Pesticides in stormwater runoff−A mini review

doi:10.1007/s11783-019-1150-3

Front. Environ. Sci. Eng.

2019, Vol. 13

Issue (5) : 72 https://doi.org/10.1007/s11783-019-1150-3

REVIEW ARTICLE

Pesticides in stormwater runoff−A mini review

Cheng Chen, Wenshan Guo, Huu Hao Ngo(

)

Centre for Technology in Water and Wastewater, School of Civil and Environmental Engineering, University of Technology Sydney, Sydney NSW 2007, Australia

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Abstract

• The sources and pathways of pesticides into stormwater runoff were diverse.

• Factors affecting pesticides in stormwater runoff were critically reviewed.

• Pesticides mitigation strategies were included in this review.

• The current knowledge gap of the pesticides in stormwater runoff was identified.

Recently, scientific interest has grown in harvesting and treating stormwater for potable water use, in order to combat the serious global water scarcity issue. In this context, pesticides have been identified as the key knowledge gap as far as reusing stormwater is concerned. This paper reviewed the presence of pesticides in stormwater runoff in both rural and urban areas. Specifically, the sources of pesticide contamination and possible pathways were investigated in this review. Influential factors affecting pesticides in stormwater runoff were critically identified as: 1) characteristics of precipitation, 2) properties of pesticide, 3) patterns of pesticides use, and 4) properties of application surface. The available pesticide mitigation strategies including best management practice (BMP), low impact development (LID), green infrastructure (GI) and sponge city (SC) were also included in this paper. In the future, large-scale multi-catchment studies that directly evaluate pesticide concentrations in both urban and rural stormwater runoff will be of great importance for the development of effective pesticides treatment approaches and stormwater harvesting strategies.

Keywords Pesticide Stormwater runoff Occurrence Urban runoff

Corresponding Author(s): Huu Hao Ngo

Issue Date: 23 September 2019

Cite this article:

Cheng Chen,Wenshan Guo,Huu Hao Ngo. Pesticides in stormwater runoff−A mini review[J]. Front. Environ. Sci. Eng., 2019, 13(5): 72.

URL:

https://academic.hep.com.cn/fese/EN/10.1007/s11783-019-1150-3
https://academic.hep.com.cn/fese/EN/Y2019/V13/I5/72

Fig.1 The sources and pathways of pesticides into stormwater runoff.

Factors	The effects on pesticides in stormwater runoff	Reference
Precipitation characteristics	For a given pesticide and site, the most vital factors in determining seasonal herbicide lost in stormwater runoff were the timing and intensity of the first storm following application, affecting total seasonal runoff by up to 2 orders of magnitude.	Huang et al.(^2004a, ^2004b)
	The rainfall intensity played an important role in determining pesticide concentrations in stormwater runoff from soil surface.	^{Müller et al. (2004)}; ^{Revitt et al. (2002)}
	A 10-fold increase in the application loss of isoproturon was observed in response to a 4-fold increase in rainfall intensity.	^{Johnson (1995)}
	Precipitation intensity had little effect on the pyrethroid concentrations in runoff on hardened concrete surface.	^{Jiang et al. (2012;} ^{Jorgenson and Young (2010)}
Pesticide fate properties	The herbicide runoff rates were correlated fairly well with octanol-water partition coefficient (log K_ow), rather than with water solubility of herbicides	^{Nakano et al. (2004)}
Pesticide fate properties	Pesticide concentration was determined by formulation and solubility, and the physiochemical properties that decides a compound’s persistence.	^{Willis and McDowell (1982)}
Pesticides use pattern	For rain and roof runoff, maximum pesticide concentrations originating primarily from agricultural use occurred during and right after the application periods.	^{Bucheli et al. (1998a)}
	For a given pesticide and site, the most vital factors in determining seasonal herbicide lost in stormwater runoff were the timing and intensity of the first storm following application, affecting total seasonal runoff by up to 2 orders of magnitude.	^{Huang et al. (2004b)}
	Highest number and concentrations of pesticides were detected at the end of spring and through summer, which are consistent with treatment periods and higher temperatures.	^{Vialle et al. (2013)}
	For concrete slabs subjected to natural rainfalls during the winter wet season, pesticide levels in the runoff decreased as the time interval between pesticide application and the rain event increased.	^{Jiang et al. (2012)}
	Pesticide concentrations were higher in an initial spring storm event following applications to control weeds and insects.	^{Hudak and Banks (2006)}
	Spray drift can result in subsequent rain events washing pesticides off trees in buffer zones leading to higher concentrations in nearby stormwater runoff. Spray drift associated with volatilization may cause pesticides deposition in the atmosphere, resulting in substantial amounts in rainwater far from application sites.	^{Glinski et al. (2018)}
	Compared to insecticides and herbicides, fungicides were more frequently detected in US, because of their more frequent, intensive application schedules in spite of lower application rates.	^{Battaglin et al. (2016)}
	Pesticide concentrations tend to follow seasonal trends with lower concentrations in winter and after crop harvesting and higher concentrations detected during periods of heavy use.	^{Konstantinou et al. (2006)}
Properties of the application surface	More variations in pesticide concentrations throughout the storm hydrograph were observed for samples of agricultural runoff than samples of urban runoff.	^{Kratzer (1988)}
	Higher pesticide concentrations were observed in runoff waters collected from roofs covered with galvanized sheet metal and ceramic tiles.	^{Polkowska et al. (2009)}
	Depending on the nature of roofing material used for rainwater collection, stormwater runoff can be contaminated with mecoprop, which is a roof protecting agent.	^{Vialle et al. (2013)}
	The dry nature of the urban catchment at the time of the storm can result in low runoff volumes and peak flow values. A catchment with a high proportion of impervious surface area generates greater urban runoff.	^{Revitt et al. (2002)}
	Runoff from highly urbanized watersheds can carry a substantial amount of OCPs and be potentially dangerous to urban water systems.	^{Zhang et al. (2011)}
	The runoff transferability of pyrethroid residues from concrete is not significantly affected by concrete surface conditions	^{Jiang et al. (2012)}
	Densely populated areas in urban watersheds with a high factor of impervious surfaces produce the highest amount of synthetic pyrethroids (SPs) runoff.	^{Chinen et al. (2016)}
	Catchment with a significant soil moisture deficit generates low runoff volumes.	^{Revitt et al. (2002)}

Tab.1 A summary of influential factors on the pesticides in stormwater runoff

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