|
|
Crystalline mesoporous transition metal oxides: hard-templating synthesis and application in environmental catalysis |
Zhen MA1(), Bei ZHOU1, Yu REN2() |
1. Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China; 2. Energy Storage Center, National Institute of Clean-and-Low-Carbon Energy, Shenhua Group, Future Science and Technology City, Beijing 102209, China |
|
|
Abstract Mesoporous silicas such as MCM-41 and SBA-15 possess high surface areas, ordered nanopores, and excellent thermal stability, and have been often used as catalyst supports. Although mesoporous metal oxides have lower surface areas compared to mesoporous silicas, they generally have more diversified functionalities. Mesoporous metal oxides can be synthesized via a soft-templating or hard-templating approach, and these materials have recently found some applications in environmental catalysis, such as CO oxidation, N2O decomposition, and elimination of organic pollutants. In this review, we summarize the synthesis of mesoporous transition metal oxides using mesoporous silicas as hard templates, highlight the application of these materials in environmental catalysis, and furnish some prospects for future development.
|
Keywords
mesoporous materials
silica
metal oxide
hard-templating
environmental catalysis
|
Corresponding Author(s):
MA Zhen,Email:zhenma@fudan.edu.cn; REN Yu,Email:renyu3@gmail.com
|
Issue Date: 01 June 2013
|
|
1 |
Beck J S, Vartuli J C, Roth W J, Leonowicz M E, Kresge C T, Schmitt K D, Chu C T W, Olson D H, Sheppard E W, Mccullen S B, Higgins J B, Schlenker J L. A new family of mesoporous molecular-sieves prepared with liquid-crystal templates. Journal of the American Chemical Society , 1992, 114(27): 10834–10843 doi: 10.1021/ja00053a020
|
2 |
Zhao D Y, Huo Q S, Feng J L, Chmelka B F, Stucky G D. Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. Journal of the American Chemical Society , 1998, 120(24): 6024–6036 doi: 10.1021/ja974025i
|
3 |
Corma A. From microporous to mesoporous molecular sieve materials and their use in catalysis. Chemical Reviews , 1997, 97(6): 2373–2420 doi: 10.1021/cr960406n pmid:11848903
|
4 |
Ying J Y, Mehnert C P, Wong M S. Synthesis and applications of supramolecular-templated mesoporous materials. Angewandte Chemie International Edition , 1999, 38(1-2): 56–77 doi: 10.1002/(SICI)1521-3773(19990115)38:1/2<56::AID-ANIE56>3.0.CO;2-E
|
5 |
Wan Y, Zhao D Y. On the controllable soft-templating approach to mesoporous silicates. Chemical Reviews , 2007, 107(7): 2821–2860 doi: 10.1021/cr068020s pmid:17580976
|
6 |
On D T, Desplantier-Giscard D, Danumah C, Kaliaguine S. Perspectives in catalytic applications of mesostructured materials. Applied Catalysis A, General , 2003, 253(2): 545–602 doi: 10.1016/S0926-860X(03)00195-9
|
7 |
Taguchi A, Schüth F. Ordered mesoporous materials in catalysis. Microporous and Mesoporous Materials , 2005, 77(1): 1–45 doi: 10.1016/j.micromeso.2004.06.030
|
8 |
Schüth F. Non-siliceous mesostructured and mesoporous materials. Chemistry of Materials , 2001, 13(10): 3184–3195 doi: 10.1021/cm011030j
|
9 |
Kondo J N, Domen K. Crystallization of mesoporous metal oxides. Chemistry of Materials , 2008, 20(3): 835–847 doi: 10.1021/cm702176m
|
10 |
Bruce P G, Scrosati B, Tarascon J M. Nanomaterials for rechargeable lithium batteries. Angewandte Chemie International Edition , 2008, 47(16): 2930–2946 doi: 10.1002/anie.200702505 pmid:18338357
|
11 |
Ren Y, Ma Z, Bruce P G. Ordered mesoporous metal oxides: synthesis and applications. Chemical Society Reviews , 2012, 41(14): 4909–4927 doi: 10.1039/c2cs35086f pmid:22653082
|
12 |
Huo Q S, Margolese D I, Ciesla U, Feng P Y, Gier T E, Sieger P, Leon R, Petroff P M, Schüth F, Stucky G D. Generalized synthesis of periodic surfactant inorganic composite-materials. Nature , 1994, 368(6469): 317–321 doi: 10.1038/368317a0
|
13 |
Yang P D, Zhao D Y, Margolese D I, Chmelka B F, Stucky G D. Generalized synthesis of large-pore mesoporous metal oxides with nanocrystalline walls. Nature , 1998, 396(6707): 152–155 doi: 10.1038/24132
|
14 |
Yu C Z, Tian B Z, Zhao D Y. Recent advances in the synthesis of non-siliceous mesoporous materials. Current Opinion in Solid State and Materials Science , 2003, 7(3): 191–197 doi: 10.1016/j.cossms.2003.10.004
|
15 |
