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Characterization of basic physical properties of Sb2Se3 and its relevance for photovoltaics
Chao CHEN, David C. BOBELA, Ye YANG, Shuaicheng LU, Kai ZENG, Cong GE, Bo YANG, Liang GAO, Yang ZHAO, Matthew C. BEARD, Jiang TANG
Front. Optoelectron.. 2017, 10 (1): 18-30.
https://doi.org/10.1007/s12200-017-0702-z
Antimony selenide (Sb2Se3) is a promising absorber material for thin film photovoltaics because of its attractive material, optical and electrical properties. In recent years, the power conversion efficiency (PCE) of Sb2Se3 thin film solar cells has gradually enhanced to 5.6%. In this article, we systematically studied the basic physical properties of Sb2Se3 such as dielectric constant, anisotropic mobility, carrier lifetime, diffusion length, defect depth, defect density and optical band tail states. We believe such a comprehensive characterization of the basic physical properties of Sb2Se3 lays a solid foundation for further optimization of solar device performance.
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Structural, optical and electrical properties of ZnO: B thin films with different thickness for bifacial a-Si:H/c-Si heterojunction solar cells
Dong XU, Sheng YIN, Xiangbin ZENG, Song YANG, Xixing WEN
Front. Optoelectron.. 2017, 10 (1): 31-37.
https://doi.org/10.1007/s12200-016-0595-2
Textured surface boron-doped zinc oxide (BZO) thin films were fabricated by metal organic chemical vapor deposition as transparent conductive oxide (TCO) for solar cells. The surface microstructure was characterized by X-ray diffraction spectrum and scanning electron microscope. The optical transmittance was shown by optical transmittance microscope and the electrical properties were tested by Hall measurements. The thickness of the BZO film has crucial impact on the surface morphology, optical transmittance, and resistivity. The electrical and optical properties as well as surface microstructure varied inconsistently with the increase of the film thickness. The grain size and the surface roughness increased with the increase of the film thickness. The conductivity increased from 0.96×103 to 6.94×103 S/cm while the optical transmittance decreased from above 85% to nearly 80% with the increase of film thickness from 195 to 1021 nm. The BZO films deposited as both front and back transparent electrodes were applied to the bifacial p-type a-Si:H/i-type a-Si:H/n-type c-Si/i-type a-Si:H/n+-type a-Si:H heterojunction solar cells to obtain the optimized parameter of thickness. The highest efficiency of all the samples was 17.8% obtained with the BZO film thickness of 829 nm. Meanwhile, the fill factor was 0.676, the open-circuit voltage was 0.63 V and the short-circuit density was 41.79 mA/cm2. The properties of the solar cells changing with the thickness were also investigated.
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