Please wait a minute...
Frontiers of Environmental Science & Engineering

ISSN 2095-2201

ISSN 2095-221X(Online)

CN 10-1013/X

Postal Subscription Code 80-973

2018 Impact Factor: 3.883

Front. Environ. Sci. Eng.    2023, Vol. 17 Issue (8) : 95    https://doi.org/10.1007/s11783-023-1695-z
PERSPECTIVES
Target the neglected VOCs emission from iron and steel industry in China for air quality improvement
Chenglin Cai1, Juexiu Li2, Yi He3, Jinping Jia1,4()
1. China-UK Low Carbon College, Shanghai Jiao Tong University, Shanghai 200240, China
2. School of Energy & Environment, Zhongyuan University of Technology, Zhengzhou 450007, China
3. John Jay College and the Graduate Center, The City University of New York, New York, NY 10019, USA
4. School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
 Download: PDF(1439 KB)   HTML
 Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks
Abstract

● Haze formation in China is highly correlated with iron and steel industry.

● VOCs generated in sinter process were neglected under current emission standard.

● Co-elimination removal of sinter flue gas complex pollutants are timely needed.

Recent years have witnessed significant improvement in China’s air quality. Strict environmental protection measures have led to significant decreases in sulfur dioxide (SO2), nitrogen oxides (NOx), and particulate matter (PM) emissions since 2013. But there is no denying that the air quality in 135 cities is inferior to reaching the Ambient Air Quality Standards (GB 30952012) in 2020. In terms of temporal, geographic, and historical aspects, we have analyzed the potential connections between China’s air quality and the iron and steel industry. The non-target volatile organic compounds (VOCs) emissions from iron and steel industry, especially from the iron ore sinter process, may be an underappreciated index imposing a negative effect on the surrounding areas of China. Therefore, we appeal the authorities to pay more attention on VOCs emission from the iron and steel industry and establish new environmental standards. And different iron steel flue gas pollutants will be eliminated concurrently with the promotion and application of new technology.