Boettcher S W, Fan J, Tsung C K, Shi Q H, Stucky G D. Harnessing the sol-gel process for the assembly of non-silicate mesostructured oxide materials. Accounts of Chemical Research , 2007, 40(9): 784–792 doi: 10.1021/ar6000389 pmid:17461540
|
16 |
Lu A H, Schüth F. Nanocasting: A versatile strategy for creating nanostructured porous materials. Advanced Materials , 2006, 18(14): 1793–1805 doi: 10.1002/adma.200600148
|
17 |
Ryoo R, Joo S H, Jun S. Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation. Journal of Physical Chemistry B , 1999, 103(37): 7743–7746 doi: 10.1021/jp991673a
|
18 |
Lee J, Yoon S, Hyeon T, Oh S M, Kim K B. Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors. Chemical Communications , 1999, 21: 2177–2178 doi: 10.1039/a906872d
|
19 |
Ryoo R, Ko C H, Kruk M, Antochshuk V, Jaroniec M. Block-copolymer-templated ordered mesoporous silica: array of uniform mesopores or mesopore-micropore network? Journal of Physical Chemistry B , 2000, 104(48): 11465–11471 doi: 10.1021/jp002597a
|
20 |
Schüth F. Endo- and exotemplating to create high-surface-area inorganic materials. Angewandte Chemie International Edition , 2003, 42(31): 3604–3622 doi: 10.1002/anie.200300593 pmid:12916030
|
21 |
Lu A H, Schüth F. Nanocasting pathways to create ordered mesoporous solids. Comptes Rendus. Chimie , 2005, 8(3-4): 609–620 doi: 10.1016/j.crci.2004.10.020
|
22 |
Yang H F, Zhao D Y. Synthesis of replica mesostructures by the nanocasting strategy. Journal of Materials Chemistry , 2005, 15: 1217–1231
|
23 |
Valdés-Solís T, Fuertes A B. High-surface area inorganic compounds prepared by nanocasting techniques. Materials Research Bulletin , 2006, 41(12): 2187–2197 doi: 10.1016/j.materresbull.2006.04.018
|
24 |
Wang Y G, Wang Y J, Li C L, Liu X H, Wang Y Q, Lu G Z. Synthetic methods of mesostructured metal oxides/composites. Progress in Chemistry , 2006, 18: 1338–1344
|
25 |
Tiemann M. Repeated templating. Chemistry of Materials , 2008, 20(3): 961–971 doi: 10.1021/cm702050s
|
26 |
Yue W B, Zhou W Z. Crystalline mesoporous metal oxide. Progress in Natural Science , 2008, 18(11): 1329–1338 doi: 10.1016/j.pnsc.2008.05.010
|
27 |
Rao Y X, Antonelli D M. Mesoporous transition metal oxides: Characterization and applications in heterogeneous catalysis. Journal of Materials Chemistry , 2009, 19(14): 1937–1944 doi: 10.1039/b813533a
|
28 |
Roggenbuck J, Sch?fer H, Tsoncheva T, Minchev C, Hanss J, Tiemann M. Mesoporous CeO2: Synthesis by nanocasting, characterization and catalytic properties. Microporous and Mesoporous Materials , 2007, 101(3): 335–341 doi: 10.1016/j.micromeso.2006.11.029
|
29 |
Carabineiro S A C, Bastos S S T, órf?o J J M, Pereira M F R, Delgado J J, Figueiredo J L. Exotemplated ceria catalysts with gold for CO oxidation. Applied Catalysis A, General , 2010, 381(1-2): 150–160 doi: 10.1016/j.apcata.2010.04.001
|
30 |
Carabineiro S A C, Bastos S S T, órf?o J J M, Pereira M F R, Delgado J J, Figueiredo J L. Carbon monoxide oxidation catalysed by exotemplated manganes oxides. Catalysis Letters , 2010, 134(3-4): 217–227 doi: 10.1007/s10562-009-0251-1
|
31 |
Bastos S S T, Carabineiro S A C, órf?o J J M, Pereira M F R, Delgado J J, Figueiredo J L. Total oxidation of ethyl acetate, ethanol and toluene catalyzed by exotemplated manganese and cerium oxides loaded with gold. Catalysis Today , 2012, 180(1): 148–154 doi: 10.1016/j.cattod.2011.01.049
|
32 |
Laha S C, Ryoo R. Synthesis of thermally stable mesoporous cerium oxide with nanocrystalline frameworks using mesoporous silica templates. Chemical Communications , 2003, 17: 2138–2139 doi: 10.1039/b305524h pmid:13678169
|
33 |
Zhu K K, Yue B, Zhou W Z, He H Y. Preparation of three-dimensional chromium oxide porous single crystals templated by SBA-15. Chemical Communications , 2003, 1: 98–99 doi: 10.1039/b210065g pmid:12610984
|
34 |
Jiao K, Zhang B, Yue B, Ren Y, Liu S X, Yan S R, Dickinson C, Zhou W Z, He H Y. Growth of porous single-crystal Cr2O3 in a 3-D mesopore system. Chemical Communications , 2005, 45: 5618–5620 doi: 10.1039/b512080b pmid:16292367
|
35 |
Zhu K K, He H Y, Xie S H, Zhang X, Zhou W Z, Jin S, Yue B. Crystalline WO3 nanowires synthesized by templating method. Chemical Physics Letters , 2003, 377(3-4): 317–321 doi: 10.1016/S0009-2614(03)01206-5
|
36 |
Jiao F, Yue B, Zhu K K, Zhao D Y, He H Y. α-Fe2O3 nanowires. Confined synthesis and catalytic hydroxylation of phenol. Chemistry Letters , 2003, 32(8): 770–771 doi: 10.1246/cl.2003.770
|
37 |
