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Frontiers in Energy

ISSN 2095-1701

ISSN 2095-1698(Online)

CN 11-6017/TK

Postal Subscription Code 80-972

2018 Impact Factor: 1.701

Front. Energy    2016, Vol. 10 Issue (3) : 363-374    https://doi.org/10.1007/s11708-016-0397-7
REVIEW ARTICLE
A review of cryogenic power generation cycles with liquefied natural gas cold energy utilization
Feier XUE1,Yu CHEN2,Yonglin JU1,*()
1. Institute of Refrigeration and Cryogenics, Shanghai Jiao Tong University, Shanghai 200240, China
2. College of Mechanical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
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Abstract

Liquefied natural gas (LNG), an increasingly widely applied clean fuel, releases a large number of cold energy in its regasification process. In the present paper, the existing power generation cycles utilizing LNG cold energy are introduced and summarized. The direction of cycle improvement can be divided into the key factors affecting basic power generation cycles and the structural enhancement of cycles utilizing LNG cold energy. The former includes the effects of LNG-side parameters, working fluids, and inlet and outlet thermodynamic parameters of equipment, while the latter is based on Rankine cycle, Brayton cycle, Kalina cycle and their compound cycles. In the present paper, the diversities of cryogenic power generation cycles utilizing LNG cold energy are discussed and analyzed. It is pointed out that further researches should focus on the selection and component matching of organic mixed working fluids and the combination of process simulation and experimental investigation, etc.

