Preparation of a novel anion exchange group modified hyper-crosslinked resin for the effective adsorption of both tetracycline and humic acid

doi:10.1007/s11783-013-0483-6

Front Envir Sci Eng

2013, Vol. 7

Issue (3) : 412-419 https://doi.org/10.1007/s11783-013-0483-6

RESEARCH ARTICLE

Preparation of a novel anion exchange group modified hyper-crosslinked resin for the effective adsorption of both tetracycline and humic acid

Qing ZHOU, Mengqiao WANG, Aimin LI(

), Chendong SHUANG, Mancheng ZHANG, Xiaohan LIU, Liuyan WU

State Key Laboratory of Pollution Control and Resources Reuse, School of the Environment, Nanjing University, Nanjing 210046, China

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Abstract

A novel hyper-crosslinked resin (MENQ) modified with an anion exchange group was prepared using divinylbenzene (DVB) and methyl acrylate (MA) as comonomers via four steps: suspension polymerization, post-crosslinking, ammonolysis and alkylation reactions. The obtained resin had both a high specific surface area (793.34 m²·g^-1) and a large exchange capacity (strong base anion exchange capacity, SEC: 0.74 mmol·g^-1, weak base anion exchange capacity, WEC: 0.45 mmol·g^-1). XAD-4 was selected as an adsorbent for comparison to investigate the adsorption behavior of tetracycline (TC) and humic acid (HA) onto the adsorbents. The results revealed that MENQ could effectively remove both TC and HA. The adsorption capacity of XAD-4 for TC was similar to that of MENQ, but XAD-4 exhibited poor performance for the adsorption of HA. The adsorption isotherms of TC and HA were well-fitted with the Freundlich model, which indicated the existence of heterogeneous adsorption through cation-π bonding and π–π interactions. The optimal solution condition for the adsorption of TC was at a pH of 5–6, whereas the adsorption of HA was enhanced with increasing pH of the solution.

Keywords high surface area adsorption anion exchange micropollutant dissolved organic matters

Corresponding Author(s): LI Aimin,Email:liaimin@nju.edu.cn

Issue Date: 01 June 2013

Cite this article:

Qing ZHOU,Mengqiao WANG,Aimin LI, et al. Preparation of a novel anion exchange group modified hyper-crosslinked resin for the effective adsorption of both tetracycline and humic acid[J]. Front Envir Sci Eng, 2013, 7(3): 412-419.

URL:

https://academic.hep.com.cn/fese/EN/10.1007/s11783-013-0483-6
https://academic.hep.com.cn/fese/EN/Y2013/V7/I3/412

Fig.1 Steps for preparing the bifunctional resin (MENQ)

Fig.2 FTIR spectra of the bifunctional resin: (a) poly(DVB-co-MA); (b) post-crosslinked resin; (c) ammonolysed resin and (d) alkylated resin (MENQ)

Fig.3 SEM image of MENQ

Tab.1 Physicochemical properties of the employed resins

Fig.4 Adsorption kinetics of (a) TC and (b) HA onto MENQ and XAD-4 at 288 K, and modeling of the adsorption onto the adsorbates (initial concentrations= 100 mg·L)

Tab.2 Kinetic parameters for the adsorption of TC and HA onto the investigated resins

Fig.5 Effects of the pH of the solution on the adsorption of TC and HA onto both adsorbents

Fig.6 Adsorption isotherms of (a) TC on MENQ; (b) TC on XAD-4; (c) HA on MENQ at 288K, 303K, and 318K

Tab.3 Constants for the Langmuir and Freundlich equations at 288 K, 303 K, and 318 K

Fig.7 Effect of HA on the adsorption of TC onto MENQ

Fig.8 Effect of regeneration cycles on the adsorption capacity of MENQ for HA and TC (initial concentrations= 100 mg·L)

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