Novel Ag-AgBr decorated composite membrane for dye rejection and photodegradation under visible light

doi:10.1007/s11705-020-2011-0

Front. Chem. Sci. Eng.

2021, Vol. 15

Issue (4) : 892-901 https://doi.org/10.1007/s11705-020-2011-0

RESEARCH ARTICLE

Novel Ag-AgBr decorated composite membrane for dye rejection and photodegradation under visible light

Yixing Wang, Liheng Dai, Kai Qu, Lu Qin, Linzhou Zhuang, Hu Yang, Zhi Xu(

)

State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

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Abstract

Photocatalytic membranes have received increasing attention due to their excellent separation and photodegradation of organic contaminants in wastewater. Herein, we bound Ag-AgBr nanoparticles onto a synthesized polyacrylonitrile-ethanolamine (PAN-ETA) membrane with the aid of a chitosan (CS)-TiO₂ layer via vacuum filtration and in-situ partial reduction. The introduction of the CS-TiO₂ layer improved surface hydrophilicity and provided attachment sites for the Ag-AgBr nanoparticles. The PAN-ETA/CS-TiO₂/Ag-AgBr photocatalytic membranes showed a relatively high water permeation flux (~ 47 L·m^–2·h^–1·bar^–1) and dyes rejection (methyl orange: 88.22%; congo red: 95%; methyl blue: 97.41%; rose bengal: 99.98%). Additionally, the composite membranes exhibited potential long-term stability for dye/salt separation (dye rejection: ~97%; salt rejection: ~6.5%). Moreover, the methylene blue and rhodamine B solutions (20 mL, 10 mg·L⁻¹) were degraded approximately 90.75% and 96.81% in batch mode via the synthesized photocatalytic membranes under visible light irradiation for 30 min. This study provides a feasible method for the combination of polymeric membranes and inorganic catalytic materials.

Keywords Ag-AgBr dye rejection photodegradation visible light

Corresponding Author(s): Zhi Xu

Just Accepted Date: 08 January 2021 Online First Date: 22 March 2021 Issue Date: 04 June 2021

Cite this article:

Yixing Wang,Liheng Dai,Kai Qu, et al. Novel Ag-AgBr decorated composite membrane for dye rejection and photodegradation under visible light[J]. Front. Chem. Sci. Eng., 2021, 15(4): 892-901.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-020-2011-0
https://academic.hep.com.cn/fcse/EN/Y2021/V15/I4/892

Fig.1 Scheme 1 Schematic for the fabrication of PAN-ETA/CS-TiO₂/Ag-AgBr membrane.

Fig.2 Surface images of the as-prepared membranes: (a) PAN-ETA, (b) PAN-ETA/CS-TiO₂ and (c) PAN-ETA/CS-TiO₂/Ag-AgBr.

Fig.3 (a) XRD patterns and (b) ATR-FTIR spectra of the as-prepared membrane.

Fig.4 (a) XPS survey of the as-prepared membranes and (b) Ag 3d high resolution spectra.

Fig.5 Water contact angle of the as-prepared membrane.

Fig.6 (a) Water flux and dye rejection of the as-prepared membranes; (b) Various dyes rejection of the PAN-ETA/CS-TiO₂/Ag-AgBr membrane.

Fig.7 Long-time stability of the PAN-ETA/CS-TiO₂/Ag-AgBr membrane.

Fig.8 The color change of RhB and MB solutions under photocatalysis using the PAN-ETA/CS-TiO₂/Ag-AgBr membrane with time from 0 min to 30 min.

Fig.9 (a) Plots of dyes degradation efficiency vs. irradiation time; (b) the corresponding kinetic linear simulation curves; (c) degradation performance (%) and (d) recycle degradation efficiency (%).

Tab.1 Comparison of the photodegradation performance of different membranes

Fig.10 Possible photocatalytic degradation mechanism of dye pollutants over Ag-AgBr nanoparticles under visible light irradiation.

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