Yue B, Tang H L, Kong Z P, Zhu K K, Dickinson C, Zhou W Z, He H Y. Preparation and characterization of three-dimensional mesoporous crystals of tungsten oxide. Chemical Physics Letters , 2005, 407(1-3): 83–86 doi: 10.1016/j.cplett.2005.03.066
|
38 |
Tian B Z, Liu X Y, Yang H F, Xie S H, Yu C Z, Tu B, Zhao D Y. General synthesis of ordered crystallized metal oxide nanoarrays replicated by microwave-digested mesoporous silica. Advanced Materials (Deerfield Beach, Fla.) , 2003, 15(16): 1370–1374 doi: 10.1002/adma.200305211
|
39 |
Tian B Z, Lui X, Yu C Z, Gao F, Luo Q, Xie S H, Tu B, Zhao D Y. Microwave assisted template removal of siliceous porous materials. Chemical Communications , 2002, 11: 1186–1187 doi: 10.1039/b202180c pmid:12109074
|
40 |
Tian B Z, Liu X Y, Solovyov L A, Liu Z, Yang H F, Zhang Z D, Xie S H, Zhang F Q, Tu B, Yu C Z, Terasaki O, Zhao D Y. Facile synthesis and characterization of novel mesoporous and mesorelief oxides with gyroidal structures. Journal of the American Chemical Society , 2004, 126(3): 865–875 doi: 10.1021/ja037877t pmid:14733562
|
41 |
Yang H F, Shi Q H, Tian B Z, Lu Q Y, Gao F, Xie S H, Fan J, Yu C Z, Tu B, Zhao D Y. One-step nanocasting synthesis of highly ordered single crystalline indium oxide nanowire arrays from mesostructured frameworks. Journal of the American Chemical Society , 2003, 125(16): 4724–4725 doi: 10.1021/ja034005i pmid:12696887
|
42 |
Yue W B, Hill A H, Harrison A, Zhou W Z. Mesoporous single-crystal Co3O4 templated by cage-containing mesoporous silica. Chemical Communications , 2007, 24: 2518–2520 doi: 10.1039/b700185a pmid:17563815
|
43 |
Yue W B, Zhou W Z. Mesoporous metal oxides templated by FDU-12 using a new convient method. Studies in Surface Science and Catalysis , 2007, 170: 1755–1762 doi: 10.1016/S0167-2991(07)81056-1
|
44 |
Yue W B, Zhou W Z. Porous crystals of cubic metal oxides templated by cage-containing mesoporous silica. Journal of Materials Chemistry , 2007, 17(47): 4947–4952 doi: 10.1039/b709076e
|
45 |
Wang Y Q, Yang C M, Schmidt W, Spliethoff B, Bill E, Schüth F. Weakly ferromagnetic ordered mesoporous Co3O4 synthesized by nanocasting from vinyl-functionaluzed cubic Ia3d mesoporous silica. Advanced Materials , 2005, 17: 53–56 doi: 10.1002/adma.200400777
|
46 |
Rumplecker A, Kleitz F, Salabas E L, Schüth F. Hard templating pathways for the synthesis of nanostructured porous Co3O4. Chemistry of Materials , 2007, 19(3): 485–496 doi: 10.1021/cm0610635
|
47 |
Shen W H, Dong X P, Zhu Y F, Chen H R, Shi J L. Mesoporous CeO2 and CuO-loaded mesoporous CeO2: Synthesis, characterization, and CO catalytic oxidation property. Microporous and Mesoporous Materials , 2005, 85(1-2): 157–162 doi: 10.1016/j.micromeso.2005.06.006
|
48 |
Yue W B, Zhou W Z. Synthesis of porous single crystals of metal oxides via a solid-liquid route. Chemistry of Materials , 2007, 19(9): 2359–2363 doi: 10.1021/cm070124b
|
49 |
Wang Y G, Wang Y Q, Liu X H, Guo Y, Guo Y L, Lu G Z, Schüth F. Nanocasted synthesis of mesoporous metal oxides and mixed oxides from mesoporous cubic (Ia3d) vinylsilica. Journal of Nanoscience and Nanotechnology , 2008, 8(11): 5652–5658 doi: 10.1166/jnn.2008.226 pmid:19198284
|
50 |
Puertolas B, Solsona B, Agouram S, Murillo R, Mastral A M, Aranda A, Taylor S H, Garcia T. The catalytic performance of mesoporous cerium oxides prepared through a nanocasting route for the total oxidation of naphthalene. Applied Catalysis B: Environmental , 2010, 93(3-4): 395–405 doi: 10.1016/j.apcatb.2009.10.014
|
51 |
Jin M S, Park J N, Shon J K, Li Z H, Yoon M Y, Na H J, Park Y W, Kim J M. Synthesis of highly ordered mesoporous CeO2 and low temperature CO oxidation over Pd/mesoporous CeO2. Research on Chemical Intermediates , 2011, 37(9): 1181–1192 doi: 10.1007/s11164-011-0385-9
|
52 |
Shen W H, Shi J L, Chen H R, Gu J L, Zhu Y F, Dong X P. Synthesis and CO oxidation catalytic character of high surface area ruthenium dioxide replicated by cubic mesoporous silica. Chemistry Letters , 2005, 34(3): 390–391 doi: 10.1246/cl.2005.390
|
53 |
Park J N, Shon J K, Jin M, Kong S S, Moon K, Park G O, Boo J H, Kim J M. Room-temperature CO oxidation over a highly ordered mesoporous RuO2 catalyst. Reaction Kinetics. Mechanism and Catalysis , 2011, 103: 87–99
|
54 |
Wang Y G, Xia Y Y. Electrochemical capacitance characterization of NiO with ordered mesostructure synthesized by template SBA-15. Electrochimica Acta , 2006, 51(16): 3223–3227 doi: 10.1016/j.electacta.2005.09.013
