Jiang, J Li, K F Shang, N Lu, Y Wu (2018). Abatement of mixed volatile organic compounds in a catalytic hybrid surface/packed-bed discharge plasma reactor. Frontiers of Environmental Science & Engineering, 12(2): 15
https://doi.org/10.1007/s11783-018-1017-z
|
12 |
J K Han, L T Jia, B Hou, D B Li, Y Liu, Y C Liu (2015). Catalytic properties of CoAl2O4/Al2O3 supported cobalt catalysts for Fischer-Tropsch synthesis. Journal of Fuel Chemistry and Technology, 43(7): 846–851
https://doi.org/10.1016/S1872-5813(15)30025-6
|
13 |
C He, J Cheng, X Zhang, M Douthwaite, S Pattisson, Z P Hao (2019). Recent advances in the catalytic oxidation of volatile organic compounds: A review based on pollutant sorts and sources. Chemical Reviews, 119(7): 4471–4568
https://doi.org/10.1021/acs.chemrev.8b00408
|
14 |
C E Hetrick, J Lichtenberger, M D Amiridis (2008). Catalytic oxidation of chlorophenol over V2O5/TiO2 catalysts. Applied Catalysis B: Environmental, 77(3–4): 255–263
https://doi.org/10.1016/j.apcatb.2007.07.022
|
15 |
H Hu, S X Cai, H R Li, L Huang, L Y Shi, D S Zhang (2015). Mechanistic aspects of deNOx processing over TiO2 supported Co–Mn oxide catalysts: Structure–activity relationships and in situ DRIFTs analysis. ACS Catalysis, 5(10): 6069–6077
https://doi.org/10.1021/acscatal.5b01039
|
16 |
Y C Huang, W J Fan, B Long, H B Li, W T Qiu, F Y Zhao, Y X Tong, H B Ji (2016a). Alkali-modified non-precious metal 3D-NiCo2O4 nanosheets for efficient formaldehyde oxidation at low temperature. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 4(10): 3648–3654
https://doi.org/10.1039/C5TA09370H
|
17 |
Y C Huang, K H Ye, H B Li, W J Fan, F Y Zhao, Y M Zhang, H B Ji (2016b). A highly durable catalyst based on CoxMn3–xO4 nanosheets for low-temperature formaldehyde oxidation. Nano Research, 9(12): 3881–3892
https://doi.org/10.1007/s12274-016-1257-9
|
18 |
M S Kamal, S A Razzak, M M Hossain (2016). Catalytic oxidation of volatile organic compounds (VOCs): A review. Atmospheric Environment, 140: 117–134
https://doi.org/10.1016/j.atmosenv.2016.05.031
|
19 |
P Li, C He, J Cheng, C Y Ma, B J Dou, Z P Hao (2011). Catalytic oxidation of toluene over Pd/Co3AlO catalysts derived from hydrotalcite-like compounds: Effects of preparation methods. Applied Catalysis B: Environmental, 101(3–4): 570–579
https://doi.org/10.1016/j.apcatb.2010.10.030
|
20 |
Q Li, M Meng, Z Q Zou, X G Li, Y Q Zha (2009). Simultaneous soot combustion and nitrogen oxides storage on potassium-promoted hydrotalcite-based CoMgAlO catalysts. Journal of Hazardous Materials, 161(1): 366–372
https://doi.org/10.1016/j.jhazmat.2008.03.103
|
21 |
S D Li, H S Wang, W M Li, X F Wu, W X Tang, Y F Chen (2015). Effect of Cu substitution on promoted benzene oxidation over porous CuCo-based catalysts derived from layered double hydroxide with resistance of water vapor. Applied Catalysis B: Environmental, 166–167: 260–269
https://doi.org/10.1016/j.apcatb.2014.11.040
|
22 |
J G Liu, M Y Ding, T J Wang, L L Ma (2012). Promoting effect of cobalt addition on higher alcohols synthesis over copper-based catalysts. Advanced Materials Research, 550–553: 270–275
https://doi.org/10.4028/www.scientific.net/AMR.550-553.270
|
23 |
Y Lou, L Wang, Z Y Zhao, Y H Zhang, Z G Zhang, G Z Lu, Y Guo, Y L Guo (2014). Low-temperature CO oxidation over Co3O4-based catalysts: Significant promoting effect of Bi2O3 on Co3O4 catalyst. Applied Catalysis B: Environmental, 146: 43–49
