Small-sized Ni-Co/Mo2C/Co6Mo6C2@C for efficient alkaline and acidic hydrogen evolution reaction by an anchoring calcination strategy

doi:10.1007/s11705-024-2416-2

2024, Vol. 18

Issue (5) : 57 https://doi.org/10.1007/s11705-024-2416-2

Small-sized Ni-Co/Mo₂C/Co₆Mo₆C₂@C for efficient alkaline and acidic hydrogen evolution reaction by an anchoring calcination strategy

Jianxia Gu¹(

), Ying Zhu², Haiyan Zheng², Chunyi Sun²(

), Zhongmin Su²

¹. Department of Chemistry, Xinzhou Normal University, Xinzhou 034000, China
². School of Chemistry, Northeast Normal University, Changchun 130024, China

Download: PDF(5903 KB) HTML
Export: BibTeX | EndNote | Reference Manager | ProCite | RefWorks

Abstract

A novel, cheap and highly efficient Ni-Co/Mo₂C/Co₆Mo₆C₂@C nanocomposite has been successfully constructed through simple one-step carbonization method in a nitrogen atmosphere. Polyethyleneimine in the precursor can effectively anchor molybdenum-based Keggin-type polyoxometallate and NiCo-layered double hydroxide through electrostatic and coordination interactions, which avoids the aggregation of catalyst particles during the pyrolysis process. After optimization, the obtained Ni-Co/Mo₂C/Co₆Mo₆C₂@C possesses small size (3–8 nm), large specific surface area and hierarchical pore structure. More importantly, Ni-Co/Mo₂C/Co₆Mo₆C₂@C presents remarkable hydrogen evolution reaction activity with low overpotentials in 0.5 mol·L^–1 H₂SO₄ (102.3 mV) and 1 mol·L^–1 KOH (95 mV) to afford the current density of 10 mA·cm^–2, as well as small Tafel slopes of 82.49 and 99.92 mV·dec^–1, respectively. Simultaneously, this catalyst also shows outstanding stability for 12 h without a significant change in current density. The excellent catalytic performance of Ni-Co/Mo₂C/Co₆Mo₆C₂@C can put down to the synergistic effect between multiple components and the small size of the catalyst. This work provides unique insights into the preparation of efficient transition metal-based catalysts for HER.

Keywords polyoxometallates layered double hydroxide transition metal-based electrocatalysts hydrogen evolution reaction

Corresponding Author(s): Jianxia Gu,Chunyi Sun

Just Accepted Date: 25 January 2024 Issue Date: 19 March 2024

Cite this article:

Jianxia Gu,Ying Zhu,Haiyan Zheng, et al. Small-sized Ni-Co/Mo₂C/Co₆Mo₆C₂@C for efficient alkaline and acidic hydrogen evolution reaction by an anchoring calcination strategy[J]. Front. Chem. Sci. Eng., 2024, 18(5): 57.

URL:

https://academic.hep.com.cn/fcse/EN/10.1007/s11705-024-2416-2
https://academic.hep.com.cn/fcse/EN/Y2024/V18/I5/57

Scheme1 Synthesis diagram of Ni-Co/Mo₂C/Co₆Mo₆C₂@C.

Fig.1 XRD patterns of Ni-Co/Mo₂C/Co₆Mo₆C₂@C, Mo₂C@C, Ni-Co@C and C.

Fig.2 (a) TEM image of Ni-Co/Mo₂C/Co₆Mo₆C₂@C (illustrated as particle size distribution in Ni-Co/Mo₂C/Co₆Mo₆C₂@C), (b–e) HRTEM images of Ni-Co/Mo₂C/Co₆Mo₆C₂@C, (f–i) EDX mapping of Ni, Co, and Mo in Ni-Co/Mo₂C/Co₆Mo₆C₂@C.

Fig.3 XPS spectra of Ni–Co/Mo₂C/Co₆Mo₆C₂@C, (a) C 1s, (b) N 1s, (c) Mo 3d and (d) Co 2p.

