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中国大型循环流化床锅炉发展与技术进程
黄中, 邓磊, 车得福
Frontiers in Energy. 2020, 14 (4): 699-714.
https://doi.org/10.1007/s11708-020-0666-3
Circulating fluidized bed (CFB) boilers has realized the clean and efficient utilization of inferior coal like gangue and coal slime, high sulfur coal, anthracite, petroleum coke, oil shale and other resources. As a country with the largest amount of CFB boilers and the largest installed capacity in the world, China has 440 100–600 MWe CFB boilers with a total capacity of 82.29 GWe, including 227 units of 135 MWe, 95 units of 300 MWe, and 24 supercritical units. The statistics of typical 100–300 MWe CFB boilers showed that the average number of unplanned shut-down was only 0.37 times per year, among which the 135 MWe was 0.26 times per year and 300 MWe was 0.46 times per year. The auxiliary power ratio of some 300 MWe CFB boilers based on flow-pattern reconstruction can be reduced to about 4%, which is closed to the same level of pulverized coal (PC) boilers. This paper summarizes the development process and application status of China’s large-scale CFB boilers, analyzes the characteristics and technical performance of the iconic units, and introduces solutions to the problems such as water wall wear and bottom ash cooling.
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Thermal annealing synthesis of double-shell truncated octahedral Pt-Ni alloys for oxygen reduction reaction of polymer electrolyte membrane fuel cells
Xiashuang LUO, Yangge GUO, Hongru ZHOU, Huan REN, Shuiyun SHEN, Guanghua WEI, Junliang ZHANG
Frontiers in Energy. 2020, 14 (4): 767-777.
https://doi.org/10.1007/s11708-020-0667-2
Shape-controlled Pt-Ni alloys usually offer an exceptional electrocatalytic activity toward the oxygen reduction reaction (ORR) of polymer electrolyte membrane fuel cells (PEMFCs), whose tricks lie in well-designed structures and surface morphologies. In this paper, a novel synthesis of truncated octahedral PtNi3.5 alloy catalysts that consist of homogeneous Pt-Ni alloy cores enclosed by NiO-Pt double shells through thermally annealing defective heterogeneous PtNi3.5 alloys is reported. By tracking the evolution of both compositions and morphologies, the outward segregation of both PtOx and NiO are first observed in Pt-Ni alloys. It is speculated that the diffusion of low-coordination atoms results in the formation of an energetically favorable truncated octahedron while the outward segregation of oxides leads to the formation of NiO-Pt double shells. It is very attractive that after gently removing the NiO outer shell, the dealloyed truncated octahedral core-shell structure demonstrates a greatly enhanced ORR activity. The as-obtained truncated octahedral Pt2.1Ni core-shell alloy presents a 3.4-folds mass-specific activity of that for unannealed sample, and its activity preserves 45.4% after 30000 potential cycles of accelerated degradation test (ADT). The peak power density of the dealloyed truncated octahedral Pt2.1Ni core-shell alloy catalyst based membrane electrolyte assembly (MEA) reaches 679.8 mW/cm2, increased by 138.4 mW/cm2 relative to that based on commercial Pt/C.
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Viability of a concentrated solar power system in a low sun belt prefecture
Rahul BHATTACHARJEE, Subhadeep BHATTACHARJEE
Frontiers in Energy. 2020, 14 (4): 850-866.
https://doi.org/10.1007/s11708-020-0664-5
Concentrating solar power (CSP) is considered as a comparatively economical, more efficient, and large capacity type of renewable energy technology. However, CSP generation is found restricted only to high solar radiation belt and installed where high direct normal irradiance is available. This paper examines the viability of the adoption of the CSP system in a low sun belt region with a lower direct normal irradiance (DNI). Various critical analyses and plant economics have been evaluated with a lesser DNI state. The obtained results out of the designed system, subjected to low DNI are not found below par, but comparable to some extent with the performance results of such CSP plants at a higher DNI. The analysis indicates that incorporation of the thermal energy storage reduces the levelized cost of energy (LCOE) and augments the plant capacity factor. The capacity factor, the plant efficiency, and the LCOE are found to be 32.50%, 17.56%, and 0.1952 $/kWh, respectively.
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