|
55 |
Jiao F, Hill A H, Harrison A, Berko A, Chadwick A V, Bruce P G. Synthesis of ordered mesoporous NiO with crystalline walls and a bimodal pore size distribution. Journal of the American Chemical Society , 2008, 130(15): 5262–5266 doi: 10.1021/ja710849r pmid:18348526
|
56 |
Kong A G, Zhu H Y, Wang W J, Zhang Q Y, Yang F, Shan Y K. Novel nanocasting method for synthesis of ordered mesoporous metal oxides. Journal of Porous Materials , 2011, 18(1): 107–112 doi: 10.1007/s10934-010-9361-9
|
57 |
Jiao F, Harrison A, Jumas J C, Chadwick A V, Kockelmann W, Bruce P G. Ordered mesoporous Fe2O3 with crystalline walls. Journal of the American Chemical Society , 2006, 128(16): 5468–5474 doi: 10.1021/ja0584774 pmid:16620119
|
58 |
Zhou Q, Li X, Li Y G, Tian B Z, Zhao D Y, Jiang Z Y. Synthesis and electrochemical properties of semicrystalline gyroidal mesoporous MnO2. Chinese Journal of Chemistry , 2006, 24(7): 835–839 doi: 10.1002/cjoc.200690159
|
59 |
Luo J Y, Xia Y Y. Effect of pore structure on the electrochemical capacitive performance of MnO2. Journal of the Electrochemical Society , 2007, 154(11): A987–A992 doi: 10.1149/1.2775167
|
60 |
Jiao F, Bruce P G. Mesoporous crystalline β-MnO2: a reversible positive electrode for rechargeable lithium batteries. Advanced Materials (Deerfield Beach, Fla.) , 2007, 19(5): 657–660 doi: 10.1002/adma.200602499
|
61 |
Chandru R A, Patra S, Oommen C, Munichandraiah N, Raghunandan B N. Exceptional activity of mesoporous β-MnO2 in the catalytic thermal sensitization of ammonium perchlorate. Journal of Materials Chemistry , 2012, 22(14): 6536–6538 doi: 10.1039/c2jm16169a
|
62 |
Du Y C, Meng Q, Wang J S, Yan J, Fan H G, Liu Y X, Dai H X. Three-dimensional mesoporous manganese oxides and cobalt oxides: highly-efficiency catalysts for the removal of toluene and carbon monoxide. Microporous and Mesoporous Materials , 2012, 162: 199–206 doi: 10.1016/j.micromeso.2012.06.030
|
63 |
Jiao F, Harrison A, Hill A H, Bruce P G. Mesoporous Mn2O3 and Mn3O4 with crystalline walls. Advanced Materials (Deerfield Beach, Fla.) , 2007, 19(22): 4063–4066 doi: 10.1002/adma.200700336
|
64 |
Jin M, Kim J W, Kim J M, Jurng J, Bae G N, Jeon J K, Park Y K. Effect of calcination temperature on the oxidation of benzene with ozone at low temperature over mesoporous α-Mn2O3. Powder Technology , 2011, 214(3): 458–462 doi: 10.1016/j.powtec.2011.08.046
|
65 |
Dickinson C, Zhou W Z, Hodgkins R, Shi Y F, Zhao D Y, He H Y. Formation mechanism of porous single-crystal Cr2O3 and Co3O4 templated by mesoporous silica. Chemistry of Materials , 2006, 18(13): 3088–3095 doi: 10.1021/cm060014p
|
66 |
Wang Y G, Yuan X H, Liu X H, Ren J W, Tong W Y, Wang Y Q, Lu G Z. Mesoporous single-crystal Cr2O3: Synthesis, characterization, and its activity in toluene removal. Solid State Sciences , 2008, 10(9): 1117–1123 doi: 10.1016/j.solidstatesciences.2007.11.018
|
67 |
Wang Y M, Wu Z Y, Wang H J, Zhu J H. Fabrication of metal oxides occluded in ordered mesoporous hosts via a solid-state grinding route: the influence of host-guest interactions. Advanced Functional Materials , 2006, 16(18): 2374–2386 doi: 10.1002/adfm.200500613
|
68 |
Wang G X, Liu H, Horvat J, Wang B, Qiao S Z, Park J, Ahn H. Highly ordered mesoporous cobalt oxide nanostructures: synthesis, characterisation, magnetic properties, and applications for electrochemical energy devices. Chemistry-A European Journal , 2010, 16(36): 11020–11027 doi: 10.1002/chem.201000562 pmid:20690118
|
69 |
Sun S J, Gao Q M, Wang H L, Zhu J K, Guo H L. Influence of textural parameters on the catalytic behavior for CO oxidation over ordered mesoporous Co3O4. Applied Catalysis B: Environmental , 2010, 97(1-2): 284–291 doi: 10.1016/j.apcatb.2010.04.016
|
70 |
Garcia T, Agouram S, Sánchez-Royo J, Murillo R, Mastral A M, Aranda A A, Vázquez I, Dejoz A, Solsona B. Deep oxidation of volatile organic compounds using ordered cobalt oxides prepared by a nanocasting route. Applied Catalysis A, General , 2010, 386(1-2): 16–27 doi: 10.1016/j.apcata.2010.07.018
|
71 |
Zhang Y H, Wang A Q, Huang Y Q, Xu Q Q, Yin J Z, Zhang T. Nanocasting synthesis of mesostructured Co3O4 via a supercritical CO2 deposition method and the catalytic performance for CO oxidation. Catalysis Letters , 2012, 142(2): 275–281 doi: 10.1007/s10562-011-0748-2
|
72 |
