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Frontiers of Mechanical Engineering

ISSN 2095-0233

ISSN 2095-0241(Online)

CN 11-5984/TH

Postal Subscription Code 80-975

2018 Impact Factor: 0.989

Front. Mech. Eng.    2014, Vol. 9 Issue (1) : 71-74    https://doi.org/10.1007/s11465-014-0291-0
RESEARCH ARTICLE
Wide gap active brazing of ceramic-to-metal-joints for high temperature applications
K. Bobzin,L. Zhao(),N. Kopp,S. Samadian Anavar
Surface Engineering Institute, RWTH Aachen University, Germany
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Abstract

Applications like solid oxide fuel cells and sensors increasingly demand the possibility to braze ceramics to metals with a good resistance to high temperatures and oxidative atmospheres. Commonly used silver based active filler metals cannot fulfill these requirements, if application temperatures higher than 600°C occur. Au and Pd based active fillers are too expensive for many fields of use. As one possible solution nickel based active fillers were developed. Due to the high brazing temperatures and the low ductility of nickel based filler metals, the modification of standard nickel based filler metals were necessary to meet the requirements of above mentioned applications. To reduce thermally induced stresses wide brazing gaps and the addition of Al2O3 and WC particles to the filler metal were applied. In this study, the microstructure of the brazed joints and the thermo-chemical reactions between filler metal, active elements and WC particles were analyzed to understand the mechanism of the so called wide gap active brazing process. With regard to the behavior in typical application oxidation and thermal cycle tests were conducted as well as tensile tests.

Keywords wide gap      active brazing      nickel filler metals      high temperature application      WC      Al2O3     
Corresponding Author(s): L. Zhao   
Issue Date: 16 May 2014
 Cite this article:   
K. Bobzin,L. Zhao,N. Kopp, et al. Wide gap active brazing of ceramic-to-metal-joints for high temperature applications[J]. Front. Mech. Eng., 2014, 9(1): 71-74.
 URL:  
https://academic.hep.com.cn/fme/EN/10.1007/s11465-014-0291-0
https://academic.hep.com.cn/fme/EN/Y2014/V9/I1/71
Fig.1  Al2O3-to-X1CrTiLa22-joint brazed at 1200°C, 10 min, with Ni650+ 5 wt.% TiH+ 30 vol.% Al2O3
Fig.2  Al2O3-to-X1CrTiLa22-joint brazed at 1200°C, 10 min, Ni650+ 10 wt.% Zr30Ni+ 30 vol.% WC
Fig.3  DSC curves of Ni650, Ni650+ 10 wt.% Zr30Ni and Ni650+ 10 wt.% Zr30Ni+ 30 vol.% WC
Fig.4  Thermal expansion coefficients of Ni650, Ni650+ 10 wt.% Zr30Ni+ 50 vol.% WC and Ni650+ 5 wt.% TiH+ 30 vol.% Al2O3
Fig.5  Al2O3-to-X1CrTiLa22-joint brazed at 1200°C, 10 min, Ni650+ 10 wt.% Zr30Ni+ 30 vol.% WC after exposure in air at 900°C for 20 h
Fig.6  Al2O3-to-X1CrTiLa22-joint brazed at 1200°C, 10 min, with Ni650+ 5 wt.% TiH+ 30 vol.% Al2O3 after thermo cyclic tests
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