Mayenite supported perovskite monoliths for catalytic combustion of methyl methacrylate

doi:10.1007/s11705-014-1410-5

Front Chem Sci Eng

2014, Vol. 8

Issue (1) : 87-94 https://doi.org/10.1007/s11705-014-1410-5

RESEARCH ARTICLE

Mayenite supported perovskite monoliths for catalytic combustion of methyl methacrylate

Zekai ZHANG(

), Zhijian KONG, Huayan LIU, Yinfei CHEN

College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310014, China

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Abstract

To improve their thermal stability, La_0.8Sr_0.2MnO₃ cordierite monoliths are washcoated with mayenite, which is a novel Al-based material with the crystal structure of 12MO·7Al₂O₃ (M= Ca, Sr). The monoliths are characterized by means of nitrogen adsorption/desorption, scanning electron microscopy, and X-ray diffraction. Catalytic performances of the monoliths are tested for methyl methacrylate combustion. The results show that mayenite obviously improves both the physic-chemical properties and the catalytic performance of the monoliths. Because mayenite improves the dispersity of La_0.8Sr_0.2MnO₃ and also prevents the interaction between La_0.8Sr_0.2MnO₃ and cordierite or γ-Al₂O₃, both crystal structure and surface morphology of La_0.8Sr_0.2MnO₃ phase can thereby be stable on the mayenite surface even at high temperature up to 1050 oC. Under the given reaction conditions, La_0.8Sr_0.2MnO₃ monolith washcoated with 12SrO·7Al₂O₃ shows the best catalytic activity for methyl methacrylate combustion among all the tested monoliths.

Keywords mayenite perovskite catalytic combustion methyl methacrylate monolith

Corresponding Author(s): ZHANG Zekai,Email:zzk@zjut.edu.cn

Issue Date: 05 March 2014

Cite this article:

Zhijian KONG,Huayan LIU,Zekai ZHANG, et al. Mayenite supported perovskite monoliths for catalytic combustion of methyl methacrylate[J]. Front Chem Sci Eng, 2014, 8(1): 87-94.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-014-1410-5
https://academic.hep.com.cn/fcse/EN/Y2014/V8/I1/87

Fig.1 XRD patterns of mayenites and LaSrMnO perovskite powders

Fig.2 XRD patterns of the LaSMnO monoliths with different supports (support amount= 10 wt-% cordierite; perovskite amount=10 wt-% cordierite; the same below if not pointed out)

Fig.3 XRD patterns of LSM/CA samples calcined at different temperatures

Fig.4 XRD patterns of LSM/SA samples calcined at different temperatures

Fig.5 SEM micrographs of of LSM monoliths with different supports (a) none support; (b) AlO; (c) S/A; (d) CA

Fig.6 SEM micrographs of LSM/SA (a, c, e) and LSM/CA (b, d, f) calcined at 850°C (a, b), 1050°C (c, d), and 1200°C (e, f)

Fig.7 Influence of supports on the catalytic activity of LSM monoliths for MMA combustion

Fig.8 Catalytic combustion performance of LSM/CA at different temperatures

Fig.9 Catalytic combustion performance of LSM/SA calcined at different temperatures

Fig.10 Influence of SA amounts on the catalytic activity of LSM monoliths for MMA combustion (LSM amount= 4 wt-% cordierite)

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