Zhou L, Ren Q J, Zhou X F, Tang J W, Chen Z H, Yu C Z. Comprehensive understanding on the formation of highly ordered mesoporous tungsten oxides by X-ray diffraction and Raman spectroscopy. Microporous and Mesoporous Materials , 2008, 109(1-3): 248–257 doi: 10.1016/j.micromeso.2007.04.054
|
73 |
Cui X Z, Zhang H, Dong X P, Chen H R, Zhang L X, Guo L M, Shi J L. Electrochemical catalytic activity for the hydrogen oxidation of mesoporous WO3 and WO3/C composites. Journal of Materials Chemistry , 2008, 18(30): 3575–3580 doi: 10.1039/b806115g
|
74 |
Yue W B, Xu X X, Irvine J T, Attidekou P S, Liu C, He H Y, Zhao D Y, Zhou W Z. Mesoporous monocrystalline TiO2 and its solid-state electrochemical properties and its solid-state electrochemical properties. Chemistry of Materials , 2009, 21(12): 2540–2546 doi: 10.1021/cm900197p
|
75 |
Yue W B, Randorn C, Attidekou P S, Su Z X, Irvine J T S, Zhou W Z. Synthesis, Li insertion, and photocatalytic of mesoporous crystalline TiO2. Advanced Functional Materials , 2009, 19(17): 2826–2833 doi: 10.1002/adfm.200900658
|
76 |
Ren Y, Hardwick L J, Bruce P G. Lithium intercalation into mesoporous anatase with an ordered 3D pore structure. Angewandte Chemie International Edition , 2010, 49(14): 2570–2574 doi: 10.1002/anie.200907099 pmid:20209547
|
77 |
Ren Y, Armstrong A R, Jiao F, Bruce P G. Influence of size on the rate of mesoporous electrodes for lithium batteries. Journal of the American Chemical Society , 2010, 132(3): 996–1004 doi: 10.1021/ja905488x pmid:20039669
|
78 |
Waitz T, Wagner T, Sauerwald T, Kohl C D, Tiemann M. Ordered mesoporous In2O3: synthesis by structure replication and application as a methane gas sensor. Advanced Functional Materials , 2009, 19(4): 653–661 doi: 10.1002/adfm.200801458
|
79 |
Shu P, Ruan J F, Gao C B, Li H C, Che S A. Formation of mesoporous Co3O4 replicas of different mesostructures with different pore sizes. Microporous and Mesoporous Materials , 2009, 123(1-3): 314–323 doi: 10.1016/j.micromeso.2009.04.017
|
80 |
Zheng M B, Cao J, Liao S T, Liu J S, Chen H Q, Zhao Y, Dai W J, Ji G B, Cao J M, Tao J. Preparation of mesoporous Co3O4 nanoparticles via solid-liquid route and effects of calcination temperature and textural parameters on their electrochemical capacitive behaviors. Journal of Physical Chemistry C , 2009, 113(9): 3887–3894 doi: 10.1021/jp810230d
|
81 |
Jin H X, Gu X J, Hong B, Lin L S, Wang C Y, Jin D F, Peng X L, Wang X Q, Ge H L. Fabrication of mesoporous Co3O4 from LP-FDU-12 via nanocasting poute and effect of wall/pore size on their magnetic properties. Journal of Physical Chemistry C , 2012, 116(24): 13374–13381 doi: 10.1021/jp300645c
|
82 |
Ren Y, Jiao F, Bruce P G. Tailoring the pore size/wall thickness of mesoporous transition metal oxides. Microporous and Mesoporous Materials , 2009, 121(1-3): 90–94 doi: 10.1016/j.micromeso.2009.01.008
|
83 |
Wang Y G, Wang Y Q, Ren J W, Mi Y, Zhang F Y, Li C L, Liu X H, Guo Y, Guo Y L, Lu G Z. Synthesis of morphology-controllable mesoporous Co3O4 and CeO2. Journal of Solid State Chemistry , 2010, 183(2): 277–284 doi: 10.1016/j.jssc.2009.11.009
|
84 |
Haffer S, Waitz T, Tiemann M. Mesoporous In2O3 with regular morphology by nanocasting: A simple relation between defined particle shape and growth mechanism. Journal of Physical Chemistry C , 2010, 114(5): 2075–2081 doi: 10.1021/jp910336f
|
85 |
Ma Z, Ren Y, Bruce P G. Co3O4-KIT-6 composite catalysts: Synthesis, characterization, and application in catalytic decomposition of N2O. Journal of Nanoparticle Research , 2012, 14(8): 874 doi: 10.1007/s11051-012-0874-9
|
86 |
Ren Y, Ma Z, Bruce P G. Ordered mesoporous NiMn2Ox with hematite or spinel structure: synthesis and application in electrochemical storage and catalytic conversion of N2O. CrystEngComm , 2011, 13(23): 6955–6959 doi: 10.1039/c1ce05972f
|
87 |
Ren Y, Ma Z, Bruce P G. Ordered mesoporous NiCoMnO4: synthesis and application in energy storage and catalytic decomposition of N2O. Journal of Materials Chemistry , 2012, 22(30): 15121–15127 doi: 10.1039/c2jm31644g
|
88 |
Jiao F, Bao J L, Hill A H, Bruce P G. Synthesis of ordered mesoporous Li-Mn-O spinel as a positive electrode for rechargeable lithium batteries. Angewandte Chemie International Edition , 2008, 47(50): 9711–9716 doi: 10.1002/anie.200803431 pmid:18989873
|
89 |