Fig.4 LSV curves and corresponding Tafel plots of Ni-Co/Mo₂C/Co₆Mo₆C₂@C, Mo₂C@C, Ni-Co@C, C and commercial 20% Pt/C in (a, c) 0.5 mol·L^–1 H₂SO₄ and (b, d) 1 mol·L^–1 KOH. (e, f) C_dl fitting graphs of Ni-Co/Mo₂C/Co₆Mo₆C₂@C, Mo₂C@C, Ni-Co@C, C in 0.5 mol·L^–1 H₂SO₄ and 1 mol·L^–1 KOH.

Fig.5 (a, b) Comparison of polarization curves of Ni-Co/Mo₂C/Co₆Mo₆C₂@C during 2000 cycles in acidic and alkaline solutions. (c, d) Stability tests of Ni-Co/Mo₂C/Co₆Mo₆C₂@C at constant voltage in acidic and alkaline solutions.

1	T Takata , J Z Jiang , Y Sakata , M Nakabayashi , N Shibata , V Nandal , K Seki , T Hisatomi , K Domen . Photocatalytic water splitting with a quantum efficiency of almost unity. Nature, 2020, 581(7809): 411–414 https://doi.org/10.1038/s41586-020-2278-9
2	Z H Yu , H Q Yan , C N Wang , Z Wang , H Q Yao , R Liu , C Li , S L Ma . Oxygen-deficient MoOx/Ni3S2 heterostructure grown onnickel foam as efficient and durable self-supported electrocatalysts for hydrogen evolution reaction. Frontiers of Chemical Science and Engineering, 2023, 17(4): 437–448 https://doi.org/10.1007/s11705-022-2228-1
3	L Q He , W B Zhang , Q J Mo , W J Huang , L C Yang , Q S Gao . Molybdenum carbide-oxide heterostructures: in-situ surface reconfiguration toward efficient electrocatalytic hydrogen evolution. Angewandte Chemie International Edition, 2020, 59(9): 3544–3548 https://doi.org/10.1002/anie.201914752
4	R W Qi , X Liu , H K Bu , X Q Niu , X Y Ji , J W Ma , H T Gao . In situ growth of phosphorized ZIF-67-derived amorphous CoP/Cu2O@CF electrocatalyst for efficient hydrogen evolution reaction. Frontiers of Chemical Science and Engineering, 2023, 17(10): 1430–1439 https://doi.org/10.1007/s11705-023-2320-1
5	Q Z Xiong , Y Wang , P F Liu , L R Zheng , G Z Wang , H G Yang , P K Wong , H M Zhang , H J Zhao . Cobalt covalent doping in MoS2 to induce bifunctionality of overall water splitting. Advanced Materials, 2018, 30(29): 1801450 https://doi.org/10.1002/adma.201801450
6	X G Feng , H X Wang , X J Bo , L P Guo . Bimetal-organic framework-derived porous rodlike cobalt/nickel nitride for all-pH value electrochemical hydrogen evolution. ACS Applied Materials & Interfaces, 2019, 11(8): 8018–8024 https://doi.org/10.1021/acsami.8b21369
7	W Huang , D J Zhou , G C Qi , X J Liu . Fe-doped MoS2 nanosheets array for high-current-density seawater electrolysis. Nanotechnology, 2021, 32(41): 415403 https://doi.org/10.1088/1361-6528/ac1195
8	S R Xu , H T Zhao , T S Li , J Liang , S Y Lu , G Chen , S Y Gao , A M Asiri , Q Wu , X P Sun . Iron-based phosphides as electrocatalysts for the hydrogen evolution reaction: recent advances and future prospects. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2020, 8(38): 19729–19745 https://doi.org/10.1039/D0TA05628F
9	J M Ge , S T Diao , J X Jin , Y P Wang , X H Zhao , F Z Zhang , X D Lei . NiFeCu phosphides with surface reconstruction via the topotactic transformation of layered double hydroxides for overall water splitting. Inorganic Chemistry Frontiers, 2023, 10(12): 3515–3524 https://doi.org/10.1039/D2QI02582E