Keywords liquefied natural gas (LNG) cold energy      power generation cycle      Rankine cycle      compound cycle     
Corresponding Author(s): Yonglin JU   
Just Accepted Date: 06 January 2016   Online First Date: 25 January 2016    Issue Date: 07 September 2016
 Cite this article:   
Feier XUE,Yu CHEN,Yonglin JU. A review of cryogenic power generation cycles with liquefied natural gas cold energy utilization[J]. Front. Energy, 2016, 10(3): 363-374.
 URL:  
https://academic.hep.com.cn/fie/EN/10.1007/s11708-016-0397-7
https://academic.hep.com.cn/fie/EN/Y2016/V10/I3/363
Fig.1  Schematic diagram of direct expansion of LNG
Fig.2  Schematic diagram of Rankin cycle
Fig.3  Schematic diagram of Rankine cycle with direct expansion of LNG
Fig.4  Schematic diagram of the regenerative Rankine cycle with direct expansion of LNG [19]
Fig.5  Schematic diagram of CO2 regenerative Rankine cycle [20]
Fig.6  Schematic diagram of two-stage Rankine cycle of horizontal [21]
Fig.7  Schematic diagram of three-stage Rankine cycle of vertical [21]
Fig.8  Schematic diagram of three-stage cascade Rankine cycle [22]
Type enhanced Researchers Structural description Working fluid Heat source Cycle characteristics
RC a) Rao et al. [15] RC Ethane Residual heat When the temperature of heat source is below 260°C and LNG vaporizing pressure is greater than a certain value, auxiliary heat source should be applied for LNG regasification in case of insufficient heat transfer in the condenser.
Wang et al. [14] RC Ammonia-water Residual heat Cycle uses HRVGb) instead of general vaporizer to enhance turbine inlet temperature of ammonia steam.
The combined cycle Miyazaki et al. [12] RC+DEC c) Ammonia-water Exhaust gas Temperature glide occurred in heat transfer process in the condenser between ammonia-water and LNG effectively reduces heat loss.
Bai [4] RC+DEC Ethane Residual heat Working medium compressed by the pump exchanges heat with cold water and waste heat successively; cooling capacity obtained by cold water can be used for air conditioning system or compressor cooling, etc. Two-stage heat exchanging improves the turbine inlet temperature.
Cao and Lu [23] RC+DEC Propane Seawater Working medium propane vaporized by seawater is shunt for two strands, one of which drives Rankine cycle and the other directly transfers heat to LNG out of the condenser; both strands get remixed through mixer and fed into working medium pump.
Wang et al. [24] Trans critical RC+DEC CO2 Geothermic heat After absorbing the heat from geothermic water, CO2 is fed into the turbine to export electrical power; LNG heated by CO2 and the ambient, in gas state is also sent into the NG turbine to do work.
Sun et al. [25] RC+DEC Propylene Solar energy Water heated by solar energy and assistant electric heater provides heat needed for the system. Propylene completes Rankine cycle as working fluid.
Installing regenerator Sun et al. [26] Regenerative RC+DEC Mixture(methane: ethylene: propane mol%=0.3:0.4:0.3) Residual heat MSCHE (multi-stream cryogenic heat exchanger) is used to substitute conventional vaporizer in the cycle. In MSCHE, LNG through the first channel releases a large amount of cold; boosted mixed working medium sent into the second channel gains cold energy then completes heat transfer to refrigerant and external heat source respectively and expands to output power; high-temperature gas from medium turbine outlet goes into the third channel as a hot fluid to release heat. In addition, cold energy obtained by the refrigerant from mixed medium will be supplied to the air conditioning system.
Wang [5] Regenerative RC+DEC Mixture (propane and isobutane) Exhaust gas Working medium is vaporized by regenerator and exhaust gas heater in succession, which effectively realizes utilization of exhaust gas waste heat and reduces condenser loads.
Poly-stage RC Yang [21] 3-stage RC of horizontal Ethane/Ethane/propylene Seawater Considering three-stage recovery of LNG cold energy, LNG successively acts as cold fluid for left ethane RC, central ethane RC and right propylene RC. Three loops from left to right operate individually and in each loop two-stage expansion is achieved by working medium with intermediate heat absorption from seawater.
Cao et al. [27] 2-stage RC of horizontal+DEC CO2/R245fa(CF3CH2CHF2) Residual heat LNG serves as the heat sink for super-critical CO2 Rankine cycle and R245fa Rankine cycle while residual heat provides requisite heat in the opposite order.
Zhu et al. [28] 2-stage RC of vertical Ethylene/propane Exhaust gas Lower ethylene Rankine cycle and upper propane Rankine cycle are linked through ethylene-propane heat exchanger where ethylene is vaporized and propane is condensed. Additionally, a strand of stream from propane turbine is elicited to heat LNG out of ethylene condenser and fed to propane pump in liquid state.
Yang [21] 2- stage regenerative RC of vertical Propylene / ethylene Seawater Ethylene, the working fluid of the upper Rankine cycle, is divided into three shares after expansion, one of which is directly used for LNG regasification, and two remaining shares supply needed heat for two-stage expansion in the lower propylene Rankine cycle, which makes up the systematic defect of insufficient work output.
Tab.1  A brief summary of main structures of enhanced Rankine cycles
Fig.9  Schematic diagram of Brayton cycle with direct expansion of LNG
Fig.10  Schematic diagram of the regenerative Brayton cycle with direct expansion of LNG [29]
Fig.11  Schematic diagram of improved Brayton cycle with direct expansion of LNG [30]
Fig.12  Schematic diagram of two-Stage Brayton cycle [34]
Researchers Structural description Working fluids Heat source Utilization efficiency of available energy/%
Liu and Guo [37] KC Mixture (ethylene: propane mol% = 0.60:0.40) Seawater 25.3
Liu and Guo [38] KC Mixture (trafluoromethane: propane mol% = 0.73:0.27) Seawater 23.5
Bai [4] KCa) + DECb) Mixture (trafluoromethane: propane mol% = 0.73:0.27) Industrial waste heat 24.0
Shi and Che [39] KC+ DEC Mixture (ammonia: water mass% = 0.50:0.50) Industrial waste heat 33.28
Wang et al. [36] KC+ DEC Mixture (ammonia: water mass% = 0.52:0.48) Industrial waste heat 39.33
Tab.2  Summary of main structures of Kalina cycles
Fig.13  Schematic diagram of Kalina cycle with direct expansion of LNG [36]
Researchers Structural description Working fluids Heat source Utilization efficiency of available energy/%
Xia et al. [40] BCa) + regenerative RCb) + DECc) Nitrogen/ammonia-water Industrial waste heat 51.04
Lu and Wang [41] RC+ DEC+ gas turbine Exhaust gas/ammonia-water Heat of combustion
Zhang and Lior [42] Super-critical RC+ BC CO2/CO2 Heat of combustion 50
Shi et al. [43] RC+ DEC+ gas turbine Exhaust gas/water vapor Heat of combustion 59.24
Najjar [44] RC+ 2-stage DEC+ gas turbine Propane/exhaust gas Seawater-heat of combustion 35.84
Hisazumi et al. [2] 2-stage RC+ gas turbine+ 2-stage DEC Freon/water vapor/exhaust gas Heat of combustion 56
Tomków and cholewiński [34] RC+ KCd) Propane/mixture of krypton and ethane Seawater 18.8
Tab.3  Summary of main structures of compound cycles
Fig.14  Schematic diagram of integration of Rankine cycle and Brayton cycle [42]
Fig.15  Schematic diagram of integration of Kalina cycle and Rankine cycle [34]
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