<i>In vitro</i> corrosion of Mg--Ca alloy --- The influence of glucose content

doi:10.1007/s11706-017-0391-y

Front. Mater. Sci.

2017, Vol. 11

Issue (3) : 284-295 https://doi.org/10.1007/s11706-017-0391-y

RESEARCH ARTICLE

In vitro corrosion of Mg--Ca alloy --- The influence of glucose content

Lan-Yue CUI¹, Xiao-Ting LI¹, Rong-Chang ZENG¹(

), Shuo-Qi LI¹, En-Hou HAN², Liang SONG¹(

)

¹. College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China
². National Engineering Center for Corrosion Control, Institute of Metals Research, Chinese Academy of Sciences, Shenyang 110016, China

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Abstract

Influence of glucose on corrosion of biomedical Mg–1.35Ca alloy was made using hydrogen evolution, pH and electrochemical polarization in isotonic saline solution. The corrosion morphologies, compositions and structures were probed by virtue of SEM, EDS, FTIR, XRD and XPS. Results indicate that the glucose accelerated the corrosion of the alloy. The elemental Ca has no visible effect on the corrosion mechanism of glucose for the Mg–1.35Ca alloy in comparison with pure Mg. In addition, the presence of CO₂ has beneficial effect against corrosion due to the formation of a layer of carbonate-containing products.

Keywords magnesium corrosion glucose biomaterial

Corresponding Author(s): Rong-Chang ZENG,Liang SONG

Online First Date: 09 August 2017 Issue Date: 24 August 2017

Cite this article:

Lan-Yue CUI,Xiao-Ting LI,Rong-Chang ZENG, et al. In vitro corrosion of Mg--Ca alloy --- The influence of glucose content[J]. Front. Mater. Sci., 2017, 11(3): 284-295.

URL:

https://academic.hep.com.cn/foms/EN/10.1007/s11706-017-0391-y
https://academic.hep.com.cn/foms/EN/Y2017/V11/I3/284

Fig.1 Corrosion and electrochemical measurements of the Mg–1.35Ca alloy in 0.9% NaCl solutions with and without glucose:(a) HER; (b) pH value; (c) OCP; (d) polarization curves.

Tab.1 Electrochemical parameters of the polarization curves

Fig.2 SEM images and corresponding EDS spectra of the Mg–1.35Ca alloy after an exposure of 72 h in 0.9% NaCl solutions with different glucose contents:(a)(d)(g) 0.0% glucose; (b)(e)(h) 2.5% glucose; (c)(f)(i) 5.0% glucose.

Fig.3 EDS mapping of the Mg–1.35Ca alloy after an exposure of 72 h in 0.9% NaCl solutions with different glucose contents:(a)(b)(c)(d) 0.0% glucose; (e)(f)(g)(h) 2.5% glucose; (i)(j)(k)(l)(m) 5.0% glucose.

Fig.4 FTIR spectra of Mg–1.35Ca alloy: (a) immersed in saline solution with different glucose contents for 72 h; (b)(c) immersed in saline solution without and with 5% glucose for various periods.

Fig.5 XRD patterns: the Mg–1.35Ca alloy (a); samples after immersion for 72 h in saline solution with 0.0% glucose (b), 2.5% glucose (c) and 5.0% glucose (d).

Fig.6 XPS spectra of the Mg–1.35Ca alloy immersed in saline solution with and without glucose: (a) survey scanning; (b) C_1s; (c)(d) curve fitting of C_1s; (e) Cl_2p; (f) curve fitting of Cl_2p; (g)(h) curve fitting of Ca_2p1/2.

Fig.7 Histogram in comparison with i_corr, OCP, HER, and pH value between Mg and Mg–1.35Ca alloy immersed in saline solution with and without glucose.

Fig.8 Illustration of corrosion process of Mg–1.35Ca alloy immersed in saline solution (a) without and (b) with glucose.

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