10	B Fabre , C Falaise , E Cadot . Polyoxometalates-functionalized electrodes for (photo)electrocatalytic applications: recent advances and prospects. ACS Catalysis, 2022, 12(19): 12055–12091 https://doi.org/10.1021/acscatal.2c01847
11	J Song , J L Chen , Z C Xu , R Y Y Lin . Metal-organic framework-derived 2D layered double hydroxide ultrathin nanosheets for efficient electrocatalytic hydrogen evolution reaction. Chemical Communications, 2022, 58(76): 10655–10658 https://doi.org/10.1039/D2CC03994J
12	Z H Hu , J T Huang , Y Luo , M Q Liu , X B Li , M G Yan , Z G Ye , Z Chen , Z J Feng , S F Huang . Wrinkled Ni-doped Mo2C coating on carbon fiber paper: an advanced electrocatalyst prepared by molten-salt method for hydrogen evolution reaction. Electrochimica Acta, 2019, 319: 293–301 https://doi.org/10.1016/j.electacta.2019.06.178
13	Y T Xu , X F Xiao , Z M Ye , S L Zhao , R G Shen , C T He , J P Zhang , Y D Li , X M Chen . Cage-confinement pyrolysis route to ultrasmall tungsten carbide nanoparticles for efficient electrocatalytic hydrogen evolution. Journal of the American Chemical Society, 2017, 139(15): 5285–5288 https://doi.org/10.1021/jacs.7b00165
14	J X Huang , J L Wang , H X Zhong , L Z Zhang . N-Cyanoethyl polyethylenimine as a water-soluble binder for LiFePO4 cathode in lithium-ion batteries. Journal of Materials Science, 2018, 53(13): 9690–9700 https://doi.org/10.1007/s10853-018-2247-y
15	K Yamamoto , T Imaoka , M Tanabe , T Kambe . New horizon of nanoparticle and cluster catalysis with dendrimers. Chemical Reviews, 2020, 120(2): 1397–1437 https://doi.org/10.1021/acs.chemrev.9b00188
16	Y Q Jiao , H J Yan , R H Wang , X W Wang , X M Zhang , A P Wu , C G Tian , B J Jiang , H G Fu . Porous plate-like MoP assembly as an efficient pH-universal hydrogen evolution electrocatalyst. ACS Applied Materials & Interfaces, 2020, 12(44): 49596–49606 https://doi.org/10.1021/acsami.0c13533
17	W S Tang , J Q Bai , P C Zhou , Q H He , F Xiao , M J Zhao , P L Yang , L Liao , Y Wang , P He . et al.. Polymethylene blue nanospheres supported honeycomb-like NiCo-LDH for high-performance supercapacitors. Electrochimica Acta, 2023, 439: 141683 https://doi.org/10.1016/j.electacta.2022.141683
18	H Y Liang , J H Lin , H N Jia , S L Chen , J L Qi , J Cao , T S Lin , W D Fei , J C Feng . Hierarchical NiCo-LDH/NiCoP@NiMn-LDH hybrid electrodes on carbon cloth for excellent supercapacitors. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2018, 6(31): 15040–15046 https://doi.org/10.1039/C8TA05065A
19	X G Feng , X J Bo , L P Guo . An advanced hollow bimetallic carbide/nitrogen-doped carbon nanotube for efficient catalysis of oxygen reduction and hydrogen evolution and oxygen evolution reaction. Journal of Colloid and Interface Science, 2020, 575: 69–77 https://doi.org/10.1016/j.jcis.2020.04.093
