Construction of sustainable, colored and multifunctional protein silk fabric using biomass riboflavin sodium phosphate

doi:10.1007/s11705-023-2321-0

Front. Chem. Sci. Eng.

2023, Vol. 17

Issue (8) : 1131-1139 https://doi.org/10.1007/s11705-023-2321-0

RESEARCH ARTICLE

Construction of sustainable, colored and multifunctional protein silk fabric using biomass riboflavin sodium phosphate

Wen-Jie Jin, Yu Xin, Xian-Wei Cheng(

), Jin-Ping Guan(

), Guo-Qiang Chen

Key Laboratory of Flame Retardancy Finishing of Textile Materials (CNTAC), College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China

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Abstract

Riboflavin sodium phosphate has been confirmed as a promising biomass product derived from natural plants. In this paper, a novel method of dyeing and multifunctional modification of silk fabric by impregnation with riboflavin sodium phosphate was proposed, such that protein silk fabric can be endowed with bright yellow color and multi-functionality. The results of this paper confirmed that the pH and concentration of riboflavin sodium phosphate solution are critical factors for dyeing and multifunctional modification. Attractively, the photochromic performance was one of the most distinctive features of the modified silk fabric, and the dyed silk fabric turned into fluorescent green from original yellow under 365 nm ultraviolet lamp. Furthermore, the modified silk fabric exhibited good antibacterial properties with a high inhibition rate of 92% for Escherichia coli. Besides, the flame retardancy of silk fabric was significantly improved after modification. The damaged length of modified silk fabric with 40% owf riboflavin sodium phosphate was lower than 10.4 cm and passed the B₁ classification. As revealed by the result of this paper, riboflavin sodium phosphate is sufficiently effective in serving as an eco-friendly multifunctional agent for strengthening the add-value of silk textiles.

Keywords biomass riboflavin sodium phosphate silk protein multifunctional modification flame retardant

Corresponding Author(s): Xian-Wei Cheng,Jin-Ping Guan

Just Accepted Date: 12 May 2023 Online First Date: 28 June 2023 Issue Date: 20 July 2023

Cite this article:

Wen-Jie Jin,Yu Xin,Xian-Wei Cheng, et al. Construction of sustainable, colored and multifunctional protein silk fabric using biomass riboflavin sodium phosphate[J]. Front. Chem. Sci. Eng., 2023, 17(8): 1131-1139.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-023-2321-0
https://academic.hep.com.cn/fcse/EN/Y2023/V17/I8/1131

Fig.1 Schematic illustration of the RSP dyeing of silk fabrics.

Tab.1 Dyeing parameters of silk with RSP

Fig.2 The influence of dyeing (a) pH, (b) temperature, (c) time and (d) RSP dosage on color depth of silk fabric.

Fig.3 (a) Visible absorption spectrum and (b) color parameters of silk fabrics dyed with different concentrations of RSP.

Fig.4 (a) Sample observation model and (b) photos of fabric samples under different light sources.

Fig.5 Antibacterial effect against Escherichia coli of silk fabrics modified with 20% and 40% owf RSP.

Fig.6 (a) Damaged length, LOI of the modified silk fabrics at various RSP concentrations and (b) photos after vertical burning test.

Fig.7 TG and Derive-TG of RSP powder and silk fabrics modified with 40% owf RSP in (a, b) nitrogen and (c, d) air.

Fig.8 Morphology of the (a, c) control and (b, d) modified fabrics before and after vertical burning.

Fig.9 (a) Phosphorus content of silk fabrics and corresponding char residues and (b) P content of 40% owf RSP modified silk at different temperature; (c) photos of fabric samples at different temperatures.

Fig.10 SEM-EDS micrographs of (a) silk fabric and (b) char residue at 700 °C.

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