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Frontiers of Chemical Science and Engineering

ISSN 2095-0179

ISSN 2095-0187(Online)

CN 11-5981/TQ

Postal Subscription Code 80-969

2018 Impact Factor: 2.809

Front Chem Sci Eng    2013, Vol. 7 Issue (1) : 43-48    https://doi.org/10.1007/s11705-013-1309-6
RESEARCH ARTICLE
Importance of emulsions in crystallization—applications for fat crystallization
Sandra PETERSEN(), K. CHALEEPA, Joachim ULRICH
Center for Engineering Science, Thermal Process Engineering, Martin Luther University Halle-Wittenberg, D-06099 Halle (Saale), Germany
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Abstract

Emulsions and crystallization are two independent research topics which normally do not overlap although a combination of the two could be applicable to many areas. Here, the importance of emulsions in the field of fat crystallization is described. Three applications with industrial relevance were chosen for investigation: fat fractionation, the solidification of phase change materials and solid lipid nanoparticles. For fat fractionation and phase change materials, emulsification can be applied as a tool to improve the fat crystallization process, and thus the product quality of the crystallized fat. Furthermore, the use of emulsification creates new application fields such as solid lipid nanoparticles in the area of fat crystallization.

Keywords emulsion      fat crystallization      phase change material      emulsion fractionation      emulsion solidification     
Corresponding Author(s): PETERSEN Sandra,Email:sandra.petersen@iw.uni-halle.de   
Issue Date: 05 March 2013
 Cite this article:   
Sandra PETERSEN,K. CHALEEPA,Joachim ULRICH. Importance of emulsions in crystallization—applications for fat crystallization[J]. Front Chem Sci Eng, 2013, 7(1): 43-48.
 URL:  
https://academic.hep.com.cn/fcse/EN/10.1007/s11705-013-1309-6
https://academic.hep.com.cn/fcse/EN/Y2013/V7/I1/43
Fig.1  (a) Viscosity of pure coconut oil (Cto), coconut oil with 1% sucrose laurate (L-195) and different water-in-oil emulsions (1% L-195 and various amounts of water); (b) Crystal morphology of coconut stearin obtained by dry fractionation without emulsifier; (c) Crystal morphology of coconut stearin from dry fractionation with emulsifier
Fig.1  (a) Viscosity of pure coconut oil (Cto), coconut oil with 1% sucrose laurate (L-195) and different water-in-oil emulsions (1% L-195 and various amounts of water); (b) Crystal morphology of coconut stearin obtained by dry fractionation without emulsifier; (c) Crystal morphology of coconut stearin from dry fractionation with emulsifier
Fig.2  Resulting melting points and solid fat contents of the fractionated stearin obtained by (b, c) dry fractionation and (d–f) emulsion fractionation in comparison to (a) the initial coconut oil.
Fig.2  Resulting melting points and solid fat contents of the fractionated stearin obtained by (b, c) dry fractionation and (d–f) emulsion fractionation in comparison to (a) the initial coconut oil.
Fig.3  Diameter of the solidified particles produced by emulsion solidification depending on (a) water content of the emulsion and (b) concentration of Span 20 []
Fig.3  Diameter of the solidified particles produced by emulsion solidification depending on (a) water content of the emulsion and (b) concentration of Span 20 []
Rotational speed /(r?min-1)Mean droplet size/μm(number-based)
800012.32
950010.15
135009.23
205009.21
Tab.1  Influence of the rotational speed of the Ultra-Turrax mixer on the mean droplet size of the emulsion []
Fig.4  Influence of the emulsion production conditions on the diameter and roundness of PCM particles
Fig.4  Influence of the emulsion production conditions on the diameter and roundness of PCM particles