20	J Wan , J B Wu , X Gao , T Q Li , Z M Hu , H M Yu , L Huang . Structure confined porous Mo2C for efficient hydrogen evolution. Advanced Functional Materials, 2017, 27(45): 1703933 https://doi.org/10.1002/adfm.201703933
21	J X Gu , X Zhao , Y Sun , J Zhou , C Y Sun , X L Wang , Z H Kang , Z M Su . A photo-activated process cascaded electrocatalysis for the highly efficient CO2 reduction over a core-shell ZIF-8@Co/C. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2020, 8(32): 16616–16623 https://doi.org/10.1039/D0TA04595K
22	H Y Zheng , N Xu , B S Hou , X Zhao , M Dong , C Y Sun , X L Wang , Z M Su . Bimetallic metal-organic framework-derived graphitic carbon-coated small Co/VN nanoparticles as advanced trifunctional electrocatalysts. ACS Applied Materials & Interfaces, 2021, 13(2): 2462–2471 https://doi.org/10.1021/acsami.0c16205
23	Y Zhu , H Y Zheng , X Y Liu , C Y Sun , M Dong , X L Wang , Z M Su . Ultra-small porous WN/W2C nanoparticles for sustained hydrogen production by a polyoxometalate-intercalated pyrolysis strategy. New Journal of Chemistry, 2022, 46(48): 23292–23296 https://doi.org/10.1039/D2NJ04218E
24	L B Wang , W B Zhang , X S Zheng , Y Z Chen , W L Wu , J X Qiu , X C Zhao , X Zhao , Y Z Dai , J Zeng . Incorporating nitrogen atoms into cobalt nanosheets as a strategy to boost catalytic activity toward CO2 hydrogenation. Nature Energy, 2017, 2(11): 869–876 https://doi.org/10.1038/s41560-017-0015-x
25	B B Fan , H Z Wang , H Zhang , Y Song , X R Zheng , C J Li , Y Q Tan , X P Han , Y D Deng , W B Hu . Phase transfer of Mo2C induced by boron doping to boost nitrogen reduction reaction catalytic activity. Advanced Functional Materials, 2022, 32(20): 2110783 https://doi.org/10.1002/adfm.202110783
26	R Boppella , J Park , W S Yang , J W Tan , J Moon . Efficient electrocatalytic proton reduction on CoP nanocrystals embedded in microporous P, N Co-doped carbon spheres with dual active sites. Carbon, 2020, 156: 529–537 https://doi.org/10.1016/j.carbon.2019.09.082
27	Y J Tang , C H Liu , W Huang , X L Wang , L Z Dong , S L Li , Y Q Lan . Bimetallic carbides-based nanocomposite as superior electrocatalyst for oxygen evolution reaction. ACS Applied Materials & Interfaces, 2017, 9(20): 16977–16985 https://doi.org/10.1021/acsami.7b01096
28	Q Qing , L L Chen , T Wei , Y M Wang , X E Liu . Ni/NiM2O4 (M = Mn or Fe) supported on N-doped carbon nanotubes as trifunctional electrocatalysts for ORR, OER and HER. Catalysis Science & Technology, 2019, 9(7): 1595–1601 https://doi.org/10.1039/C8CY02504E
29	H J Liu , S Zhang , W Z Qiao , R Y Fan , B Liu , S T Wang , H Hu , Y M Chai , B Dong . Bimetallic metal-organic framework-derived bamboo-like N-doped carbon nanotube-encapsulated Ni-doped MoC nanoparticles for water oxidation. Journal of Colloid and Interface Science, 2024, 657: 208–218 https://doi.org/10.1016/j.jcis.2023.11.133
