Removal of copper ions from aqueous solution by adsorption using LABORATORIES-modified bentonite (organo-bentonite)

doi:10.1007/s11705-011-1160-6

Front Chem Sci Eng

2012, Vol. 6

Issue (1) : 58-66 https://doi.org/10.1007/s11705-011-1160-6

RESEARCH ARTICLE

Removal of copper ions from aqueous solution by adsorption using LABORATORIES-modified bentonite (organo-bentonite)

Sandy¹, Velycia MARAMIS¹, Alfin KURNIAWAN¹, Aning AYUCITRA¹, Jaka SUNARSO², Suryadi ISMADJI¹(

)

1. Department of Chemical Engineering, Widya Mandala Surabaya Catholic University, Surabaya 60114, Indonesia; 2. Australian Research Council (ARC) Centre of Excellence for Electromaterials Science, Institute for Technology Research and Innovation, Deakin University, Victoria 3125, Australia

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Abstract

Equilibrium, kinetic and thermodynamic aspects of the adsorption of copper ions from an aqueous solution using linear alkylbenzene sulfonate (LABORATORIES) modified bentonite (organo-bentonite) are reported. Modification of bentonite was performed via microwave heating with a concentration of LABORATORIES surfactant equivalent to 1.5 times that of the cation exchange capacity (CEC) of the raw bentonite. Experimental parameters affecting the adsorption process such as pH, contact time and temperature were studied. Several adsorption equations (e.g., Langmuir, Freundlich, Sips and Toth) with temperature dependency were used to correlate the equilibrium data. These models were evaluated based on the theoretical justifications of each isotherm parameter. The Sips model had the best fit for the adsorption of copper ions onto organo-bentonite. For the kinetic data, the pseudo-second order model was superior to the pseudo-first order model. Thermodynamically, the adsorption of copper ions occurs via chemisorption and the process is endothermic (ΔH⁰>0), irreversible (ΔS⁰>0) and nonspontaneous (ΔG⁰>0).

Keywords heavy metal copper adsorption organo-bentonite temperature dependent

Corresponding Author(s): ISMADJI Suryadi,Email:suryadiismadji@yahoo.com

Issue Date: 05 March 2012

Cite this article:

Sandy,Velycia MARAMIS,Alfin KURNIAWAN, et al. Removal of copper ions from aqueous solution by adsorption using LABORATORIES-modified bentonite (organo-bentonite)[J]. Front Chem Sci Eng, 2012, 6(1): 58-66.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-011-1160-6
https://academic.hep.com.cn/fcse/EN/Y2012/V6/I1/58

Tab.1 FTIR assignments of raw bentonite and organo-bentonite

Fig.1 Effect of pH on the adsorption of Cu(II) ions onto organo-bentonite
(Operation conditions: = 400 mg/L, adsorbent mass= 0.8 g, = 303.15 K)

Fig.2 ? ( = 303.15 K); ○ ( = 313.15 K); ? ( = 323.15 K); — (Langmuir model)
Equilibrium plot of the adsorption of Cu(II) onto organo-bentonite at various temperatures–Langnuir model

Tab.2 Fitted temperature dependent parameters for several adsorption equations for the adsorption of Cu(II) ions onto organo-bentonite

Fig.3 ? ( = 303.15 K); ○ ( = 313.15 K); ? ( = 323.15 K); — (Freundlich model)
Equilibrium plot of the adsorption of Cu(II) ions onto organo-bentonite at various temperatures–Freundich model

Fig.4 ? ( = 303.15 K); ○ ( = 313.15 K); ? ( = 323.15 K); — (Sips model)
Equilibrium plot of the adsorption of onto Cu(II) organo-bentonite at various temperatures–Sip smodel

Fig.5 ? ( = 303.15 K); ○ ( = 313.15 K); ? ( = 323.15 K); — (Toth model)
Equilibrium plot of the adsorption of Cu(II) ions onto organo-bentonite at various temperatures–Toth model