Fig.5  Influence of the emulsifier type and concentration on the mean droplet size of oil-in-water emulsions produced by (a) disc systems and (b) high-pressure homogenization
Fig.5  Influence of the emulsifier type and concentration on the mean droplet size of oil-in-water emulsions produced by (a) disc systems and (b) high-pressure homogenization
1 Zaliha O, Chong C L, Cheow C S, Norizzah A R, Kellens M J. Crystallization properties of palm oil by dry fractionation. Food Chemistry , 2004, 86(2): 245–250
doi: 10.1016/j.foodchem.2003.09.032
2 Arnaud E, Relkin P, Pina M, Collignan A. Characterisation of chicken fat dry fractionation at the pilot scale. European Journal of Lipid Science and Technology , 2004, 106(9): 591–598
doi: 10.1002/ejlt.200400946
3 Chaleepa K, Szepes A, Ulrich J. Dry fractionation of coconut oil by melt crystallization. ChERD , 2010, 88(9): 1217–1222
4 Kellens M, Gibon V, Hendrix M, de Greyt W. Palm oil fractionation. European Journal of Lipid Science and Technology , 2007, 109(4): 336–349
doi: 10.1002/ejlt.200600309
5 Chaleepa K, Ulrich J. Emulsion fractionation of coconut oil: a new fractionation technology. Chemical Engineering & Technology , 2011, 34(4): 557–562
doi: 10.1002/ceat.201000485
6 Tiedtke M. Die Fraktionierung von Milchfett- Ein neues Einsatzgebiet für die Schichtkristallisation. Dissertation for the Doctoral Degree . Aachen: University of Bremen, 1997
7 Ulrich J, Neumann M. Purification by solid layer melt crystallization. Journal of Thermal Analysis , 1997, 48(3): 527–533
doi: 10.1007/BF01979499
8 Chaleepa K. A new concept in layer-based fractional crystallization processes. Dissertation for the Doctoral Degree . Halle: Martin Luther University Halle-Wittenberg, 2010, p-p?
9 Velraj R, Seeniraj R V, Hafner B, Faber C, Schwarzer K. Heat transfer enhancement in a latent heat storage system. Solar Energy , 1999, 65(3): 171–180
doi: 10.1016/S0038-092X(98)00128-5
10 Nakao Y, Hishida M, Tanaka G, Shiina Y. Solidification characteristics of rising immiscible oil droplets in coolant. International Journal of Heat and Mass Transfer , 2004, 47(24): 5339–5349
doi: 10.1016/j.ijheatmasstransfer.2004.05.036
11 Iqbal J, Ulrich J. Spherical-particle generation by phase change materials: Near-monosize particles from emulsions. Chemical Engineering & Technology , 2010, 33(6): 1011–1014
12 Iqbal J, Petersen S, Ulrich J. Emulsion Solidification: Influence of the Droplet Size of the Water-in-Oil Emulsion on the Generated Particle Size. Chemical Engineering & Technology , 2011, 34(4): 530–534
doi: 10.1002/ceat.201000449
13 Weiss J, Decker E, McClements D, Kristbergsson K, Helgason T, Awad T. Solid Lipid Nanoparticles as Delivery Systems for Bioactive Food Components. In: Food Biophysics, Volume 3 . New York: Springer, 2008, 146–154
14 Müller R H, M?der K, Gohla S. Solid lipid nanoparticles (SLN) for controlled drug delivery—a review of the state of the art. European Journal of Pharmaceutics and Biopharmaceutics , 2000, 50(1): 161–177
doi: 10.1016/S0939-6411(00)00087-4
15 Jenning V, Lippacher A, Gohla S H. Medium scale production of solid lipid nanoparticles (SLN) by high pressure homogenization. Journal of Microencapsulation , 2002, 19(1): 1–10
doi: 10.1080/713817583
16 Bunjes H, Koch M H J, Westesen K. Influence of emulsifiers on the crystallization of solid lipid nanoparticles. Journal of Pharmaceutical Sciences , 2003, 92(7): 1509–1520
doi: 10.1002/jps.10413
17 Petersen S, Ulrich J. Effectiveness of polyoxyethylene nonionic emulsifiers in emulsification processes using disc systems. Chemical Engineering & Technology , 2011, 34(11): 1869–1875
doi: 10.1002/ceat.201100257
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