Jiao F, Jumas J C, Womes M, Chadwick A V, Harrison A, Bruce P G. Synthesis of ordered mesoporous Fe3O4 and γ-Fe2O3 with crystalline walls using post-template reduction/oxidation. Journal of the American Chemical Society , 2006, 128(39): 12905–12909 doi: 10.1021/ja063662i pmid:17002386
|
90 |
Ren Y, Bruce P G, Ma Z. Solid-solid conversion of ordered crystalline mesoporous metal oxides under reducing atmosphere. Journal of Materials Chemistry , 2011, 21(25): 9312–9318 doi: 10.1039/c1jm10336a
|
91 |
Tüysüz H, Liu Y, Weidenthaler C, Schüth F. Pseudomorphic transformation of highly ordered mesoporous Co3O4 to CoO via reduction with glycerol. Journal of the American Chemical Society , 2008, 130(43): 14108–14110 doi: 10.1021/ja806202v pmid:18826304
|
92 |
Tüysüz H, Weidenthaler C, Schüth F. A strategy for the synthesis of mesostructured metal oxides with lower oxidation states. Chemistry-A European Journal , 2012, 18(16): 5080–5086 doi: 10.1002/chem.201103650 pmid:22411225
|
93 |
Ren Y, Ma Z, Bruce P G. Transformation of mesoporous Cu/Cu2O into porous Cu2O nanowires in ethanol. CrystEngComm , 2012, 14(8): 2617–2620 doi: 10.1039/c2ce25045d
|
94 |
Tüysüz H, Salaba? E L, Bill E, Bongard H, Spliethoff B, Lehmann C W, Schüth F. Synthesis of hard magnetic ordered mesoporous Co3O4/CoFe2O4 nanocomposites. Chemistry of Materials , 2012, 24(13): 2493–2500 doi: 10.1021/cm3005166
|
95 |
Shi Y F, Wan Y, Zhang R Y, Zhao D Y. Synthesis of self-supported ordered mesoporous cobalt and chromium nitrides. Advanced Functional Materials , 2008, 18(16): 2436–2443 doi: 10.1002/adfm.200800488
|
96 |
Shi Y F, Guo B K, Corr S A, Shi Q H, Hu Y S, Heier K R, Chen L Q, Seshadri R, Stucky G D. Ordered mesoporous metallic MoO2 materials with highly reversible lithium storage capacity. Nano Letters , 2009, 9(12): 4215–4220 doi: 10.1021/nl902423a pmid:19775084
|
97 |
Kang E, An S, Yoon S, Kim J K, Lee J. Ordered mesoporous WO3-x possessing electronically conductive framework comparable to carbon framework toward long-term stable cathode supports for fuel cells. Journal of Materials Chemistry , 2010, 20(35): 7416–7421 doi: 10.1039/c0jm00227e
|
98 |
Yen H, Seo Y, Guillet-Nicolas R, Kaliaguine S, Kleitz F. One-step-impregnation hard templating synthesis of high-surface-area nanostructured mixed metal oxides (NiFe2O4, CuFe2O4 and Cu/CeO2). Chemical Communications , 2011, 47(37): 10473–10475 doi: 10.1039/c1cc13867g pmid:21858306
|
99 |
Wang Y G, Ren J W, Wang Y Q, Zhang F Y, Liu X H, Guo Y, Lu G Z. Nanocated synthesis of mesoporous LaCoO3 perovskite with extremely high surface area and excellent activity in methane combustion. Journal of Physical Chemistry C , 2008, 112(39): 15293–15298 doi: 10.1021/jp8048394
|
100 |
Wang Y G, Wang Y Q, Liu X H, Guo Y, Guo Y L, Lu G Z. Nanocasted synthesis of the mesostructured LaCoO3 perovskite and its catalytic activity in methane combustion. Journal of Nanoscience and Nanotechnology , 2009, 9(2): 933–936 doi: 10.1166/jnn.2009.C057 pmid:19441425
|
101 |
Nair M M, Kleitz F, Kaliaguine S. Kinetics of methanol oxidation over mesoporous perovskite catalysts. ChemCatChem , 2012, 4(3): 387–394 doi: 10.1002/cctc.201100356
|
102 |
Zhu J K, Gao Q M. Mesoporous MCo2O4 (M= Cu, Mn and Ni) spinels: Structural replication, characterization and catalytic application in CO oxidation. Microporous and Mesoporous Materials , 2009, 124(1-3): 144–152 doi: 10.1016/j.micromeso.2009.05.003
|
103 |
Cabo M, Pellicer E, Rossinyol E, Castell O, Suri?ach S, Baró M D. Mesoporous NiCo2O4 spinel: influence of calcination temperature over phase purity and thermal stability. Crystal Growth & Design , 2009, 9(11): 4814–4821 doi: 10.1021/cg900648q
|
104 |
Cabo M, Pellicer E, Rossinyol E, Solsona P, Castell O, Suri?ach S, Baró M D. Influence of the preparation method on the morphology of templated NiCo2O4 spinel. Journal of Nanoparticle Research , 2011, 13(9): 3671–3681 doi: 10.1007/s11051-011-0287-1
|
105 |
Ma C Y, Mu Z, He C, Li P, Li J J, Hao Z P. Catalytic oxidation of benzene over nanostructured porous Co3O4-CeO2 composite catalysts. Journal of Environmental Sciences (China) , 2011, 23(12): 2078–2086 pmid:22432341
|
106 |
Cabo M, Pellicer E, Rossinyol E, Estrader M, López-Ortega A, Nogués J, Castell O, Suri?ach S, Baró M D. Synthesis of compositionally graded nanocast NiO/NiCo2O4/Co3O4 mesoporous composites with tunable magnetic properties. Journal of Materials Chemistry , 2010, 20(33): 7021–7028 doi: 10.1039/c0jm00406e
|
107 |
