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Effect of pressure on gasification reactivity of three Chinese coals with different ranks |
Chunyu LI1,2, Jiantao ZHAO1( ), Yitian FANG1( ), Yang WANG1 |
1. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China; 2. Graduate School of Chinese Academy of Sciences, Beijing 100039, China |
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Abstract The gasification reactivities of three kinds of different coal ranks (Huolinhe lignite, Shenmu bituminous coal, and Jincheng anthracite) with CO2 and H2O was carried out on a self-made pressurized fixed-bed reactor at increased pressures (up to 1.0 MPa). The physicochemical characteristics of the chars at various levels of carbon conversion were studied via scanning electron microscopy (SEM), X-ray diffraction (XRD), and BET surface area. Results show that the char gasification reactivity increases with increasing partial pressure. The gasification reaction is controlled by pore diffusion, the rate decreases with increasing total system pressure, and under chemical kinetic control there is no pressure dependence. In general, gasification rates decrease for coals of progressively higher rank. The experimental results could be well described by the shrinking core model for three chars during steam and CO2 gasification. The values of reaction order n with steam were 0.49, 0.46, 0.43, respectively. Meanwhile, the values of reaction order n with CO2 were 0.31, 0.28, 0.26, respectively. With the coal rank increasing, the pressure order m is higher, the activation energies increase slightly with steam, and the activation energy with CO2 increases noticeably. As the carbon conversion increases, the degree of graphitization is enhanced. The surface area of the gasified char increases rapidly with the progress of gasification and peaks at about 40% of char gasification.
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Keywords
coal
gasification
pressure
reaction order
shrinking core model
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Corresponding Author(s):
ZHAO Jiantao,Email:zhaojt@sxicc.ac.cn; FANG Yitian,Email:fyt@sxicc.ac.cn
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Issue Date: 05 December 2010
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1 |
Kajitani S, Suzuki N, Ashizawa M, Hara S. CO2 gasification rate analysis of coal char in entrained flow coal gasifier. Fuel , 2006, 85(2): 163-169 doi: 10.1016/j.fuel.2005.07.024
|
2 |
Huang J J, Fang Y T, Chen H S, Wang Y. Coal gasification characteristic in a pressurized fluidized bed. Energy & Fuels , 2003, 17(6): 1474-1479 doi: 10.1021/ef030052k
|
3 |
Liu G, Tate A G, Bryant G W, Wall T F. Mathematical modeling of coal char reactivity with CO2 at high pressures and temperatures. Fuel , 2000, 79(10): 1145-1154 doi: 10.1016/S0016-2361(99)00274-4
|
4 |
Kajitani S, Hara S, Matsuda H. Gasification rate analysis of coal char with a pressurized drop tube furnace. Fuel , 2002, 81(5): 539-546 doi: 10.1016/S0016-2361(01)00149-1
|
5 |
Muhlen H J, van Heek K H, Juntgen H. Influence of pretreatment temperature and pressure on the char reactivity during hydrogasification. Fuel , 1986, 65(4): 591-593 doi: 10.1016/0016-2361(86)90054-2
|
6 |
Li S, Xiao X. Influence of pretreatment temperature and pressure on the char reactivity during hydrogasification. Fuel , 1993, 72: 1351-1353
|
7 |
Li S, Sun R. Kinetic studies of a lignite char pressurized gasification with CO2, H2 and steam. Fuel , 1994, 73(3): 413-416 doi: 10.1016/0016-2361(94)90095-7
|
8 |
Bhatia K S, Perlmutter S D. A random pore model for fluid-solid reactions. I. Isothermal kinetic control. American Institute of Chemical Engineers , 1980, 26(3): 379-386
|
9 |
Liu G S, Niksa S. Coal conversion submodels for design applications at elevated pressures. Part II. Char gasification. Progress in Energy and Combustion Science , 2004, 30(6): 679-717 doi: 10.1016/j.pecs.2004.08.001
|
10 |
Li C Y, Zhao J T, Fang Y T, Wang Y. Pressurized fast-pyrolysis characteristics of typical Chinese coals with different ranks. Energy & Fuels , 2009, 23(10): 5099-5105 doi: 10.1021/ef900437h
|
11 |
Zhang L X, Huang J J, Fang Y T, Wang Y. Gasification reactivity and kinetics of typical Chinese anthracite chars with steam and CO2. Energy & Fuels , 2006, 20(3): 1201-1210 doi: 10.1021/ef050343o
|
12 |
Ahn D H, Gibbs B M, Ko K H, Kim J J. Gasification kinetics of an Indonesian subbituminous coal char with CO2 at elevated pressure. Fuel , 2001, 80(11): 1651-1658 doi: 10.1016/S0016-2361(01)00024-2
|
13 |
Linares-Solano A, Mahajan O P, Walker P Jr. Reactivity of heat-treated coals in steam. Fuel , 1979, 58(5): 327-332 doi: 10.1016/0016-2361(79)90148-0
|
14 |
Liu T F, Fang Y T, Wang Y. An experimental investigation into the gasification reactivity of chars prepared at high temperatures. Fuel , 2008, 87(4-5): 460-466 doi: 10.1016/j.fuel.2007.06.019
|
15 |
Jüntgen H. Reactivities of carbon to steam and hydrogen and applications to technical gasification processes—A review. Carbon , 1981, 19(3): 167-173 doi: 10.1016/0008-6223(81)90039-7
|
16 |
Goyal A, Zabransky R F, Rehmat A. Gasification kinetics of Western Kentucky bituminous coal char. Industrial & Engineering Chemistry Research , 1989, 28(12): 1767-1778 doi: 10.1021/ie00096a006
|
17 |
Jones R B, Mccourt C B, Morley C, King K. Maceral and rank influences on the morphology of coal char. Fuel , 1985, 64(10): 1460-1467 doi: 10.1016/0016-2361(85)90351-5
|
18 |
Hurt R H, Davis K A, Yang N Y C, Headley T J, Mitchell G D. Residual carbon from pulverized-coal-fired boilers. 2. Morphology and physicochemical properties. Fuel , 1995, 74(9): 1297-1306 doi: 10.1016/0016-2361(95)00100-J
|
19 |
Sadhukhan A K, Gupta P, Saha R K. Characterization of porous structure of coal char from a single devolatilized coal particle: Coal combustion in a fluidized bed. Fuel Processing Technology , 2009, 90(5): 692-700 doi: 10.1016/j.fuproc.2008.12.010
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