Methanation of carbon dioxide: an overview

doi:10.1007/s11705-010-0528-3

Front Chem Sci Eng

2011, Vol. 5

Issue (1) : 2-10 https://doi.org/10.1007/s11705-010-0528-3

REVIEW ARTICLE

Methanation of carbon dioxide: an overview

Wei WANG, Jinlong GONG(

)

Key Laboratory for Green Chemical Technology (Ministry of Education), School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

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Abstract

Although being very challenging, utilization of carbon dioxide (CO₂) originating from production processes and flue gases of CO₂-intensive sectors has a great environmental and industrial potential due to improving the resource efficiency of industry as well as by contributing to the reduction of CO₂ emissions. As a renewable and environmentally friendly source of carbon, catalytic approaches for CO₂ fixation in the synthesis of chemicals offer the way to mitigate the increasing CO₂ buildup. Among the catalytic reactions, methanation of CO₂ is a particularly promising technique for producing energy carrier or chemical. This article focuses on recent developments in catalytic materials, novel reactors, and reaction mechanism for methanation of CO₂.

Keywords CO₂ methanation hydrogenation catalysis methane environmental science

Corresponding Author(s): GONG Jinlong,Email:jlgong@tju.edu.cn

Issue Date: 05 March 2011

Cite this article:

Wei WANG,Jinlong GONG. Methanation of carbon dioxide: an overview[J]. Front Chem Sci Eng, 2011, 5(1): 2-10.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-010-0528-3
https://academic.hep.com.cn/fcse/EN/Y2011/V5/I1/2

Tab.1 Comparison of activity of hydrogenation of CO on nickel catalysts []

Fig.1 Comparison of CO conversion and CH yield for CO hydrogenation over 15 wt-% Ni/RHA-AlO and 15 wt-% Ni/SiO-AlO catalysts []

Fig.2 XRD patterns of Ni-CeZrO catalysts at various nickel loadings: (a) CeZrO; (b) 5 wt-% Ni-CeZrO; (c) 10 wt-% Ni-CeZrO; (d) 15 wt-% Ni-CeZrO []

Fig.3 Variations of in situ FT-IR signal intensities with temperature raising (a) Pt/Tnt and (b) Pt/TiO []

Fig.4 S: the support, M: the metal, I: the metal-support interface
The proposed reaction mechanism of CO methanation []

Fig.5 A potential bifunctional mechanism for Pd-Mg/SiO []

Fig.6 DRIFT results after adsorption of CO and CO and after adsorption of CO and reaction with hydrogen []

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