Sun Y Y, Ji G B, Zheng M B, Chang X F, Li S D, Zhang Y. Synthesis and magnetic properties of crystalline mesoporous CoFe2O4 with large specific surface area. Journal of Materials Chemistry , 2010, 20(5): 945–952 doi: 10.1039/b919090b
|
108 |
Gu X, Zhu W M, Jia C J, Zhao R, Schmidt W, Wang Y Q. Synthesis and microwave absorbing properties of highly ordered mesoporous crystalline NiFe2O4. Chemical Communications , 2011, 47(18): 5337–5339 doi: 10.1039/c0cc05800a pmid:21445385
|
109 |
Hill M R, Booth J, Bourgeois L, Whitfield H J. Periodic mesoporous Lix(Mn1/3Ni1/3Co1/3)O2 spinel. Dalton Transactions (Cambridge, England) , 2010, 39(22): 5306–5309 doi: 10.1039/c005146m
|
110 |
Haruta M. Catalysis of gold nanoparticles deposited on metal oxides. CATTECH , 2002, 6(3): 102–115 doi: 10.1023/A:1020181423055
|
111 |
Ma Z, Dai S. Development of novel supported gold catalysts: A materials perspective. Nano Research , 2011, 4(1): 3–32 doi: 10.1007/s12274-010-0025-5
|
112 |
Ma Z, Dai S. Design of novel structured gold nanocatalysts. Acs Catalysis , 2011, 1(7): 805–818 doi: 10.1021/cs200100w
|
113 |
Zhu J K, Gao Q M, Chen Z. Preparation of mesoporous copper cerium bimetal oxides with high performance for catalytic oxidation of carbon monoxide. Applied Catalysis B: Environmental , 2008, 81(3-4): 236–243 doi: 10.1016/j.apcatb.2007.12.017
|
114 |
Ren Y, Ma Z, Qian L P, Dai S, He H Y, Bruce P G. Ordered crystalline mesoporous oxide as catalysts for CO oxidation. Catalysis Letters , 2009, 131(1-2): 146–154 doi: 10.1007/s10562-009-9931-0
|
115 |
Wang H J, Teng Y H, Radhakrishnan L, Nemoto Y, Imura M, Shimakawa Y, Yamauchi Y. Mesoporous Co3O4 for low temperature CO oxidation: effect of calcination temperatures on their catalytic performance. Journal of Nanoscience and Nanotechnology , 2011, 11(5): 3843–3850 doi: 10.1166/jnn.2011.3836 pmid:21780376
|
116 |
Tüysüz H, Lehmann C W, Bongard H, Tesche B, Schmidt R, Schüth F. Direct imaging of surface topology and pore system of ordered mesoporous silica (MCM-41, SBA-15, and KIT-6) and nanocast metal oxides by high resolution scanning electron microscopy. Journal of the American Chemical Society , 2008, 130(34): 11510–11517 doi: 10.1021/ja803362s pmid:18671351
|
117 |
Tüysüz H, Comotti M, Schüth F. Ordered mesoporous Co3O4 as highly active catalyst for low temperature CO-oxidation. Chemical Communications , 2008, (34): 4022–4024 doi: 10.1039/b808815b pmid:18758613
|
118 |
Xie X W, Li Y, Liu Z Q, Haruta M, Shen W J. Low-temperature oxidation of CO catalysed by Co3O4 nanorods. Nature , 2009, 458(7239): 746–749 doi: 10.1038/nature07877 pmid:19360084
|
119 |
Yu Y B, Takei T, Ohashi H, He H, Zhang X L, Haruta M. Pretreatments of Co3O4 at moderate temperature for CO oxidation at -80 °C. Journal of Catalysis , 2009, 267(2): 121–128 doi: 10.1016/j.jcat.2009.08.003
|
120 |
Kapteijn F, Rodriguez-Mirasol J, Moulijn J A. Heterogeneous catalytic decomposition of nitrous oxide. Applied Catalysis B: Environmental , 1996, 9: 25–64
|
121 |
Kannan S. Catalytic applications of hydrotalcite-like materials and their derived forms. Catalysis Surveys from Asia , 2006, 10(3-4): 117–137 doi: 10.1007/s10563-006-9012-y
|
122 |
Deng J G, Zhang L, Dai H X, Xia Y S, Jiang H Y, Zhang H, He H. Ultrasound-assisted nanocasting fabrication of ordered mesoporous MnO2 and Co3O4 with high surface areas and polycrystalline walls. Journal of Physical Chemistry C , 2010, 114(6): 2694–2700 doi: 10.1021/jp910159b
|
123 |
Xia Y S, Dai H X, Jiang H Y, Deng J G, He H, Au C T. Mesoporous chromia with ordered three-dimensional structures for the complete oxidation of toluene and ethyl acetate. Environmental Science & Technology , 2009, 43(21): 8355–8360 doi: 10.1021/es901908k pmid:19924969
|
124 |
Xia Y S, Dai H X, Zhang L, Deng J G, He H, Au C T. Ultrasound-assisted nanocasting fabrication and excellent catalytic performance of three-dimensionally ordered mesoporous chromia for the combustion of formaldehyde, acetone, and methanol. Applied Catalysis B: Environmental , 2010, 100(1-2): 229–237 doi: 10.1016/j.apcatb.2010.07.037
|
125 |
Xia Y S, Dai H X, Jiang H Y, Zhang L, Deng J G, Liu Y. Three-dimensionally ordered and wormhole-like mesoporous iron oxide catalysts highly active for the oxidation of acetone and methanol. Journal of Hazardous Materials , 2011, 186(1): 84–91 doi: 10.1016/j.jhazmat.2010.10.073 pmid:21131127
|
126 |