Keywords Volatile organic compounds      Iron and steel industry      Air quality      Sinter flue gas emission     
Corresponding Author(s): Jinping Jia   
Issue Date: 16 February 2023
 Cite this article:   
Chenglin Cai,Juexiu Li,Yi He, et al. Target the neglected VOCs emission from iron and steel industry in China for air quality improvement[J]. Front. Environ. Sci. Eng., 2023, 17(8): 95.
 URL:  
https://academic.hep.com.cn/fese/EN/10.1007/s11783-023-1695-z
https://academic.hep.com.cn/fese/EN/Y2023/V17/I8/95
Fig.1  Illustration of a typical sinter process and sinter flue gas emissions.
Fig.2  Haze formation associated with the interactions of iron ore sinter process primary pollutants emissions.
1 C Acciai, Z Zhang, F Wang, Z Zhong, G Lonati. (2017). Characteristics and source analysis of trace elements in PM2.5 in the urban atmosphere of Wuhan in spring. Aerosol and Air Quality Research, 17(9): 2224–2234
https://doi.org/10.4209/aaqr.2017.06.0207
2 X Bai, W Liu, B Wu, S Liu, X Liu, Y Hao, W Liang, S Lin, L Luo, S Zhao, et al. (2022). Emission characteristics and inventory of volatile organic compounds from the Chinese cement industry based on field measurements. EnvironmentalPollution, 316(Pt 1): 120600
3 Z Bai, W Winiwarter, Z Klimont, G Velthof, T Misselbrook, Z Zhao, X Jin, O Oenema, C Hu, L Ma. (2019). Further improvement of air quality in China needs clear ammonia mitigation target. Environmental Science & Technology, 53(18): 10542–10544
https://doi.org/10.1021/acs.est.9b04725
4 M L Bell, D L Davis. (2001). Reassessment of the lethal London fog of 1952: novel indicators of acute and chronic consequences of acute exposure to air pollution. Environmental Health Perspectives, 109(Suppl 3): 389–394
https://doi.org/10.1289/ehp.01109s3389
5 F J Brüggemeier (1990). The Ruhr Basin 1850–1980: a case of large-scale environmental pollution. The Silent COUNTDOWN. Berlin: Springer-Verlag
6 C I Davidson. (1979). Air pollution in Pittsburgh: a historical perspective. Journal of the Air Pollution Control Association, 29(10): 1035–1041
https://doi.org/10.1080/00022470.1979.10470892
7 X Ding, Q Li, D Wu, Y Huo, Y Liang, H Wang, J Zhang, S Wang, T Wang, X Ye, J Chen. (2020). Gaseous and particulate chlorine emissions from typical iron and steel industry in China. Journal of Geophysical Research. Atmospheres, 125(15): e2020JD032729
https://doi.org/10.1029/2020JD032729
8 W J Duan, J L Lang, S Y Cheng, J Jia, X Q Wang. (2018). Air pollutant emission inventory from iron and steel industry in the Beijing-Tianjin-Hebei region and its impact on PM2.5. Environmental Sciences (Ruse), 39: 1445–1454
9 H Fu, J Chen. (2017). Formation, features and controlling strategies of severe haze-fog pollutions in China. Science of the Total Environment, 578: 121–138
https://doi.org/10.1016/j.scitotenv.2016.10.201
10 S Guo, M Hu, M L Zamora, J Peng, D Shang, J Zheng, Z Du, Z Wu, M Shao, L Zeng, M J Molina, R Zhang. (2014). Elucidating severe urban haze formation in China. Proceedings of the National Academy of Sciences of the United States of America, 111(49): 17373–17378
https://doi.org/10.1073/pnas.1419604111
11 T Han, L Yao, L Liu, A Xian, H Chen, W Dong, J Chen. (2018). Baosteel emission control significantly benefited air quality in Shanghai. Journal of Environmental Sciences (China), 71: 127–135
https://doi.org/10.1016/j.jes.2018.01.014
12 F Hu, Y Guo. (2021). Health impacts of air pollution in China. Frontiers of Environmental Science & Engineering, 15(4): 74
https://doi.org/10.1007/s11783-020-1367-1
13 W Hua, B Wu. (2022). Atmospheric circulation anomaly over mid- and high-latitudes and its association with severe persistent haze events in Beijing. Atmospheric Research, 277: 106315