https://doi.org/10.1016/j.apcatb.2013.06.007
|
24 |
W J Lu, Y Abbas, M F Mustafa, C Pan, H T Wang (2019). A review on application of dielectric barrier discharge plasma technology on the abatement of volatile organic compounds. Frontiers of Environmental Science & Engineering, 13(2): 30
https://doi.org/10.1007/s11783-019-1108-5
|
25 |
M Salavati-Niasari, N Mir, F Davar (2009). Synthesis and characterization of Co3O4 nanorods by thermal decomposition of cobalt oxalate. Journal of Physics and Chemistry of Solids, 70(5): 847–852
https://doi.org/10.1016/j.jpcs.2009.04.006
|
26 |
Z N Shi, P Yang, F Tao, R X Zhou (2016). New insight into the structure of CeO2–TiO2 mixed oxides and their excellent catalytic performances for 1,2-dichloroethane oxidation. Chemical Engineering Journal, 295: 99–108
https://doi.org/10.1016/j.cej.2016.03.032
|
27 |
X F Tang, J M Hao, J H Li (2009). Complete oxidation of methane on Co3O4–SnO2 catalysts. Frontiers of Environmental Science & Engineering in China, 3(3): 265–270
https://doi.org/10.1007/s11783-009-0019-2
|
28 |
M J Tian, C He, Y K Yu, H Pan, L Smith, Z Y Jiang, N B Gao, Y F Jian, Z P Hao, Q Zhu (2018). Catalytic oxidation of 1,2-dichloroethane over three-dimensional ordered meso-macroporous Co3O4/La0.7Sr0.3Fe0.5Co0.5O3: Destruction route and mechanism. Applied Catalysis A, General, 553: 1–14
https://doi.org/10.1016/j.apcata.2018.01.013
|
29 |
Z Y Tian, P H Tchoua Ngamou, V Vannier, K Kohse-Höinghaus, N Bahlawane (2012). Catalytic oxidation of VOCs over mixed Co–Mn oxides. Applied Catalysis B: Environmental, 117–118: 125–134
https://doi.org/10.1016/j.apcatb.2012.01.013
|
30 |
L L Yang, G R Liu, M H Zheng, Y Y Zhao, R Jin, X L Wu, Y Xu (2017). Molecular mechanism of dioxin formation from chlorophenol based on electron paramagnetic resonance spectroscopy. Environmental Science & Technology, 51(9): 4999–5007
https://doi.org/10.1021/acs.est.7b00828
|
31 |
P Yang, S S Yang, Z N Shi, Z H Meng, R X Zhou (2015). Deep oxidation of chlorinated VOCs over CeO2-based transition metal mixed oxide catalysts. Applied Catalysis B: Environmental, 162: 227–235
https://doi.org/10.1016/j.apcatb.2014.06.048
|
32 |
L P Zeng, K Z Li, F Huang, X Zhu, H C Li (2016). Effects of Co3O4 nanocatalyst morphology on CO oxidation: Synthesis process map and catalytic activity. Chinese Journal of Catalysis, 37(6): 908–922
https://doi.org/10.1016/S1872-2067(16)62460-9
|
33 |
C H Zhang, C Wang, S Gil, A Boreave, L Retailleau, Y L Guo, J L Valverde, A Giroir-Fendler (2017). Catalytic oxidation of 1,2-dichloropropane over supported LaMnOx oxides catalysts. Applied Catalysis B: Environmental, 201: 552–560
https://doi.org/10.1016/j.apcatb.2016.08.038
|
34 |
X Zhang, Z Wang, Y Y Tang, N L Qiao, Y Li, S Q Qu, Z P Hao (2015). Catalytic behaviors of combined oxides derived from Mg/AlxFe1–x–Cl layered double hydroxides for H2S selective oxidation. Catalysis Science & Technology, 5(11): 4991–4999
https://doi.org/10.1039/C5CY00689A
|
35 |
Z Z Zhu, G Z Lu, Z G Zhang, Y Guo, Y L Guo, Y Q Wang (2013). Highly active and stable Co3O4/ZSM-5 catalyst for propane oxidation: Effect of the preparation method. ACS Catalysis, 3(6): 1154–1164
https://doi.org/10.1021/cs400068v
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|