Utilization of surface differences to improve dyeing properties of poly(<i>m</i>-phenylene isophthalamide) membranes

doi:10.1007/s11706-018-0422-3

Front. Mater. Sci.

2018, Vol. 12

Issue (2) : 129-138 https://doi.org/10.1007/s11706-018-0422-3

RESEARCH ARTICLE

Utilization of surface differences to improve dyeing properties of poly(m-phenylene isophthalamide) membranes

Shenshen OUYANG, Tao WANG(

), Longgang ZHONG, Shunli WANG, Sheng WANG(

)

Key Laboratory of Advanced Textile Materials and Manufacturing Technology (Ministry of Education), Zhejiang Sci-Tech University, Hangzhou 310018, China

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Abstract

Bulk poly(m-phenylene isophthalamide) (PMIA) can achieve flexibility upon dissolution by a LiCl/dimethylacetamide co-solvent, but remains hydrophobic despite the occasional emergence of cis amide groups providing a weak negative charge. In this study, based on the significant surface differences between PMIA membranes processed by nanofiber electrospinning and casting, a series of chemical analyses, in-situ Au nanoparticle depositions, and dye-adsorption experiments revealed that more cis-configuration amide groups appeared on the surface of the electrospun PMIA membrane than on that of the cast membrane. Based on this surface difference, a strategy was proposed to improve the dyeing properties of PMIA by reversibly changing the cis/trans configurations of electrospun and cast membranes. The reversible chain–segment switch mechanism is a novel method for tuning the macroscale properties of polymer materials based on inherent molecular characteristics.

Keywords wettability polymer surface difference electrospun PMIA interfaces

Corresponding Author(s): Tao WANG,Sheng WANG

Online First Date: 16 May 2018 Issue Date: 29 May 2018

Cite this article:

Shenshen OUYANG,Tao WANG,Longgang ZHONG, et al. Utilization of surface differences to improve dyeing properties of poly(m-phenylene isophthalamide) membranes[J]. Front. Mater. Sci., 2018, 12(2): 129-138.

URL:

https://academic.hep.com.cn/foms/EN/10.1007/s11706-018-0422-3
https://academic.hep.com.cn/foms/EN/Y2018/V12/I2/129

Fig.1 Schematics of preparation and photographs and FESEM images of PMIA ESM and CM (inset: SCAs of water droplets, EDX spectra of the membrane samples).

Fig.2 (a) ATR-FTIR spectra of ESM and CM. Enlarged spectra in the ranges of (b) 1200–1700 cm⁻¹ and (c) 650–850 cm⁻¹.

Tab.1 Results of ARXPS fit for ESM and CM

Tab.2 Characteristics of ESM and CM used in this study

Fig.3 Representative SCA images of (a) ESM and (d) CM, and SEM images of (b)(c) PMIA ESM/Au and (e)(f) PMIA CM/Au at Au precursor concentration of 0.01 mol·L⁻¹.

Fig.4 UV-vis spectra of adsorption of (a)(b) MB and (c)(d) MO of the PMIA ESM and the CM. The membrane sample (0.01 g) are placed in 10 mL of 10 mg·L⁻¹ dye solution.

Fig.5 (a) Adsorption isotherm curves for several cationic dyes. (b) Photographs of the dye-adsorption experiment of the PMIA ESM (at pH~7, room temperature). From left to right: BV 14, Rh B, MG, basic yellow 2, MB, basic blue 7.

Fig.6 Schematic of the adsorption mechanisms of MB and MO on the PMIA ESM and the CM.

Fig.7 (a) Schematic of the reversible chain segment switch and adsorption behavior for cationic dyes. (b) Change of contact angle (black line) and dye-adsorption capacity (red line) of the ESM/CM during the switching process. Digital images (inset) represent the colors of the ESM with adsorbed MB after multiple electrospinning cycles. (c)(d) Different dyes adsorbed by the ESM.

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