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Progress of nanoscience in China
Yu-Liang Zhao, Yan-Lin Song, Wei-Guo Song, Wei Liang, Xing-Yu Jiang, Zhi-Yong Tang, Hong-Xing Xu, Zhi-Xiang Wei, Yun-Qi Liu, Ming-Hua Liu, Lei Jiang, Xin-He Bao, Li-Jun Wan, Chun-Li Bai
Front. Phys. . 2014, 9 (3 ): 257-288.
https://doi.org/10.1007/s11467-013-0324-x
Fast evolving nanosciences and nanotechnology in China has made it one of the front countries of nanotechnology development. In this review, we summarize some most recent progresses in nanoscience research and nanotechnology development in China. The topics we selected in this article include nano-fabrication, nanocatalysis, bioinspired nanotechnology, green printing nanotechnology, nanoplasmonics, nanomedicine, nanomaterials and their applications, energy and environmental nanotechnology, nano EHS (nanosafety), etc. Most of them have great potentials in applications or application-related key issues in future.
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Hierarchical nanowires for high-performance electrochemical energy storage
Shuo Li(李硕), Yi-Fan Dong(董轶凡), Dan-Dan Wang(王丹丹), Wei Chen(陈伟), Lei Huang(黄磊), Chang-Wei Shi(石长玮), Li-Qiang Mai(麦立强)
Front. Phys. . 2014, 9 (3 ): 303-322.
https://doi.org/10.1007/s11467-013-0343-7
Nanowires are promising candidates for energy storage devices such as lithium-ion batteries, supercapacitors and lithium-air batteries. However, simple-structured nanowires have some limitations hence the strategies to make improvements need to be explored and investigated. Hierarchical nanowires with enhanced performance have been considered as an ideal candidate for energy storage due to the novel structures and/or synergistic properties. This review describes some of the recent progresses in the hierarchical nanowire merits, classification, synthesis and performance in energy storage applications. Herein we discuss the hierarchical nanowires based on their structural design from three major categories, including exterior design, interior design and aligned nanowire assembly. This review also briefly outlines the prospects of hierarchical nanowires in morphology control, property enhancement and application versatility.
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Nanomaterials for electrochemical energy storage
Nian Liu, Weiyang Li, Mauro Pasta, Yi Cui
Front. Phys. . 2014, 9 (3 ): 323-350.
https://doi.org/10.1007/s11467-013-0408-7
The development of nanotechnology in the past two decades has generated great capability of controlling materials at the nanometer scale and has enabled exciting opportunities to design materials with desirable electronic, ionic, photonic, and mechanical properties. This development has also contributed to the advance in energy storage, which is a critical technology in this century. In this article, we will review how the rational design of nanostructured materials has addressed the challenges of batteries and electrochemical capacitors and led to high-performance electrochemical energy storage devices. Four specific material systems will be discussed: i) nanostructured alloy anodes for Li-batteries, ii) nanostructured sulfur cathodes for Li-batteries, iii) nanoporous openframework battery electrodes, and iv) nanostructured electrodes for electrochemical capacitors.
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Applications of carbon nanotubes in high performance lithium ion batteries
Yang Wu, Jiaping Wang, Kaili Jiang, Shoushan Fan
Front. Phys. . 2014, 9 (3 ): 351-369.
https://doi.org/10.1007/s11467-013-0308-x
The development of lithium ion batteries (LIBs) relies on the improvement in the performance of electrode materials with higher capacity, higher rate capability, and longer cycle life. In this review article, the recent advances in carbon nanotube (CNT) anodes, CNT-based composite electrodes, and CNT current collectors for high performance LIBs are concerned. CNT has received considerable attentions as a candidate material for the LIB applications. In addition to a possible choice for anode, CNT has been recognized as a solution in improving the performance of the state-of-the-art electrode materials. The CNT-based composite electrodes can be fabricated by mechanical or chemical approaches. Owing to the large aspect ratio and the high electrical conductivity, CNTs at very low loading can lead to an efficient conductive network. The excellent mechanical strength suggests the great potential in forming a structure scaffold to accommodate nano-sized electrode materials. Accordingly, the incorporation of CNTs will enhance the conductivity of the composite electrodes, mitigate the agglomeration problem, decrease the dependence on inactive binders, and improve the electrochemical properties of both anode and cathode materials remarkably. Freestanding CNT network can be used as lightweight current collectors to increase the overall energy density of LIBs. Finally, research perspectives for exploiting CNTs in high-performance LIBs are discussed.
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