Crystalline mesoporous transition metal oxides: hard-templating synthesis and application in environmental catalysis

doi:10.1007/s11783-012-0472-1

Front Envir Sci Eng

2013, Vol. 7

Issue (3) : 341-355 https://doi.org/10.1007/s11783-012-0472-1

REVIEW ARTICLE

Crystalline mesoporous transition metal oxides: hard-templating synthesis and application in environmental catalysis

Zhen MA¹(

), Bei ZHOU¹, Yu REN²(

)

1. Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP³), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China; 2. Energy Storage Center, National Institute of Clean-and-Low-Carbon Energy, Shenhua Group, Future Science and Technology City, Beijing 102209, China

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Abstract

Mesoporous silicas such as MCM-41 and SBA-15 possess high surface areas, ordered nanopores, and excellent thermal stability, and have been often used as catalyst supports. Although mesoporous metal oxides have lower surface areas compared to mesoporous silicas, they generally have more diversified functionalities. Mesoporous metal oxides can be synthesized via a soft-templating or hard-templating approach, and these materials have recently found some applications in environmental catalysis, such as CO oxidation, N₂O decomposition, and elimination of organic pollutants. In this review, we summarize the synthesis of mesoporous transition metal oxides using mesoporous silicas as hard templates, highlight the application of these materials in environmental catalysis, and furnish some prospects for future development.

Keywords mesoporous materials silica metal oxide hard-templating environmental catalysis

Corresponding Author(s): MA Zhen,Email:zhenma@fudan.edu.cn; REN Yu,Email:renyu3@gmail.com

Issue Date: 01 June 2013

Cite this article:

Zhen MA,Bei ZHOU,Yu REN. Crystalline mesoporous transition metal oxides: hard-templating synthesis and application in environmental catalysis[J]. Front Envir Sci Eng, 2013, 7(3): 341-355.

URL:

https://academic.hep.com.cn/fese/EN/10.1007/s11783-012-0472-1
https://academic.hep.com.cn/fese/EN/Y2013/V7/I3/341

Fig.1 Schematic illustration of the nanocasting pathway []. Reproduced with permission of Wiley-VCH

Fig.2 TEM images of crystalline mesoporous CeO prepared using KIT-6 (a) and SBA-15 (b) as hard templates []. Reproduced with permission of the Royal Society of Chemistry

Fig.3 Schematic drawing of the growth of InO particles in the pores of mesoporous KIT-6 []. After the first cycle of impregnation with In(NO) and subsequent conversion into InO, spherical “islands” are formed inside the silica pore network; additional cycles lead predominantly to the growth of existing InO particles rather than to nucleation of new ones

Fig.4 CO conversions and T over different catalysts [] (a) mesoporous CeO; (b) 10%CuO/mesoporous CeO; (c) 20%CuO/mesoporous CeO; (d) 30%CuO/mesoporous CeO; (e) CeO-D prepared by calcining Ce(NO) at 550°C.

Fig.5 CO conversions on metal oxide catalysts: () and (b) mesoporous (denoted as ) catalysts; (c) and (d) bulk (denoted as -) catalysts [].

Fig.6 Bar diagram comparing the conversions of NO on different commercial or mesoporous metal oxides at 350°C. Reaction conditions: 0.5% NO (balance He), 60 cm·min, 0.5 g catalyst

Fig.7 Variation of the catalytic activity for naphthalene oxidation (expressed as yield to CO) on nanocast CeO catalysts, as a function of reaction temperature []

Fig.8 Variation of the propane conversion (a) and toluene conversion (b) with the reaction temperature for CoO samples prepared by a nanocasting route [] Influence of the aging temperature during the synthesis of the silica template (40, 70, and 100°C). For comparison, the results of a CoO prepared by simple evaporation of Co-nitrate and calcined at 500°C has been included. Symbols: reference catalyst (?), C40-550 (○), C70-550 (●), and C100-550 (●)

Fig.9 Variation of the propane conversion with the reaction temperature for CoO samples prepared by a nanocasting route (a) Influence of the calcination temperature of the silica template on the catalytic activity and on the specific catalytic activity at 200°C (b) Symbols: C100-550 (●), C100-700 (?), C100-800 (Δ), and C100-900 (◇) []

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