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Electrolyte-dependent photovoltaic responses in dye-sensitized solar cells |
Hong LIN( ), Feng HAO, Jianbao LI |
State Key Laboratory of New Ceramics & Fine Processing, Department of Material Science and Engineering, Tsinghua University, Beijing 100084, China |
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Abstract Promoted by the growing concerns about the worldwide energy demand and global warming, dye-sensitized solar cells (DSSCs) are currently attracting worldwide scientific and technological interest because of their high energy conversion efficiency and simple fabrication process. Considering long-terms stability and practice applications, growing attentions have been paid to non-volatile, 3-methoxyproprionitrile (MPN)-based electrolyte, ionic liquids (ILs) electrolyte, as well as quasi-solid state electrolyte. In this present review, recent progress in electrolyte for DSSCs made by our group are summarized, including component-optimization of the non-volatile electrolyte, the fluidity-dependent charge transport mechanism in the binary IL electrolytes as well as the structure dominance of the employed ILs. Furthermore, progress on the quasi-solid state electrolyte based on inorganic nanomaterials as gelators in our group has also been outlined.
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Keywords
electrolyte
non-volatile
ionic liquid (IL)
quasi-solid state
dye-sensitized solar cell (DSSC)
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Corresponding Author(s):
LIN Hong,Email:Hong-lin@tsinghua.edu.cn
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Issue Date: 05 March 2011
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1 |
O’Regan B, Gr?tzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature , 1991, 353(6346): 737–740 doi: 10.1038/353737a0
|
2 |
Gr?tzel M. Photoelectrochemical cells. Nature , 2001, 414(6861): 338–344 doi: 10.1038/35104607 pmid:11713540
|
3 |
Gr?tzel M. Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells. Journal of Photochemistry and Photobiology A , 2004, 164(1-3): 3–14 doi: 10.1016/j.jphotochem.2004.02.023
|
4 |
Chiba Y, Islam A, Watanabe Y, Komiya R, Koide N, Han L Y. Dye-sensitized solar cells with conversion efficiency of 11.1%. Japanese Journal of Applied Physics Part 2 , 2006, 45: L638–L640
|
5 |
Kroon J M, Bakker N J, Smit H J P, Liska P, Thampi K R, Wang P, Zakeeruddin S M, Gr?tzel M, Hinsch A, Hore S, Wurfel U, Sastrawan R, Durrant J R, Palomares E, Pettersson H, Gruszecki T, Walter J, Skupien K, Tulloch G E. Nanocrystalline dye-sensitized solar cells having maximum performance. Progress in Photovoltaics , 2007, 15(1): 1–18 doi: 10.1002/pip.707
|
6 |
Nazeeruddin M K, De Angelis F, Fantacci S, Selloni A, Viscardi G, Liska P, Ito S, Takeru B, Gr?tzel M. Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers. Journal of the American Chemical Society , 2005, 127(48): 16835–16847 doi: 10.1021/ja052467l pmid:16316230
|
7 |
Gr?tzel M. Solar energy conversion by dye-sensitized photovoltaic cells. Inorganic Chemistry , 2005, 44(20): 6841–6851 doi: 10.1021/ic0508371 pmid:16180840
|
8 |
Chiba Y, Islam A, Komiya R, Koide N, Han L Y. 10.8% conversion efficiency of dye-sensitized solar cells using modified TiO2 substrates. Applied Physics Letters , 2006, 88(22): 223505 doi: 10.1063/1.2208920
