Catalytic conversion of biomass-derived compounds to various amino acids: status and perspectives

doi:10.1007/s11705-022-2254-z

Front. Chem. Sci. Eng.

2023, Vol. 17

Issue (7) : 817-829 https://doi.org/10.1007/s11705-022-2254-z

REVIEW ARTICLE

Catalytic conversion of biomass-derived compounds to various amino acids: status and perspectives

Benjing Xu¹, Jinhang Dai²(

), Ziting Du², Fukun Li^1,²(

), Huan Liu^2,³, Xingxing Gu², Xingmin Wang², Ning Li², Jun Zhao⁴(

)

¹. Engineering Research Center for Waste Oil Recovery Technology and Equipment of Ministry of Education, Chongqing Technology and Business University, Chongqing 400067, China
². College of Environment and Resources, Chongqing Technology and Business University, Chongqing 400067, China
³. Key Laboratory of Energy Resource Utilization from Agriculture Residue, Academy of Agricultural Planning and Engineering, Ministry of Agriculture and Rural Affairs, Beijing 100125, China
⁴. Department of Biology, Hong Kong Baptist University, Hong Kong, China

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Abstract

Amino acids are important nitrogen-containing chemicals that have a variety of applications. Currently, fermentation is the widely employed method to produce amino acids; however, the products are mostly limited to natural amino acids in the L-configuration. Catalytic synthesis is an alternative approach for the synthesis of amino acids with different types and configurations, where the use of renewable biomass-based feedstocks is highly attractive. To date, several lignocellulose and triacylglycerol-derived intermediates, typically α-keto acids and α-hydroxyl acids, have been transformed into amino acids via the amination reaction in the presence of additional nitrogen sources (i.e., NH₃·H₂O). Making full use of inherent nitrogen in biomass (i.e., chitin and protein) to produce amino acids avoids the use of extra nitrogen sources and meets the requirements of green chemistry, which is attracting increasing attention. In this review, we summarize different chemical-catalytic systems for the transformation of biomass to amino acids. An outlook on the challenges and opportunities for more effective production of amino acids from biomass by catalytic methods is provided.

Keywords biomass amino acids chitin nitrogen-containing compounds lignocellulose

Corresponding Author(s): Jinhang Dai,Fukun Li,Jun Zhao

About author:

^* These authors contributed equally to this work.

Just Accepted Date: 26 October 2022 Online First Date: 28 February 2023 Issue Date: 05 July 2023

Cite this article:

Benjing Xu,Jinhang Dai,Ziting Du, et al. Catalytic conversion of biomass-derived compounds to various amino acids: status and perspectives[J]. Front. Chem. Sci. Eng., 2023, 17(7): 817-829.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-022-2254-z
https://academic.hep.com.cn/fcse/EN/Y2023/V17/I7/817

Scheme1 Production of amino acids via Strecker and Petasis reaction.

Scheme2 Overview of main chemical methods for production of amino acids from different biomass-based intermediates.

Scheme3 Conversion of α-keto acids and α-hydroxyl acids to amino acids.

Scheme4 (a) Conversion of α-keto acids to amino acids over Rh-based catalysts. (b) Structures of (R,R)-norphos, (S,S)-chiraphos, and (R,R)-deguphos. Reprinted with permission from Ref. [25], copyright 2003, American Chemical Society.

Scheme15 Conversion of chitin biomass to glycine and its derivatives.

Scheme16 Oxidation of NMEA by water under basic conditions.

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