Ma C Y, Mu Z, Li J J, Jin Y G, Cheng J, Lu G Q, Hao Z P, Qiao S Z. Mesoporous Co3O4 and Au/Co3O4 catalysts for low-temperature oxidation of trace ethylene. Journal of the American Chemical Society , 2010, 132(8): 2608–2613 doi: 10.1021/ja906274t pmid:20141130
|
127 |
Ma C Y, Wang D H, Xue W J, Dou B J, Wang H L, Hao Z P. Investigation of formaldehyde oxidation over Co3O4-Ce2 and Au/Co3O4-CeO2 catalysts at room temperature: effective removal and determination of reaction mechanism. Environmental Science & Technology , 2011, 45(8): 3628–3634 doi: 10.1021/es104146v pmid:21375237
|
128 |
Aranda A, Puértolas B, Solsona B, Agouram S, Murillo R, Mastral A M, Taylor S H, Garcia T. Total oxidation of naphthalene using mesoporous CeO2 catalysts synthesized by nanocasting from two dimensional SBA-15 and three dimensional KIT-6 and MCM-48 silica templates. Catalysis Letters , 2010, 134(1-2): 110–117 doi: 10.1007/s10562-009-0203-9
|
129 |
Sun S M, Wang W Z, Zeng S Z, Shang M, Zhang L. Preparation of ordered mesoporous Ag/WO3 and its highly efficient degradation of acetaldehyde under visible-light irradiation. Journal of Hazardous Materials , 2010, 178(1-3): 427–433 doi: 10.1016/j.jhazmat.2010.01.098 pmid:20172648
|
130 |
Solsona B, Aylón E, Murillo R, Mastral A M, Monzonís A, Agouram S, Davies T E, Taylor S H, Garcia T. Deep oxidation of pollutants using gold deposited on a high surface area cobalt oxide prepared by a nanocasting route. Journal of Hazardous Materials , 2011, 187(1-3): 544–552 doi: 10.1016/j.jhazmat.2011.01.073 pmid:21315508
|
131 |
Ying F, Wang S J, Au C T, Lai S Y. Highly active and stable mesoporous Au/CeO2 catalysts prepared from MCM-48 hard-template. Microporous and Mesoporous Materials , 2011, 142(1): 308–315 doi: 10.1016/j.micromeso.2010.12.017
|
132 |
Djinovi? P, Batista J, Pintar A. Efficient catalytic abatement of greenhouse gases: Methane reforming with CO2 using a novel and thermally stable Rh-CeO2 catalyst. International Journal of Hydrogen Energy , 2012, 37(3): 2699–2707 doi: 10.1016/j.ijhydene.2011.10.107
|
133 |
Jin M, Park J N, Shon J K, Kim J H, Li Z H, Park Y K, Kim J M. Low temperature CO oxidation over Pd catalysts supported on highly ordered mesoporous metal oxides. Catalysis Today , 2012, 185(1): 183–190 doi: 10.1016/j.cattod.2011.09.019
|
134 |
Armatas G, Katsoulidis A P, Petrakis D E, Pomonis P J, Kanatzidis M G. Nanocasting of ordered mesoporous Co3O4-based polyoxometalate composite frameworks. Chemistry of Materials , 2010, 22(20): 5739–5746 doi: 10.1021/cm101972h
|
135 |
Tamiolakis I, Lykakis I N, Katsoulidis A P, Stratakis M, Armatas G S. Mesoporous Cr2O3-phosphomolybdic acid solid solution frameworks with high catalytic activity. Chemistry of Materials , 2011, 23(18): 4204–4211 doi: 10.1021/cm201547r
|
136 |
Tamiolakis I, Lykakis I N, Katsoulidis A P, Malliakas C D, Armatas G S. Ordered mesoporous Cr2O3 frameworks incorporating Keggin-type 12-phosphotungstic acids as efficient catalysts for oxidation of benzyl alcohols. Journal of Materials Chemistry , 2012, 22(14): 6919–6927 doi: 10.1039/c2jm16390j
|
137 |
Djinovi? P, Batista J, Levec J, Pintar A. Comparison of water-gas shift reaction activity and long-term stability of nanostructured CuO-CeO2 catalysts prepared by hard template and co-precipitation methods. Applied Catalysis A, General , 2009, 364(1-2): 156–165 doi: 10.1016/j.apcata.2009.05.044
|
138 |
Park J N, Shon J K, Jin M, Hwang S H, Park G O, Boo J H, Han T H, Kim J M. Highly ordered mesoporous α-MnO2 for catalytic decomposition of H2O2 at low temperatures. Chemistry Letters , 2010, 39(5): 493–494 doi: 10.1246/cl.2010.493
|
139 |
Cui X Z, Zhou J, Ye Z Q, Chen H R, Li L, Ruan M L, Shi J L. Selective catalytic oxidation of ammonia to nitrogen over mesoporous CuO/RuO2 synthesized by co-casting-replication method. Journal of Catalysis , 2010, 270(2): 310–317 doi: 10.1016/j.jcat.2010.01.005
|
140 |
Gong L, Sun L B, Sun Y H, Li T T, Liu X Q. Exploring in situ functionalization strategy in a hard template process: Preparation of sodium-modified mesoporous trtragonal zirconia with superbasicity. Journal of Physical Chemistry C , 2011, 115(23): 11633–11640 doi: 10.1021/jp2021165
|
141 |
Liu T T, Sun L B, Gong L, Liu X Y, Liu X Q. In situ generation of superbasic sites on mesoporous ceria and their application in transesterification. Journal of Molecular Catalysis A: Chemical , 2012, 352(1): 38–44 doi: 10.1016/j.molcata.2011.09.030
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|