Tab.3 Fitted kinetic parameters for the adsorption of Cu(II) ions onto organo-bentonite

Fig.6 ? ( = 303.15 K); ○ ( = 313.15 K); ? ( = 323.15 K); — (pseudo-first order model)
Kinetic plot for the adsorption of Cu(II) ions onto organo-bentonite at various temperatures

Fig.7 ? ( = 303.15 K); ○ ( = 313.15 K); ? ( = 323.15 K); — (pseudo-second order model)
Kinetic plot for the adsorption of Cu(II) ions onto organo-bentonite at various temperatures

Tab.4 Thermodynamic parameters for the adsorption of Cu(II) ions onto organo-bentonite

Fig.8 van’t Hoff plot for adsorption of Cu(II) ions onto organo-bentonite

1	Huang C C, Su Y J. Removal of copper ions from wastewater by adsorption/electrosorption on modified activated carbon cloths. Journal of Hazardous Materials , 2010, 175(1-3): 477-483 doi: 10.1016/j.jhazmat.2009.10.030 pmid:19896268
2	Zhao G, Zhang H, Fan Q, Ren X, Li J, Chen Y, Wang X. Sorption of copper(II) onto super-adsorbent of bentonite-polyacrylamide composites. Journal of Hazardous Materials , 2010, 173(1-3): 661-668 doi: 10.1016/j.jhazmat.2009.08.135 pmid:19766390
3	Fu F, Wang Q. Removal of heavy metal ions from wastewaters: a review. Journal of Environmental Management , 2011, 92(3): 407-418 doi: 10.1016/j.jenvman.2010.11.011 pmid:21138785
4	G?k O, Ozcan A, Erdem B, Ozcan A S. Prediction of the kinetics, equilibrium and thermodynamic parameters of adsorption of copper(II) ions onto 8-hydroxyquinoline immobilized bentonite. Colloids and Surfaces A: Physicochemical and Engineering Aspects , 2008, 317(1-3): 174-185 doi: 10.1016/j.colsurfa.2007.10.009
5	Liu Y, Cao Q, Luo F, Chen J. Biosorption of Cd²⁺, Cu²⁺, Ni²⁺ and Zn²⁺ ions from aqueous solutions by pretreated biomass of brown algae. Journal of Hazardous Materials , 2009, 163(2-3): 931-938 doi: 10.1016/j.jhazmat.2008.07.046 pmid:18755544
6	Chen Z, Ma W, Han M. Biosorption of nickel and copper onto treated alga (Undaria pinnatifida): application of isotherm and kinetic models. Journal of Hazardous Materials , 2008, 155(1-2): 327-333 doi: 10.1016/j.jhazmat.2007.11.064 pmid:18178002
7	Anirudhan T S, Radhakrishnan P G. Thermodynamics and kinetics of adsorption of Cu(II) from aqueous solutions onto a new cation exchanger derived from tamarind fruit shell. Journal of Chemical Thermodynamics , 2008, 40(4): 702-709 doi: 10.1016/j.jct.2007.10.005
8	Nathaniel E, Kurniawan A, Soetaredjo F E, Ismadji S. Organo-bentonite for the adsorption of Pb(II) from aqueous solution: temperature dependent parameters of several adsorption equations. Desalination and Water Treatment 2011, 36: 1-9
9	Kurniawan A, Sisnandy V O A, Trilestari K, Sunarso J, Indraswati N, Ismadji S. Performance of durian shell waste as high capacity biosorbent for Cr(VI) removal from synthetic wastewater. Ecological Engineering , 2011, 37(6): 940-947 doi: 10.1016/j.ecoleng.2011.01.019
10	Monier M, Ayad D M, Wei Y, Sarhan A A. Adsorption of Cu(II), Co(II), and Ni(II) ions by modified magnetic chitosan chelating resin. Journal of Hazardous Materials , 2010, 177(1-3): 962-970 doi: 10.1016/j.jhazmat.2010.01.012 pmid:20122793