30	J Q Chi , J Y Xie , W W Zhang , B Dong , J F Qin , X Y Zhang , J H Lin , Y M Chai , C G Liu . Chai Y M. N-Doped sandwich-structured Mo2C@C@Pt interface with ultralow Pt loading for pH-universal hydrogen evolution reaction. ACS Applied Materials & Interfaces, 2019, 11(4): 4047–4056 https://doi.org/10.1021/acsami.8b20209
31	L F Lai , J R Potts , D Zhan , L Wang , C K Poh , C H Tang , H Gong , Z X Shen , J Y Lin , R S Ruoff . Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction. Energy & Environmental Science, 2012, 5(7): 7936–7942 https://doi.org/10.1039/c2ee21802j
32	C Wu , D Liu , H Li , J H Li . Molybdenum carbide-decorated metallic cobalt@nitrogen-doped carbon polyhedrons for enhanced electrocatalytic hydrogen evolution. Small, 2018, 14(16): 1704227 https://doi.org/10.1002/smll.201704227
33	H J Liu , S Zhang , Y M Chai , B Dong . Ligand modulation of active sites to promote cobalt-doped 1T-MoS2 electrocatalytic hydrogen evolution in alkaline media. Angewandte Chemie International Edition, 2023, 62(48): 202313845 https://doi.org/10.1002/anie.202313845
34	Q S Gao , W B Zhang , Z P Shi , L C Yang , Y Tang . Structural design and electronic modulation of transition metal-carbide electrocatalysts toward efficient hydrogen evolution. Advanced Materials, 2019, 31(2): 1802880 https://doi.org/10.1002/adma.201802880
35	M S Faber , S Jin . Earth-abundant inorganic electrocatalysts and their nanostructures for energy conversion applications. Energy & Environmental Science, 2014, 7(11): 3519–3542 https://doi.org/10.1039/C4EE01760A
36	J Q Chi , Y M Chai , X Shang , B Dong , C G Liu , W J Zhang , Z Jin . Heterointerface engineering of trilayer-shelled ultrathin MoS2/MoP/N-doped carbon hollow nanobubbles for efficient hydrogen evolution. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2018, 6(48): 24783–24792 https://doi.org/10.1039/C8TA08753A
37	N N Chen , W B Zhang , J C Zeng , L Q He , D Li , Q S Gao . Plasma-engineered MoP with nitrogen doping: electron localization toward efficient alkaline hydrogen evolution. Applied Catalysis B: Environmental, 2020, 268: 118441 https://doi.org/10.1016/j.apcatb.2019.118441
38	X Z Chen , J Qi , P Wang , C Li , X Chen , C H Liang . Polyvinyl alcohol protected Mo2C/Mo2N multicomponent electrocatalysts with controlled morphology for hydrogen evolution reaction in acid and alkaline medium. Electrochimica Acta, 2018, 273: 239–247 https://doi.org/10.1016/j.electacta.2018.04.033
39	Y Zang , B P Yang , A Li , C G Liao , G Chen , M Liu , X H Liu , R Z Ma , N Zhang . Tuning interfacial active sites over porous Mo2N-supported cobalt sulfides for efficient hydrogen evolution reactions in acid and alkaline electrolytes. ACS Applied Materials & Interfaces, 2021, 13(35): 41573–41583 https://doi.org/10.1021/acsami.1c10060
40	H J Yan , Y Xie , Y Q Jiao , A P Wu , C G Tian , X M Zhang , L Wang , H G Fu . Holey reduced graphene oxide coupled with an Mo2N-Mo2C heterojunction for efficient hydrogen evolution. Advanced Materials, 2018, 30(2): 1704156 https://doi.org/10.1002/adma.201704156
