Superior performance for lithium storage from an integrated composite anode consisting of SiO-based active material and current collector

doi:10.1007/s11706-020-0511-y

Front. Mater. Sci.

2020, Vol. 14

Issue (3) : 243-254 https://doi.org/10.1007/s11706-020-0511-y

RESEARCH ARTICLE

Superior performance for lithium storage from an integrated composite anode consisting of SiO-based active material and current collector

Junqiang HUA, Hailiang CHU, Ying ZHU, Tingting FANG, Shujun QIU(

), Yongjin ZOU, Cuili XIANG, Kexiang ZHANG, Bin LI, Huanzhi ZHANG, Fen XU, Lixian SUN(

)

Guangxi Key Laboratory of Information Materials, Guangxi Collaborative Innovation Centre of Structure and Property for New Energy Materials, and School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, China

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Abstract

Silicon-based material is considered to be one of the most promising anodes for the next-generation lithium-ion batteries (LIBs) due to its rich sources, non-toxicity, low cost and high theoretical specific capacity. However, it cannot maintain a stable electrode structure during repeated charge/discharge cycles, and therefore long cycling life is difficult to be achieved. To address this problem, herein a simple and efficient method is developed for the fabrication of an integrated composite anode consisting of SiO-based active material and current collector, which exhibits a core–shell structure with nitrogen-doped carbon coating on SiO/P micro-particles. Without binder and conductive agent, the volume expansion of SiO active material in the integrated composite anode is suppressed to prevent its pulverization. At a current density of 500 mA·g⁻¹, this integrated composite anode exhibits a reversible specific capacity of 458 mA·h·g⁻¹ after 200 cycles. Furthermore, superior rate performance and cycling stability are also achieved. This work illustrates a potential method for the fabrication of integrated composite anodes with superior electrochemical properties for high-performance LIBs.

Keywords lithium-ion battery silicon monoxide red phosphorus rate performance integrated composite anode

Corresponding Author(s): Shujun QIU,Lixian SUN

Online First Date: 13 July 2020 Issue Date: 10 September 2020

Cite this article:

Junqiang HUA,Hailiang CHU,Ying ZHU, et al. Superior performance for lithium storage from an integrated composite anode consisting of SiO-based active material and current collector[J]. Front. Mater. Sci., 2020, 14(3): 243-254.

URL:

https://academic.hep.com.cn/foms/EN/10.1007/s11706-020-0511-y
https://academic.hep.com.cn/foms/EN/Y2020/V14/I3/243

Fig.1 Schematic diagram for the fabrication of the integrated SiO/P@GC composite anode.

Fig.2 (a) XRD patterns, (b) Raman spectra and (c) TGA plots of the samples.

Fig.3 SEM images of (a) uncarbonizated SiO/P@GC, (b) SiO/P@GC-450 and (c) SiO/P@GC-550. (d) TEM image, (e)(f)(g) HRTEM images and (h) EDS elemental mappings of SiO/P@GC-550.

Fig.4 (a) Survey XPS spectrum and (b)(c)(d)(e)(f) high-resolution XPS spectra of Si 2p, P 2p, C 1s, N 1s and O 1s of SiO/P@GC-550.

Fig.5 CV curves at 0.1 mV·s⁻¹: (a) SiO/P@GC-450; (b) SiO/P@GC-550.

Fig.6 Electrochemical performance of anodes: charge and discharge curves at 200 mA·g⁻¹ of (a) SiO/P@GC-450 and (b) SiO/P@GC-550; cycling performance at (c) 200 mA?g⁻¹ and (d) 500 mA?g⁻¹; (e) rate capability; (f) coulombic efficiency.

Fig.7 (a) Nyquist plots of ball-milled SiO, SiO/P@GC-450 and SiO/P@GC-550 composite anodes and (b) the corresponding equivalent circuit.

Tab.1 EIS fitting parameters of the pristine SiO anode and integrated SiO/P@GC-450 and SiO/P@GC-550 composite anodes

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