11	Acharya J, Sahu J N, Mohanty C R, Meikap B C. Removal of lead(II) from wastewater by activated carbon developed from Tamarind wood by zinc chloride activation. Chemical Engineering Journal , 2009, 149(1-3): 249-262 doi: 10.1016/j.cej.2008.10.029
12	Erdem E, Karapinar N, Donat R. The removal of heavy metal cations by natural zeolites. Journal of Colloid and Interface Science , 2004, 280(2): 309-314 doi: 10.1016/j.jcis.2004.08.028 pmid:15533402
13	Yesi, Sisnandy F P, Ju Y H, Soetaredjo F E, Ismadji S. Adsorption of acid blue 129 from aqueous solutions onto raw and surfactant-modified bentonite. Adsorption Science and Technology , 2010, 28: 847-868 doi: 10.1260/0263-6174.28.10.847
14	Rahardjo A K, Susanto M J J, Kurniawan A, Indraswati N, Ismadji S. Modified Ponorogo bentonite for the removal of ampicillin from wastewater. Journal of Hazardous Materials , 2011, 190(1-3): 1001-1008 doi: 10.1016/j.jhazmat.2011.04.052 pmid:21550716
15	Do D D. Adsorption Analysis: equilibria and kinetics. London: Imperial College Press, 1998
16	Ismadji S, Bhatia S K. A modified pore-filling isotherm for liquid-phase adsorption in activated carbon. Langmuir , 2001, 17(5): 1488-1498 doi: 10.1021/la0009339
17	Bhattacharyya K G, Gupta S S. Kaolinite, montmorillonite, and their modified derivatives as adsorbents for removal of Cu(II) from aqueous solution. Separation and Purification Technology , 2006, 50(3): 388-397 doi: 10.1016/j.seppur.2005.12.014
18	Lin S H, Juang R S. Heavy metal removal from water by sorption using surfactant-modified montmorillonite. Journal of Hazardous Materials , 2002, 92(3): 315-326 doi: 10.1016/S0304-3894(02)00026-2 pmid:12031615
19	álvarez-Ayuso E, Garcia-Sanchez A. Removal of heavy metals from waste waters by natural and Na-exchanged bentonites. Clays and Clay Minerals , 2003, 51(5): 475-480 doi: 10.1346/CCMN.2003.0510501
20	Karapinar N, Donat R. Adsorption behaviour of Cu²⁺ and Cd²⁺ onto natural bentonite. Desalination , 2009, 249(1): 123-129 doi: 10.1016/j.desal.2008.12.046
21	Ijagbemi C O, Baek M H, Kim D S. Montmorillonite surface properties and sorption characteristics for heavy metal removal from aqueous solutions. Journal of Hazardous Materials , 2009, 166(1): 538-546 doi: 10.1016/j.jhazmat.2008.11.085 pmid:19131158
22	Lagergren S. About the theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar , 1898, 24: 1-39
23	Blanchard G, Maunaye M, Martin G. Removal of heavy metals from waters by means of natural zeolites. Water Research , 1984, 18(12): 1501-1507 doi: 10.1016/0043-1354(84)90124-6
24	Plazinski W, Rudzinski W, Plazinska A. Theoretical models of sorption kinetics including a surface reaction mechanism: a review. Advances in Colloid and Interface Science , 2009, 152(1-2): 2-13 doi: 10.1016/j.cis.2009.07.009 pmid:19735907
25	Kul A R, Koyuncu H. Adsorption of Pb(II) ions from aqueous solution by native and activated bentonite: kinetic, equilibrium and thermodynamic study. Journal of Hazardous Materials , 2010, 179(1-3): 332-339 doi: 10.1016/j.jhazmat.2010.03.009 pmid:20356674
26	Schneider R M, Cavalin C F, Barros M A S D, Tavares C R G. Adsorption of chromium ions in activated carbon. Chemical Engineering Journal , 2007, 132(1-3): 355-362 doi: 10.1016/j.cej.2007.01.031

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