|
9 |
Wang P, Zakeeruddin S M, Moser J E, Nazeeruddin M K, Sekiguchi T, Gr?tzel M. A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte. Nature Materials , 2003, 2(6): 402–407 doi: 10.1038/nmat904 pmid:12754500
|
10 |
Wang P, Zakeeruddin S M, Humphry-Baker R, Moser J E, Gr?tzel M. Molecular-scale interface engineering of TiO2 nanocrystals: improve the efficiency and stability of dye-sensitized solar cells. Advanced Materials (Deerfield Beach, Fla.) , 2003, 15(24): 2101–2104 doi: 10.1002/adma.200306084
|
11 |
Wang P, Klein C, Humphry-Baker R, Zakeeruddin S M, Gr?tzel M. A high molar extinction coefficient sensitizer for stable dye-sensitized solar cells. Journal of the American Chemical Society , 2005, 127(3): 808–809 doi: 10.1021/ja0436190 pmid:15656598
|
12 |
Wang P, Klein C, Humphry-Baker R, Zakeeruddin S M, Gr?tzel M. Stable ≥ 8% efficient nanocrystalline dye-sensitized solar cell based on an electrolyte of low volatility. Applied Physics Letters , 2005, 86(12): 123508 doi: 10.1063/1.1887825
|
13 |
Kuang D B, Klein C, Snaith H J, Moser J E, Humphry-Baker R, Comte P, Zakeeruddin S M, Gr?tzel M. Ion coordinating sensitizer for high efficiency mesoscopic dye-sensitized solar cells: influence of lithium ions on the photovoltaic performance of liquid and solid-state cells. Nano Letters , 2006, 6(4): 769–773 doi: 10.1021/nl060075m pmid:16608281
|
14 |
Kawano R, Watanabe M. Anomaly of charge transport of an iodide/tri-iodide redox couple in an ionic liquid and its importance in dye-sensitized solar cells. Chemical Communications , 2005, 16(16): 2107–2109 doi: 10.1039/b418031c pmid:15846415
|
15 |
Kubo W, Kambe S, Nakade S, Kitamura T, Hanabusa K, Wada Y, Yanagida S. Photocurrent-determining processes in quasi-solid-state dye-sensitized solar cells using ionic gel electrolytes. Journal of Physical Chemistry B , 2003, 107(18): 4374–4381 doi: 10.1021/jp034248x
|
16 |
Wang P, Zakeeruddin S M, Comte P, Exnar I, Gr?tzel M. Gelation of ionic liquid-based electrolytes with silica nanoparticles for quasi-solid-state dye-sensitized solar cells. Journal of the American Chemical Society , 2003, 125(5): 1166–1167 doi: 10.1021/ja029294+ pmid:12553808
|
17 |
Kuang D B, Wang P, Ito S, Zakeeruddin S M, Gr?tzel M. Stable mesoscopic dye-sensitized solar cells based on tetracyanoborate ionic liquid electrolyte. Journal of the American Chemical Society , 2006, 128(24): 7732–7733 doi: 10.1021/ja061714y pmid:16771475
|
18 |
Gorlov M, Pettersson H, Hagfeldt A, Kloo L. Electrolytes for dye-sensitized solar cells based on interhalogen ionic salts and liquids. Inorganic Chemistry , 2007, 46(9): 3566–3575 doi: 10.1021/ic062244b pmid:17417833
|
19 |
Noda A, Hayamizu K, Watanabe M. Pulsed-gradient spin-echo 1H and 19F NMR ionic diffusion coefficient, viscosity, and ionic conductivity of non-chloroaluminate room-temperature ionic liquids. Journal of Physical Chemistry B , 2001, 105(20): 4603–4610 doi: 10.1021/jp004132q
|
20 |
Suarez P A Z, Einloft S, Dullius J E L, de Souza R F, Dupont J J. Synthesis and physical-chemical properties of ionic liquids based on 1- n-butyl-3-methylimidazolium cation. Journal of Chemical Physics , 1998, 95(7): 1626–1639
|
21 |