41	Q Q Du , R H Zhao , T Y Guo , L Liu , X J Chen , J Zhang , J P Du , J P Li , L Q Mai , T Asefa . Highly dispersed Mo2C nanodots in carbon nanocages derived from Mo-based xerogel: efficient electrocatalysts for hydrogen evolution. Small Methods, 2021, 5(11): 2100334 https://doi.org/10.1002/smtd.202100334
42	W Liu , X T Wang , J K Qu , X L Liu , Z F Zhang , Y Z Guo , H Y Yin , D H Wang . Tuning Ni dopant concentration to enable co-deposited superhydrophilic self-standing Mo2C electrode for high-efficient hydrogen evolution reaction. Applied Catalysis B: Environmental, 2022, 307: 121–201 https://doi.org/10.1016/j.apcatb.2022.121201
43	J Y Qin , C Xi , R Zhang , T Liu , P C Zou , D Y Wu , Q J Guo , J Mao , H L Xin , J Yang . Activating edge-Mo of 2H-MoS2 via coordination with pyridinic N–C for pH-universal hydrogen evolution electrocatalysis. ACS Catalysis, 2021, 11(8): 4486–4497 https://doi.org/10.1021/acscatal.0c04415
44	T Ouyang , Y Q Ye , C Y Wu , K Xiao , Z Q Liu . Heterostructures composed of N-doped carbon nanotubes encapsulating cobalt and beta-Mo2C nanoparticles as bifunctional electrodes for water splitting. Angewandte Chemie International Edition, 2019, 58(15): 4923–4928 https://doi.org/10.1002/anie.201814262
45	X B Hou , H M Zhou , M Zhao , Y B Cai , Q F Wei . MoS2 nanoplates embedded in Co-N-doped carbon nanocages as efficient catalyst for HER and OER. ACS Sustainable Chemistry & Engineering, 2020, 8(14): 5724–5733 https://doi.org/10.1021/acssuschemeng.0c00810
46	C Y Wang , W J Zhao , H X Jiang , M Y Cui , Y Jin , R X Sun , X F Lin , L L Zhang . Molybdenum disulfide composite materials with encapsulated copper nanoparticles as hydrogen evolution catalysts. RSC Advances, 2022, 12(21): 13393–13400 https://doi.org/10.1039/D2RA02012B
47	J L Wei , L Xu , L H Hu , T J Wang , Y F Ma . Dual-doping strategy for enhancing hydrogen evolution on molybdenum carbide catalysts. Catalysts, 2023, 13(6): 931 https://doi.org/10.3390/catal13060931
48	P R Chen , L Z Ouyang , C G Lang , H Zhong , J W Liu , H Wang , Z G Huang , M Zhu . All-pH hydrogen evolution by heterophase molybdenum carbides prepared via mechanochemical synthesis. ACS Sustainable Chemistry & Engineering, 2023, 11(9): 3585–3593 https://doi.org/10.1021/acssuschemeng.2c05547
49	Y Qiu , J Z Liu , M X Sun , J F Yang , J Z Liu , X Y Zhang , X J Liu , L X Zhang . Rational design of electrocatalyst with abundant Co/MoN heterogeneous domains for accelerating hydrogen evolution reaction. Chinese Journal of Structural Chemistry, 2022, 41: 2207040–2207045
50	M Y Ma , H Z Yu , L M Deng , L Q Wang , S Y Liu , H Pan , J W Ren , M Y Maximov , F Hu , S J Peng . Interfacial engineering of heterostructured carbon-supported molybdenum cobalt sulfides for efficient overall water splitting. Tungsten, 2023, 5(4): 589–597 https://doi.org/10.1007/s42864-023-00212-6

