Adsorption of 1,3-propanediol from synthetic mixture using polymeric resin as adsorbents

doi:10.1007/s11705-009-0087-7

Front Chem Eng Chin

2009, Vol. 3

Issue (1) : 52-57 https://doi.org/10.1007/s11705-009-0087-7

RESEARCH ARTICLE

Adsorption of 1,3-propanediol from synthetic mixture using polymeric resin as adsorbents

W. LUERRUK¹, A. SHOTIPRUK¹, V. TANTAYAKOM², P. PRASITCHOKE², C. MUANGNAPOH¹(

)

1. Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Bangkok 10330, Thailand; 2. Department of Innovation and Technology, PTT Chemical Public Company Limited, Rayong 21150, Thailand

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Abstract

The aim of this work was to separate 1,3-PDO from a synthetic mixture using polymeric resins, Amberlite XAD-7 and XAD-16 resins. The equilibrium adsorption of 1,3-PDO onto two polymeric resins were investigated in binary and tertiary systems. Experimental results of binary component adsorption equilibrium indicated that the adsorption capacity (q) of 1,3-PDO at 160 g/L onto XAD-7 and XAD-16 was 835.96 and 584.61 mg 1,3-PDO/g dry resin, respectively. The adsorption isotherms were closely predicted by the Langmuir-Freundlich model among the two isotherm model tested. The value of n of 1,3-PDO adsorbed on XAD-7 are much higher than those on XAD-16. This result suggested that XAD-7 resin has a higher affinity for the 1,3-PDO adsorption than XAD-16 resin. Moreover, the value of adsorption capacity of 1,3-PDO in the binary and tertiary component were compared at the same conditions. In the tertiary system, although the selectivity of 1,3-PDO from XAD-7 was approximately six times higher than XAD-16, the adsorption capacity of 1,3-PDO at 160 g/L onto XAD-16 was higher than XAD-7. Interestingly, the reusability of XAD-7 and XAD-16 resins in the three cycle times shows a slight loss of adsorption capacity. Furthermore, the investigation about desorption by an ethanol/water mixture at 50% (V/V) indicated that the desorption yield of 1,3-PDO from XAD-7 was lower than XAD-16 resin for both the binary and tertiary component. This was due to the more favorable adsorption characteristics of XAD-7 resin than XAD-16 resin.

Keywords adsorption 1 3-propanediol glycerol polymeric resin adsorption isotherm

Corresponding Author(s): MUANGNAPOH C.,Email:chirakarn.m@chula.ac.th

Issue Date: 05 March 2009

Cite this article:

W. LUERRUK,V. TANTAYAKOM,P. PRASITCHOKE, et al. Adsorption of 1,3-propanediol from synthetic mixture using polymeric resin as adsorbents[J]. Front Chem Eng Chin, 2009, 3(1): 52-57.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-009-0087-7
https://academic.hep.com.cn/fcse/EN/Y2009/V3/I1/52

Fig.1 Equilibrium adsorption isotherm for 1,3-PDO onto XAD-7 and XAD-16 resins in binary component system at 303 K

Fig.2 1,3-PDO equilibrium adsorption isotherm of XAD-7 and XAD-16 resin at 303 K. Fitting to Langmuir, Freundlich and Langmuir-Freundlich models are shown together with these experimental data points

Tab.1 Isotherm models

Tab.2 Fitting parameters of models

Fig.3 Comparison of the experimental binary equilibrium adsorption data (●) with tertiary equilibrium adsorption data (?) of 1,3-PDO onto XAD-7 and XAD-16 resins

Tab.3 Desorption yield of 1,3-PDO from XAD-7 and XAD-16 resins at 303 K for 24 h

Tab.4 Mass of adsorption at 160 g/L and desorption of 1,3-PDO from XAD-7 and XAD-16 resins.

Fig.4 Adsorption ratio and desorption yield (%) of 1,3-PDO with XAD-7 and XAD-16 resins in binary component system at 303 K

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