Wang P, Zakeeruddin S M, Moser J E, Gr?tzel M. A new ionic liquid electrolyte enhances the conversion efficient of dye-sensitized solar cells. Journal of Physical Chemistry B , 2003, 107(48): 13280–13285 doi: 10.1021/jp0355399
|
22 |
Wang P, Zakeeruddin S M, Humphry-Baker R, Gr?tzel M. A binary ionic liquid electrolyte to achieve ≥ 7% power conversion efficiencies in dye-sensitized solar cells. Chemistry of Materials , 2004, 16(14): 2694–2696 doi: 10.1021/cm049916l
|
23 |
Wang P, Zakeeruddin S M, Moser J E, Humphry-Baker R, Gr?tzel M. A solvent-free, SeCN-/(SeCN)3- based ionic liquid electrolyte for high-efficiency dye-sensitized nanocrystalline solar cells. Journal of the American Chemical Society , 2004, 126(23): 7164–7165 doi: 10.1021/ja048472r pmid:15186139
|
24 |
Wang P, Wenger B, Humphry-Baker R, Moser J E, Teuscher J, Kantlehner W, Mezger J, Stoyanov E V, Zakeeruddin S M, Gr?tzel M. Charge separation and efficient light energy conversion in sensitized mesoscopic solar cells based on binary ionic liquids. Journal of the American Chemical Society , 2005, 127(18): 6850–6856 doi: 10.1021/ja042232u pmid:15869308
|
25 |
Kawano R, Matsui H, Matsuyama C, Sato A, Susan M A B H, Tanabe N, Watanabe M. High performance dye-sensitized solar cells using ionic liquids as their electrolytes. Journal of Photochemistry and Photobiology A Chemistry , 2004, 164(1-3): 87–92 doi: 10.1016/j.jphotochem.2003.12.019
|
26 |
Zhao Y, Zhai J, Tan S, Wang L, Jiang L, Zhu D. TiO2 micro/nano-composite structured electrodes for quasi-solid-state dye-sensitized solar cells. Nanotechnology , 2006, 17(9): 2090–2097 doi: 10.1088/0957-4484/17/9/003
|
27 |
Wang P, Zakeeruddin S M, Gr?tzel M. Solidifying liquid electrolytes with fluorine polymer and silica nanoparticles for quasi-solid dye-sensitized solar cells. Journal of Fluorine Chemistry , 2004, 125(8): 1241–1245 doi: 10.1016/j.jfluchem.2004.05.010
|
28 |
Kim J H, Kang M S, Kim Y J, Won J, Park N G, Kang Y S. Dye-sensitized nanocrystalline solar cells based on composite polymer electrolytes containing fumed silica nanoparticles. Chemical Communications , 2004, (14): 1662–1663 doi: 10.1039/b405215c pmid:15263968
|
29 |
Kato T, Kado T, Tanaka S, Okazaki A, Hayase S. Quasi-solid dye-sensitized solar cells containing nanoparticles modified with ionic liquid-type molecules. Journal of the Electrochemical Society , 2006, 153(3): A626–A630 doi: 10.1149/1.2161578
|
30 |
Usui H, Matsui H, Tanabe N, Yanagida S. Improved dye-sensitized solar cells using ionic nanocomposite gel electrolytes. Journal of Photochemistry and Photobiology A Chemistry , 2004, 164(1-3): 97–101 doi: 10.1016/j.jphotochem.2003.12.020
|
31 |
Tu C W, Liu K Y, Chien A T, Yen M H, Weng T H, Ho K C, Lin K F. Enhancement of photocurrent of polymer-gelled dye-sensitized solar cell by incorporation of exfoliated montmorillonite nanoplatelets. Journal of Polymer Science. Part A, Polymer Chemistry , 2008, 46(1): 47–53 doi: 10.1002/pola.22356
|
32 |
Park J H, Kim B W, Moon J H. Dual functions of clay nanoparticles with high aspect ratio indye-sensitized solar cells. Electrochemical and Solid-State Letters , 2008, 11(10): B171–B173 doi: 10.1149/1.2957601
|
33 |