https://doi.org/10.1016/j.atmosres.2022.106315
14 R J Huang, Y Zhang, C Bozzetti, K F Ho, J J Cao, Y Han, K R Daellenbach, J G Slowik, S M Platt, F Canonaco. et al.. (2014). High secondary aerosol contribution to particulate pollution during haze events in China. Nature, 514(7521): 218–222
https://doi.org/10.1038/nature13774
15 W Isard. (1948). Some locational factors in the iron and steel industry since the early nineteenth century. Journal of Political Economy, 56(3): 203–217
https://doi.org/10.1086/256673
16 E T Jacobs, J L Burgess, M B Abbott. (2018). The donora smog revisited: 70 years after the event that inspired the clean air act. American Journal of Public Health, 108(S2): S85–S88
https://doi.org/10.2105/AJPH.2017.304219
17 P D Koman, P Mancuso. (2017). Ozone exposure, cardiopulmonary health, and obesity: a substantive review. Chemical Research in Toxicology, 30(7): 1384–1395
https://doi.org/10.1021/acs.chemrestox.7b00077
18 T Le, Y Wang, L Liu, J Yang, Y L Yung, G Li, J H Seinfeld. (2020). Unexpected air pollution with marked emission reductions during the COVID-19 outbreak in China. Science, 369(6504): 702–706
https://doi.org/10.1126/science.abb7431
19 J Li, X He, B Pei, X Li, D Ying, Y Wang, J Jia. (2019). The ignored emission of volatile organic compounds from iron ore sinter process. Journal of Environmental Sciences (China), 77: 282–290
https://doi.org/10.1016/j.jes.2018.08.007
20 S Li, G Liu, M Zheng, W Liu, J Li, M Wang, C Li, Y Chen. (2017). Unintentional production of persistent chlorinated and brominated organic pollutants during iron ore sintering processes. Journal of Hazardous Materials, 331: 63–70
https://doi.org/10.1016/j.jhazmat.2017.02.027
21 B Lin, R Wu. (2020). Designing energy policy based on dynamic change in energy and carbon dioxide emission performance of China’s iron and steel industry. Journal of Cleaner Production, 256: 120412
https://doi.org/10.1016/j.jclepro.2020.120412
22 Y Lin, Y Zhao, X Qiu, J Ma, Q Yang, M Shao, T Zhu. (2013). Spatial distribution of polychlorinated naphthalenes in the atmosphere across North China based on gridded field observations. Environmental Pollution, 180: 27–33
https://doi.org/10.1016/j.envpol.2013.04.037
23 Y C Lin, S C Hsu, C C Chou, R Zhang, Y Wu, S J Kao, L Luo, C H Huang, S H Lin, Y T Huang (2016). Wintertime haze deterioration in Beijing by industrial pollution deduced from trace metal fingerprints and enhanced health risk by heavy metals. Environmental Pollution, 208(Pt A): 284–293
24 J Liu, S Wang, H Yi, X Tang, Z Li, Q Yu, S Zhao, F Gao, Y Zhou, Y Wang. (2022). Air pollutant emission and reduction potentials from the sintering process of the iron and steel industry in China in 2017. Environmental Pollution, 307: 119512
https://doi.org/10.1016/j.envpol.2022.119512
25 Z Liu, C X Xu, J H Chen, L Han, B Wang, W P Xiong, L D Mei. (2020). Emission estimation and component characteristics of volatile organic compounds in typical iron and steel enterprise. China Environmental Science, 40(10): 4292–4303
26 W Long, S Wang, C Lu, R Xue, T Liang, N Jiang, R Zhang. (2020). Quantitative assessment of energy conservation potential and environmental benefits of an iron and steel plant in China. Journal of Cleaner Production, 273: 123163
https://doi.org/10.1016/j.jclepro.2020.123163
27 Y F Luo, Y F Wang, J J Li, Z W Yu, J C Wei, H M Long. (2021). Influence of coking coal ratio on emission characteristics of volatile organic compounds in sintering flue gas. China Evironmental Science, 41: 4077–4084 (in Chinese)
28 J Ma, B Chu, J Liu, Y Liu, H Zhang, H He. (2018). NOx promotion of SO2 conversion to sulfate: an important mechanism for the occurrence of heavy haze during winter in Beijing. Environmental Pollution, 233: 662–669
