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Frontiers in Energy

ISSN 2095-1701

ISSN 2095-1698(Online)

CN 11-6017/TK

Postal Subscription Code 80-972

2018 Impact Factor: 1.701

Front. Energy    2018, Vol. 12 Issue (2) : 276-296    https://doi.org/10.1007/s11708-018-0545-3
REVIEW ARTICLE
Unconventional hydrodynamics of hybrid fluid made of liquid metals and aqueous solution under applied fields
Xu-Dong ZHANG1, Yue SUN1, Sen CHEN1, Jing LIU2()
1. Beijing Key Lab of Cryo-Biomedical Engineering and Key Lab of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190; School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049, China
2. Beijing Key Lab of Cryo-Biomedical Engineering and Key Lab of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190; School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049; Department of Biomedical Engineering, School of Medicine, Tsinghua University, Beijing 100084, China
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Abstract

The hydrodynamic characteristics of hybrid fluid made of liquid metal/aqueous solution are elementary in the design and operation of conductive flow in a variety of newly emerging areas such as chip cooling, soft robot, and biomedical practices. In terms of physical and chemical properties, such as density, thermal conductivity and electrical conductivity, their huge differences between the two fluidic phases remain a big challenge for analyzing the hybrid flow behaviors. Besides, the liquid metal immersed in the solution can move and deform when administrated with non-contact electromagnetic force, or even induced by redox reaction, which is entirely different from the cases of conventional contact force. Owing to its remarkable capability in flow and deformation, liquid metal immersed in the solution is apt to deform on an extremely large scale, resulting in marked changes on its boundary and interface. However, the working mecha- nisms of the movement and deformation of liquid metal lack appropriate models to describe such scientific issues via a set of well-established unified equations. To promote investigations in this important area, the present paper is dedicated to summarizing this unconventional hydrodynamics from experiment, theory, and simulation. Typical experimental phenomena and basic working mechanisms are illustrated, followed by the movement and deformation theories to explain these phenomena. Several representative simulation methods are then proposed to tackle the governing functions of the electrohydrodynamics. Finally, prospects and challenges are raised, offering an insight into the new physics of the hybrid fluid under applied fields.

Keywords liquid metal      hybrid fluid      hydrodynamics      surface tension      applied fields      self-actuation     
Corresponding Author(s): Jing LIU   
Just Accepted Date: 22 January 2018   Online First Date: 19 April 2018    Issue Date: 04 June 2018
 Cite this article:   
Xu-Dong ZHANG,Yue SUN,Sen CHEN, et al. Unconventional hydrodynamics of hybrid fluid made of liquid metals and aqueous solution under applied fields[J]. Front. Energy, 2018, 12(2): 276-296.
 URL:  
https://academic.hep.com.cn/fie/EN/10.1007/s11708-018-0545-3
https://academic.hep.com.cn/fie/EN/Y2018/V12/I2/276
Fig.1  Typical applications of room temperature liquid metal
Fig.2  Electric-field-induced rotation of a liquid metal sphere (Adapted with permission from Ref. [18])
Fig.3  An electrohydrodynamic shooting phenomenon of liquid metal stream
Fig.4  A liquid metal enabled pump
Fig.5  Large deformation of liquid metal under electric field
Fig.6  Non-coalescence phenomenon of liquid metal drop
Fig.7  Self-running of liquid Ga-In-Al soft motor along different geometrical space filled with NaOH solution (Adapted with permission from Ref. [19])
Fig.8  Oscillation behavior of copper wire in liquid metal machine
Fig.9  Transformation of the liquid metal droplet on graphite in an electrolyte (Adapted with permission from Ref. [21])
Fig.10  Unusual biomimetic amoeba-like behaviors of liquid metal
Fig.11  Liquid metal motor under magnetic trap
Fig.12  Rotation of liquid metal under the coupled interaction of electric field and magnetic field
Fig.13  Movement of liquid metal droplets adding aluminum under electric field
Composition Melting point/°C Boiling point/°C Thermal conductivity/(W·m−1·K−1) Electrical conductivity/(Ω−1·m−1) Surface tension/(N·m−1) Viscosity/ (m2·s−1) Density/(kg·m−3) Water compatibility
Hg –38.8 356.65 8.34 1.0 0.455 13.5 1353 Soluble
Ga 29.8 2204.8 29.4 3.7 0.707 2.7 6080 Insoluble
Cs 28.65 2023.8 17.4 4.89 0.248 1879 Active
Rb 38.85 756.5 29.3 7.79 0.081 1532 Active
GaIn24.5 15.5 2000 27.5 4.6 0.624 2.7 6280 Insoluble
GaIn20.5Sn12.5 10.5 >1300 3.1 0.535 2.98 6360 Insoluble
NaK77.8 –12 785 26.2 2.88 0.11 2.4 750 Active
Tab.1  Some physical properties of liquid metals [5154]
Fig.14  Shape of gallium in different media and substrates
Fig.15  EDL around the liquid metal drop
Year Name Breakthroughs
1903 Smoluchowski The electrophoretic velocity of solid-particle electrophoresis
1946 Frumkin The first analysis of liquid metal drops in weak applied fields
1951 Booth A same electrophoretic velocity for all dielectrics
1962 Levich Multiplying the Smoluchowski’s scale by δ−1 and confirmed experimentally
1978 O’Brien and White Weak-field linearization
1984 Ohshima et al. The first systematic analysis of charged conducting drops
2012 Schnitzer Nonlinear macroscopic model
Tab.2  Development of conducting drop model
Fig.16  Charge redistribution on surface of liquid metal drop under electric field
Fig.17  Deformation process of liquid metal based on gallium immersed in the alkaline solution under electric field
Fig.18  Deformation process of gallium-based liquid metal on the graphite and immersed in the alkaline solution without electric field (Adapted with permission from Ref. [21])
Fig.19  Forces acting on gallium-based liquid metal before and after deformation
Fig.20  Comparison of deformation factor D between predicted values and computational results for different ratios of the electric conductivities σ1?σ2 and ε1??2=10 (Adapted with permission from Ref. [79])
Fig.21  Relations of drop deformation factor and induced flow pattern
Fig.22  Deformation, velocity vectors, and fluid density contours of the droplet(a quarter of the central region)

(a) R>S, D>0; (b) R<S, D>0; (c) R<S, D<0 (Adapted with permission from Ref. [81])

Fig.23  Calculated drop shape, equipotential and velocity vectors
Fig.24  Finite-volume/front tracking simulations of deformation and motion of two-phase drop suspension system, streamline on the left and velocity vector on the right
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