Yang S C, Yoon H G, Lee S S, Lee H. Roles of layered titanates in ionic liquid electrolytes for quasi-solid state dye-sensitized solar cells. Materials Letters , 2009, 63(17): 1465–1467 doi: 10.1016/j.matlet.2009.03.042
|
34 |
Wang N, Lin H, Li J B, Li X. Improved quasi-solid dye-sensitized solar cells by composite ionic liquid electrolyte including layered α-zirconium phosphate. Applied Physics Letters , 2006, 89(19): 194104 doi: 10.1063/1.2387967
|
35 |
Zhang Z P, Ito S, Moser J E, Zakeeruddin S M, Gr?tzel M. Influence of iodide concentration on the efficiency and stability of dye-sensitized solar cell containing non-volatile electrolyte. ChemPhysChem , 2009, 10(11): 1834–1838 doi: 10.1002/cphc.200900199 pmid:19472254
|
36 |
Hao F, Lin H, Zhang J, Zhuang D T, Liu Y Z, Li J B. Influence of iodine concentration on the photoelectrochemical performance of dye-sensitized solar cells containing non-volatile electrolyte. Electrochimica Acta , 2010, 55(24): 7225–7229 doi: 10.1016/j.electacta.2010.06.079
|
37 |
Bearcroft D J, Nachtrieb N H. Electrical conductance of salts in liquid iodine. II. Iodide acceptor solutes. Journal of Physical Chemistry , 1967, 71(13): 4400–4404 doi: 10.1021/j100872a036
|
38 |
Bargeman D, Kommandeur J. Ionic conductivity in single crystals of iodine: ions in iodine. Journal of Chemical Physics , 1968, 49(9): 4069 doi: 10.1063/1.1670719
|
39 |
Stegemann H, Rohde A, Reiche A, Schnittke A, Füllbier H. Room temperature molten polyiodides. Electrochimica Acta , 1992, 37(3): 379–383 doi: 10.1016/0013-4686(92)87025-U
|
40 |
Dahms H. Electronic conduction in aqueous solution. Journal of Physical Chemistry , 1968, 72(1): 362–364 doi: 10.1021/j100847a073
|
41 |
Ruff I, Friedrich V J. Transfer diffusion. I. Theoretical. Journal of Physical Chemistry , 1971, 75(21): 3297–3302 doi: 10.1021/j100690a016
|
42 |
Leone A M, Weatherly S C, Williams M E, Thorp H H, Murray R W. An ionic liquid form of DNA: redox-active molten salts of nucleic acids. Journal of the American Chemical Society , 2001, 123(2): 218–222 doi: 10.1021/ja003332c pmid:11456507
|
43 |
Hao F, Lin H, Zhang J, Li J B. Balance between the physical diffusion and the exchange reaction on binary ionic liquid electrolyte for dye-sensitized solar cells. Journal of Power Sources , 2011, 196: 1645
|
44 |
Huddleston J D, Visser A E, Reichert W M, Willauer H D, Broker G A, Rogers R D. Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation. Green Chemistry , 2001, 3(4): 156–164 doi: 10.1039/b103275p
|
46 |
Hao F, Lin H, Liu Y Z, Li J B. Anionic structure-dependent photoelectrochemical responses of dyesensitized solar cells based on a binary ionic liquid electrolyte. Physical Chemistry Chemical Physics , 2011, doi: 10.1039/c0cp02704a
|
47 |
Hao F, Lin H, Li X, Zhang J, Liu Y Z, Li J B. Enhancement of photocurrent of dye-sensitized solar cell by composite liquid electrolyte including NiO nanosheets. Journal of Nanoscience and Nanotechnology , 2010, 10(11): 7390–7393 doi: 10.1166/jnn.2010.2794 pmid:21137942
|
48 |
Shi D, Pootrakulchote N, Li R, Guo J, Wang Y, Zakeeruddin S M, Gr?tzel M, Wang P. New efficiency records for stable dye-sensitized solar cells with low-volatility and ionic liquid electrolytes. Journal of Physical Chemistry C , 2008, 112(44): 17046–17050 doi: 10.1021/jp808018h
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