[1]

FCE-23095-OF-GJ_suppl_1

Download

[1]	Na Xing, Nan Gao, Panbin Ye, Xiaowei Yang, Haifeng Wang, Jijun Zhao. Bilayer borophene: an efficient catalyst for hydrogen evolution reaction[J]. Front. Chem. Sci. Eng., 2024, 18(3): 26-.
[2]	Yongji Qin, Huijie Cao, Qian Liu, Shaoqing Yang, Xincai Feng, Hao Wang, Meiling Lian, Dongxing Zhang, Hua Wang, Jun Luo, Xijun Liu. Multi-functional layered double hydroxides supported by nanoporous gold toward overall hydrazine splitting[J]. Front. Chem. Sci. Eng., 2024, 18(1): 6-.
[3]	Zihuan Yu, Haiqing Yan, Chaonan Wang, Zheng Wang, Huiqin Yao, Rong Liu, Cheng Li, Shulan Ma. Oxygen-deficient MoO_x/Ni₃S₂ heterostructure grown on nickel foam as efficient and durable self-supported electrocatalysts for hydrogen evolution reaction[J]. Front. Chem. Sci. Eng., 2023, 17(4): 437-448.
[4]	Xuanze Li, Wenyan Tian, Caichao Wan, Sulai Liu, Xinyi Liu, Jiahui Su, Huayun Chai, Yiqiang Wu. Hierarchically porous cellulose nanofibril aerogel decorated with polypyrrole and nickel-cobalt layered double hydroxide for high-performance nonenzymatic glucose sensors[J]. Front. Chem. Sci. Eng., 2023, 17(10): 1593-1607.
[5]	Lihong Chen, Ruxin Deng, Shaoshi Guo, Zihuan Yu, Huiqin Yao, Zhenglong Wu, Keren Shi, Huifeng Li, Shulan Ma. Synergistic effect of V and Fe in Ni/Fe/V ternary layered double hydroxides for efficient and durable oxygen evolution reaction[J]. Front. Chem. Sci. Eng., 2023, 17(1): 102-115.
[6]	Folin Liu, Shaohua Feng, Siyuan Xiu, Bin Yang, Yang Hou, Lecheng Lei, Zhongjian Li. Co anchored on porphyrinic triazine-based frameworks with excellent biocompatibility for conversion of CO₂ in H₂-mediated microbial electrosynthesis[J]. Front. Chem. Sci. Eng., 2022, 16(12): 1761-1771.
[7]	Vishal Kandathil, Akshay Moolakkil, Pranav Kulkarni, Alaap Kumizhi Veetil, Manjunatha Kempasiddaiah, Sasidhar Balappa Somappa, R. Geetha Balakrishna, Siddappa A. Patil. Pd/Fe₃O₄ supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C–C coupling and electrocatalytic application[J]. Front. Chem. Sci. Eng., 2022, 16(10): 1514-1525.
[8]	Laicong Deng, Zhuxian Yang, Rong Li, Binling Chen, Quanli Jia, Yanqiu Zhu, Yongde Xia. Graphene-reinforced metal-organic frameworks derived cobalt sulfide/carbon nanocomposites as efficient multifunctional electrocatalysts[J]. Front. Chem. Sci. Eng., 2021, 15(6): 1487-1499.
[9]	Hao-Yu Wang, Chen-Chen Weng, Jin-Tao Ren, Zhong-Yong Yuan. An overview and recent advances in electrocatalysts for direct seawater splitting[J]. Front. Chem. Sci. Eng., 2021, 15(6): 1408-1426.
[10]	Yu Lin, Jinlei Wang, Duanlin Cao, Yaqiong Gong. Tuning the electronic structure of NiCoP arrays through V doping for pH-universal hydrogen evolution reaction electrocatalyst[J]. Front. Chem. Sci. Eng., 2021, 15(5): 1134-1146.
[11]	Ling Tan, Kipkorir Peter, Jing Ren, Baoyang Du, Xiaojie Hao, Yufei Zhao, Yu-Fei Song. Photocatalytic syngas synthesis from CO₂ and H₂O using ultrafine CeO₂-decorated layered double hydroxide nanosheets under visible-light up to 600 nm[J]. Front. Chem. Sci. Eng., 2021, 15(1): 99-108.
[12]	Shenghua Ye, Gaoren Li. Polypyrrole@NiCo hybrid nanotube arrays as high performance electrocatalyst for hydrogen evolution reaction in alkaline solution[J]. Front. Chem. Sci. Eng., 2018, 12(3): 473-480.
[13]	Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang. Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes[J]. Front. Chem. Sci. Eng., 2018, 12(3): 494-508.
[14]	Wenfu Xie, Zhenhua Li, Mingfei Shao, Min Wei. Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting[J]. Front. Chem. Sci. Eng., 2018, 12(3): 537-554.
[15]	Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu. Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas[J]. Front. Chem. Sci. Eng., 2017, 11(4): 613-623.

Viewed

Full text

Abstract

Cited

Shared

Discussed