https://doi.org/10.1016/j.envpol.2017.10.103
29 Y Peng, Q Yang, L Wang, S Wang, J Li, X Zhang, S Zhang, H Zhao, B Zhang, C Wang. et al.. (2021). VOC emissions of coal-fired power plants in China based on life cycle assessment method. Fuel, 292: 120325
https://doi.org/10.1016/j.fuel.2021.120325
30 L Qian, T Chun, H Long, J Li, Z Di, Q Meng, P Wang. (2018). Emission reduction research and development of PCDD/Fs in the iron ore sintering. Process Safety and Environmental Protection, 117: 82–91
https://doi.org/10.1016/j.psep.2018.04.014
31 X Shen, Y Zhao, Z Chen, D Huang. (2013). Heterogeneous reactions of volatile organic compounds in the atmosphere. Atmospheric Environment, 68: 297–314
https://doi.org/10.1016/j.atmosenv.2012.11.027
32 J Shi, H Deng, Z Bai, S Kong, X Wang, J Hao, X Han, P Ning (2015). Emission and profile characteristic of volatile organic compounds emitted from coke production, iron smelt, heating station and power plant in Liaoning Province, China. Science of the Total Environment, 515–516: 101–108
https://doi.org/10.1016/j.scitotenv.2015.02.034
33 S Sun, W Liu, W Guan, S Zhu, J Jia, X Wu, R Lei, T Jia, Y He. (2021). Effects of air pollution control devices on volatile organic compounds reduction in coal-fired power plants. Science of the Total Environment, 782: 146828
https://doi.org/10.1016/j.scitotenv.2021.146828
34 Y Sun, L Liu, X Fu, T Zhu, A Buekens, X Yang, Q Wang. (2016). Mechanism of unintentionally produced persistent organic pollutant formation in iron ore sintering. Journal of Hazardous Materials, 306: 41–49
https://doi.org/10.1016/j.jhazmat.2015.11.059
35 C W Sweet, S J Vermette, S Landsberger. (1993). Sources of toxic trace elements in urban air in Illinois. Environmental Science & Technology, 27(12): 2502–2510
https://doi.org/10.1021/es00048a030
36 L Tang, X Xue, M Jia, H Jing, T Wang, R Zhen, M Huang, J Tian, J Guo, L Li. et al.. (2020b). Iron and steel industry emissions and contribution to the air quality in China. Atmospheric Environment, 237: 117668
https://doi.org/10.1016/j.atmosenv.2020.117668
37 L Tang, X Xue, X Bo, J Guo, P Wang, W Zhai, W Cui, S Wang, S Li, G Dong. (2020a). Contribution of emissions from cement to air quality in China. Environmental Science, 41: 4776–4785
38 B Tian, J Huang, B Wang, S Deng, G Yu. (2012). Emission characterization of unintentionally produced persistent organic pollutants from iron ore sintering process in China. Chemosphere, 89(4): 409–415
https://doi.org/10.1016/j.chemosphere.2012.05.069
39 J H Tsai, K H Lin, C Y Chen, N Lai, S Y Ma, H L Chiang (2008). Volatile organic compound constituents from an integrated iron and steel facility. Journal of Hazardous Materials, 157(2–3): 569–578
https://doi.org/10.1016/j.jhazmat.2008.01.022
40 H Wang, R Hao, L Fang, L Nie, Z Zhang, Z Hao. (2021). Study on emissions of volatile organic compounds from a typical coking chemical plant in China. Science of the Total Environment, 752: 141927
https://doi.org/10.1016/j.scitotenv.2020.141927
41 M Wang, Q Li, W Liu (2019). Temporal trends in polychlorinated naphthalene emissions from sintering plants in China between 2005 and 2015. Environmental Pollution, 255(Pt 1): 113096
https://doi.org/10.1016/j.envpol.2019.113096
42 Wang P, Zhu S, Vrekoussis M, Brasseur G P, Wang S, Zhang H (2022a). Is atmospheric oxidation capacity better in indicating tropospheric O3 formation? Frontiers of Environmental Science & Engineering, 16(5): 65
43 R Wang, X Wang, S Cheng, K Wang, L Cheng, J Zhu, H Zheng, W Duan. (2022b). Emission characteristics and reactivity of volatile organic compounds from typical high-energy-consuming industries in North China. Science of the Total Environment, 809: 151134
https://doi.org/10.1016/j.scitotenv.2021.151134
