Enhanced desulfurization performance of hybrid membranes using embedded hierarchical porous SBA-15

doi:10.1007/s11705-019-1830-3

Front. Chem. Sci. Eng.

2020, Vol. 14

Issue (4) : 661-672 https://doi.org/10.1007/s11705-019-1830-3

RESEARCH ARTICLE

Enhanced desulfurization performance of hybrid membranes using embedded hierarchical porous SBA-15

Ye Zhang^1,², Jian Song^1,², Josue Quispe Mayta^1,², Fusheng Pan^1,², Xue Gao¹, Mei Li¹, Yimeng Song^1,², Meidi Wang^1,², Xingzhong Cao³, Zhongyi Jiang^1,²(

)

¹. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
². Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China
³. Multi-discipline Research Division, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

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Abstract

The utilization of materials with a hierarchical porous structure as multi-functional additives is highly attractive in the preparation of hybrid membranes. In this study, novel hybrid membranes are designed by embedding hierarchical porous Santa Barbara Amorphous 15 (SBA-15) with a dual-pore architecture (micropores and mesopores) for pervaporation desulfurization. The SBA-15 with cylindrical mesopores provides molecular transport expressways to ensure improved permeability, while micropores on the wall have molecular sieving effects that are essential for the enhancement of permselectivity of thiophene molecules. Considering thiophene/n-octane mixture as a model system, the hybrid membrane with embedded 6 wt-% SBA-15 exhibits optimal pervaporation desulfurization performance with a permeation flux of 22.07 kg·m⁻²·h⁻¹ and an enrichment factor of 6.76. Moreover, the detailed structure and properties of hybrid membranes are systematically characterized. This study demonstrates the immense potential of hierarchical porous materials as additives in membranes to simultaneously increase permeability and permselectivity.

Keywords hybrid membranes hierarchical porous SBA-15 sieving effect pervaporation desulfurization

Corresponding Author(s): Zhongyi Jiang

Just Accepted Date: 21 August 2019 Online First Date: 09 October 2019 Issue Date: 22 May 2020

Cite this article:

Ye Zhang,Jian Song,Josue Quispe Mayta, et al. Enhanced desulfurization performance of hybrid membranes using embedded hierarchical porous SBA-15[J]. Front. Chem. Sci. Eng., 2020, 14(4): 661-672.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-019-1830-3
https://academic.hep.com.cn/fcse/EN/Y2020/V14/I4/661

Fig.1 (a) Chemical structure of Pebax 2533 and (b) scheme structure of hierarchical porous SBA-15.

Fig.2 SEM image (a) and TEM image (b) of SBA-15.

Fig.3 (a) FTIR spectra and (b) the wide-angle XRD patterns of SBA-15 (inset indicates the small-angle XRD patterns of SBA-15).

Fig.4 SEM cross-section images of (a) Pebax/PSf, (b) Pebax-SBA-15(4)/PSf, (c) Pebax- SBA-15(6)/PSf, (d) Pebax-SBA-15(10)/PSf; SEM surface images of (e) Pebax /PSf, (f) Pebax-SBA-15(4)/PSf, (g) Pebax-SBA-15(6)/PSf, (h) Pebax-SBA-15(10)/PSf.

Fig.5 (a) FTIR spectra, (b) XRD patterns, (c) degree of swelling and (d) TGA results for the pristine Pebax and Pebax-SBA-15(X) membranes.

Fig.6 Separation performance of pristine Pebax/PSf and Pebax-SBA-15(6)/PSf hybrid membranes.

Fig.7 (a) The sorption selectivity and (b) diffusion selectivity of thiophene and n-octane in membranes.

Fig.8 Effect of feed temperature on (a) total flux and enrichment factor, (b) n-octane flux and thiophene flux, (c) permeance and selectivity of Pebax-SBA-15(6)/PSf hybrid membranes for the desulfurization of 1312 ppm thiophene/n-octane mixtures and (d) Arrhenius plots of n-octane and thiophene fluxes.

Fig.9 Effect of thiophene concentration in the feed on the (a) total flux and enrichment factor, (b) thiophene and n-octane flux and (c) permeance and selectivity of Pebax-SBA-15(6)/PSf hybrid membranes for the desulfurization of thiophene/n-octane mixture.

Fig.10 Long-term operating stability of Pebax-SBA-15(6)/PSf hybrid membrane.

Fig.11 Comparison of separation performance for desulfurization of Pebax-SBA-15(6)/PSf hybrid membrane with other membranes reported in the literature.

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