Oxidation-extraction desulfurization of model oil over Zr-ZSM-5/SBA-15 and kinetic study

doi:10.1007/s11705-014-1420-3

Front. Chem. Sci. Eng.

2014, Vol. 8

Issue (2) : 203-211 https://doi.org/10.1007/s11705-014-1420-3

RESEARCH ARTICLE

Oxidation-extraction desulfurization of model oil over Zr-ZSM-5/SBA-15 and kinetic study

Chuanzhu LU,Hui FU,Huipeng LI(

),Hua ZHAO,Tianfeng CAI

School of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China

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Abstract

ZSM-5/SBA-15 composite molecular sieves were synthesized using post-synthesis method and characterized by X-ray diffraction and N₂ adsorption-desorption. The oxidative-extration desulfurization of model oil was investigated by using hydrogen peroxide as the oxidant, tetrabutyl ammonium bromide as phase transfer catalyst, dimethyl sulfoxide as extractant, and Zr-ZSM-5/SBA-15, Ag-ZSM-5/SBA-15, Ce-ZSM-5/SBA-15 as catalyst. Under the optimal conditions, the desulfurization rate decreases in the order: Zr-ZSM-5/SBA-15>Ce-ZSM-5/SBA-15>Ag-ZSM-5/SBA-15. The highest desulfurization rate is 84.53% under the catalysis of Zr-ZSM-5/SBA-15. Kinetics analysis shows that the reaction is pseudo-first-order with the activation energy of 44.23 kJ/mol.

Keywords composite molecular sieve oxidation desulfuration extraction kinetic

Corresponding Author(s): Huipeng LI

Issue Date: 22 May 2014

Cite this article:

Tianfeng CAI,Chuanzhu LU,Hui FU, et al. Oxidation-extraction desulfurization of model oil over Zr-ZSM-5/SBA-15 and kinetic study[J]. Front. Chem. Sci. Eng., 2014, 8(2): 203-211.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-014-1420-3
https://academic.hep.com.cn/fcse/EN/Y2014/V8/I2/203

Fig.1 (a) Small angle and (b) wide angle XRD patterns of SBA-15, ZSM-5/SBA-15 and Zr-ZSM-5/SBA-15

Fig.2 Adsorption-desorption isotherms of ZSM-5/SBA-15 and Zr(20%)-ZSM-5/SBA-15

Fig.3 The influence of different catalysts on desulfurization rate

Fig.4 The influence of different catalysts loaded by Zr on desulfurization rate

Fig.5 The influence of different metal modified ZSM-5/SBA-15 on desulfurization rate

Fig.6 The effects of (a) reaction temperature, (b) reaction time, (c) the dosage of oxidant and (d) ratio of catalyst to oil on the desulfurization rate

Tab.1 Factors and levels of L₉(3⁴) orthogonal test*

Tab.2 Arrangement and results of L₉(3⁴) orthogonal test

Tab.3 Influence of the different methods on desulfurization rate

Fig.7 The influence of catalyst used times on desulfurization rate

Tab.4 Reaction kinetic parameters under different temperatures

Fig.8 The activation energy of the reaction

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