44 Y Wang, L Ding, Q Shi, S Liu, L Qian, Z Yu, H Wang, J Lei, Z Gao, H Long, C Charles Xu. (2022c). Volatile organic compounds (VOC) emissions control in iron ore sintering process: recent progress and future development. Chemical Engineering Journal, 448: 137601
https://doi.org/10.1016/j.cej.2022.137601
45 Y Wang, R Zhu, X Bo, M Dan, M Shu (2022d). Volatile organic compounds constituents of a typical integrated iron and steel plant and influence on O3 pollution. International Journal of Environmental Science and Technology, doi: 10.1007/s13762-022-04135-6
46 H E Wichmann, W Mueller, P Allhoff, M Beckmann, N Bocter, M J Csicsaky, M Jung, B Molik, G Schoeneberg. (1989). Health effects during a smog episode in West Germany in 1985. Environmental Health Perspectives, 79: 89–99
https://doi.org/10.1289/ehp.897989
47 WSA(2010). World Steel in Figures 2010. World Steel Association. Available online at worldsteel.org/wp-content
48 WSA(2021). World Steel in Figures 2021. World Steel Association. Available online at worldsteel.org/media-centre
49 X Wu, L Zhao, Y Zhang, C Zheng, X Gao, K Cen. (2015). Primary air pollutant emissions and future prediction of iron and steel industry in China. Aerosol and Air Quality Research, 15(4): 1422–1432
https://doi.org/10.4209/aaqr.2015.01.0029
50 J Xu, F Zhu, X Ge, H Li, X Zhao, W Tian, X Zhang, Y Bai, F An, S Wang. (2022). Research progress on volatile organic compounds emissions from coal-fired power plants. Current Pollution Reports, 8(3): 303–314
https://doi.org/10.1007/s40726-022-00225-8
51 X Xu, X Xu, Q Chen, Y Che. (2018). The impacts on CO2 emission reduction and haze by coal resource tax reform based on dynamic CGE model. Resources Policy, 58: 268–276
https://doi.org/10.1016/j.resourpol.2018.05.015
52 Y Xu, H Yu, Y Yan, L Peng, R Li, C Wang, Z Li. (2021). Emission characteristics of volatile organic compounds from typical coal utilization sources: a case study in Shanxi of northern China. Aerosol and Air Quality Research, 21(9): 210050
https://doi.org/10.4209/aaqr.210050
53 H Yang, W Tao, Y Liu, M Qiu, J Liu, K Jiang, K Yi, Y Xiao, S Tao (2019). The contribution of the Beijing-Tianjin-Hebei region’s iron and steel industry to local air pollution in winter. Environmental Pollution, 245: 1095–1106
https://doi.org/10.1016/j.envpol.2018.11.088
54 W Yang, Q Ma, Y Liu, J Ma, B Chu, L Wang, H He. (2018). Role of NH3 in the heterogeneous formation of secondary inorganic aerosols on mineral oxides. Journal of Physical Chemistry A, 122(30): 6311–6320
https://doi.org/10.1021/acs.jpca.8b05130
55 H Zhang, M Rao, Z Fan, Y Zhang, G Li, T Jiang. (2012). Effects of circulated flue gas components on iron ore sintering. ISIJ International, 52(12): 2139–2144
https://doi.org/10.2355/isijinternational.52.2139
56 R Zhang, G Wang, S Guo, M L Zamora, Q Ying, Y Lin, W Wang, M Hu, Y Wang. (2015). Formation of urban fine particulate matter. Chemical Reviews, 115(10): 3803–3855
https://doi.org/10.1021/acs.chemrev.5b00067
57 S Zhang, J Xing, G Sarwar, Y Ge, H He, F Duan, Y Zhao, K He, L Zhu, B Chu. (2019). Parameterization of heterogeneous reaction of SO2 to sulfate on dust with coexistence of NH3 and NO2 under different humidity conditions. Atmospheric Environment, 208: 133–140
https://doi.org/10.1016/j.atmosenv.2019.04.004
58 X Zhang, S Gao, Q Fu, D Han, X Chen, S Fu, X Huang, J Cheng. (2020a). Impact of VOCs emission from iron and steel industry on regional O3 and PM2.5 pollutions. Environmental Science and Pollution Research International, 27(23): 28853–28866
https://doi.org/10.1007/s11356-020-09218-w
59 X Zhang, D Wang, Y Liu, Y Cui, Z Xue, Z Gao, J Du. (2020b). Characteristics and ozone formation potential of volatile organic compounds in emissions from a typical Chinese coking plant. Journal of Environmental Sciences (China), 95: 183–189
https://doi.org/10.1016/j.jes.2020.03.018
[1] Qiyue Wu, Yun Geng, Xinyuan Wang, Dongsheng Wang, ChangKyoo Yoo, Hongbin Liu. A novel deep learning framework with variational auto-encoder for indoor air quality prediction[J]. Front. Environ. Sci. Eng., 2024, 18(1): 8-.
[2] Yuanxin Zhang, Fei Li, Chaoqiong Ni, Song Gao, Shuwei Zhang, Jin Xue, Zhukai Ning, Chuanming Wei, Fang Fang, Yongyou Nie, Zheng Jiao. Prediction and cause investigation of ozone based on a double-stage attention mechanism recurrent neural network[J]. Front. Environ. Sci. Eng., 2023, 17(2): 21-.
[3] Hengrui Tao, Jia Xing, Gaofeng Pan, Jonathan Pleim, Limei Ran, Shuxiao Wang, Xing Chang, Guojing Li, Fei Chen, Junhua Li. Impact of anthropogenic heat emissions on meteorological parameters and air quality in Beijing using a high-resolution model simulation[J]. Front. Environ. Sci. Eng., 2022, 16(4): 44-.
[4] Jianwei Liu, Peng Yue, Nana Zang, Chen Lu, Xinyue Chen. Removal of odors and VOCs in municipal solid waste comprehensive treatment plants using a novel three-stage integrated biofilter: Performance and bioaerosol emissions[J]. Front. Environ. Sci. Eng., 2021, 15(3): 48-.
[5] Kun Zhang, Jialuo Xu, Qing Huang, Lei Zhou, Qingyan Fu, Yusen Duan, Guangli Xiu. Precursors and potential sources of ground-level ozone in suburban Shanghai[J]. Front. Environ. Sci. Eng., 2020, 14(6): 92-.
[6] Wenjing Lu, Yawar Abbas, Muhammad Farooq Mustafa, Chao Pan, Hongtao Wang. A review on application of dielectric barrier discharge plasma technology on the abatement of volatile organic compounds[J]. Front. Environ. Sci. Eng., 2019, 13(2): 30-.
[7] Cong Liu, Yinping Zhang. Relations between indoor and outdoor PM2.5 and constituent concentrations[J]. Front. Environ. Sci. Eng., 2019, 13(1): 5-.
[8] Kajetan Kalus, Sebastian Opaliński, Devin Maurer, Somchai Rice, Jacek A. Koziel, Mariusz Korczyński, Zbigniew Dobrzański, Roman Kołacz, Beata Gutarowska. Odour reducing microbial-mineral additive for poultry manure treatment[J]. Front. Environ. Sci. Eng., 2017, 11(3): 7-.
[9] Christian GEORGE, Anne BEELDENS, Fotios BARMPAS, Jean-François DOUSSIN, Giuseppe MANGANELLI, Hartmut HERRMANN, Jörg KLEFFMANN, Abdelwahid MELLOUKI. Impact of photocatalytic remediation of pollutants on urban air quality[J]. Front. Environ. Sci. Eng., 2016, 10(5): 2-.
[10] Pu ZHAO,Lizhong ZHU. Optimized porous clay heterostructure for removal of acetaldehyde and toluene from indoor air[J]. Front. Environ. Sci. Eng., 2016, 10(2): 219-228.
[11] Hengyi DUAN,Xiaotu LIU,Meilin YAN,Yatao WU,Zhaorong LIU. Characteristics of carbonyls and volatile organic compounds (VOCs) in residences in Beijing, China[J]. Front. Environ. Sci. Eng., 2016, 10(1): 73-84.
[12] Jinying XI,Insun KANG,Hongying HU,Xian ZHANG. A biofilter model for simultaneous simulation of toluene removal and bed pressure drop under varied inlet loadings[J]. Front. Environ. Sci. Eng., 2015, 9(3): 554-562.
[13] Wei WEI, Shuxiao WANG, Jiming HAO, Shuiyuan CHENG. Trends of chemical speciation profiles of anthropogenic volatile organic compounds emissions in China, 2005–2020[J]. Front Envir Sci Eng, 2014, 8(1): 27-41.
[14] Junhua LI, Hong HE, Chun HU, Jincai ZHAO. The abatement of major pollutants in air and water by environmental catalysis[J]. Front Envir Sci Eng, 2013, 7(3): 302-325.
[15] Can DONG, Lingxiao YANG, Chao YAN, Qi YUAN, Yangchun YU, Wenxing WANG. Particle size distributions, PM2.5 concentrations and water-soluble inorganic ions in different public indoor environments: a case study in Jinan, China[J]. Front Envir Sci Eng, 2013, 7(1): 55-65.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed